Effects of water on low-overpotential CO2 reduction in ionic liquid studied by sum-frequency generation spectroscopy

2017 ◽  
Vol 19 (16) ◽  
pp. 10491-10501 ◽  
Author(s):  
Natalia García Rey ◽  
Dana D. Dlott
Keyword(s):  
Ionic Liquid ◽  
Structural Transition ◽  
Co2 Reduction ◽  
Sum Frequency Generation ◽  
Catalytic Site ◽  
Threshold Potential ◽  
Sum Frequency ◽  
Transition Potential ◽  
Sum Frequency Generation Spectroscopy ◽  
Multiply Bonded

Adding water lowers the RTIL structural transition potential and the CO2 reduction threshold potential. Multiply-bonded CO is likely the more efficient catalytic site.

Anion Configuration at the Air/Liquid Interface of Ionic Liquid [bmim]OTf Studied by Sum-Frequency Generation Spectroscopy

2008 ◽  
Vol 112 (38) ◽  
pp. 11936-11941 ◽  
Author(s):  
Takashi Iwahashi ◽  
Takayuki Miyamae ◽  
Kaname Kanai ◽  
Kazuhiko Seki ◽  
Doseok Kim ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Sum Frequency Generation ◽  
Liquid Interface ◽  
Sum Frequency ◽  
Sum Frequency Generation Spectroscopy ◽  
Frequency Generation ◽  
Air Liquid Interface
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