scholarly journals The elusive silica/water interface: isolated silanols under water as revealed by vibrational sum frequency spectroscopy

2017 ◽  
Vol 19 (16) ◽  
pp. 10343-10349 ◽  
Author(s):  
Laetitia Dalstein ◽  
Elizaveta Potapova ◽  
Eric Tyrode

Isolated surface silanols are unambiguously identified under water. They are found to be not easily deprotonated and their populations to be clearly dependent on the surface pre-treatment method.

2016 ◽  
Vol 18 (27) ◽  
pp. 18424-18430 ◽  
Author(s):  
Yujin Tong ◽  
Tobias Kampfrath ◽  
R. Kramer Campen

Vibrational sum frequency spectroscopy measurements reveal that the libration frequency of interfacial water is significantly higher than bulk liquid water, suggesting that water's rotational potential stiffens on moving from the bulk liquid to the air/water interface.


2018 ◽  
Vol 122 (15) ◽  
pp. 3837-3849 ◽  
Author(s):  
Brittany P. Gordon ◽  
Frederick G. Moore ◽  
Lawrence F. Scatena ◽  
Nicholas A. Valley ◽  
Sumi N. Wren ◽  
...  

Soft Matter ◽  
2019 ◽  
Vol 15 (1) ◽  
pp. 38-46
Author(s):  
Petru Niga ◽  
Petra M. Hansson-Mille ◽  
Agne Swerin ◽  
Per M. Claesson ◽  
Joachim Schoelkopf ◽  
...  

Propofol adsorbs at the water interface forming a dense film, sitting tilted and oriented with the OH-group towards the water.


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