Decoupling diffusion from the bimolecular photoinduced electron transfer reaction: a combined ultrafast spectroscopic and kinetic analysis

2017 ◽  
Vol 19 (18) ◽  
pp. 11220-11229 ◽  
Author(s):  
Puspal Mukherjee ◽  
Pratik Sen

We have studied the bimolecular photoinduced electron transfer (PET) reaction between benzophenone (Bp) and DABCO using femtosecond broadband transient absorption spectroscopy in different compositions of acetonitrile/1-butanol binary solvent mixtures.

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