Highly tuneable proton-conducting coordination polymers derived from a sulfonate-based ligand

CrystEngComm ◽  
2017 ◽  
Vol 19 (46) ◽  
pp. 7050-7056 ◽  
Author(s):  
Mei-Jie Wei ◽  
Jia-Qi Fu ◽  
Yi-Di Wang ◽  
Yi Zhang ◽  
Hong-Ying Zang ◽  
...  

Three highly proton-conducting coordination compounds have been synthesized via the HCl steaming-assisted conversion approach by using multiple functional groups including the sulfonate group and the Cl− or HPO42− group.

2017 ◽  
Vol 5 (3) ◽  
pp. 1085-1093 ◽  
Author(s):  
Mei-Jie Wei ◽  
Jia-Qi Fu ◽  
Yi-Di Wang ◽  
Jing-Yang Gu ◽  
Bai-Ling Liu ◽  
...  

We have synthesised three proton-conducting coordination complexes as solid proton-conducting electrolytes. Changes of sulfonate group coordination modes and different packing modes, as well as introduction of halide ions may remarkably enhance the proton conductivity of coordination compounds.


2016 ◽  
Vol 40 (3) ◽  
pp. 1997-2006 ◽  
Author(s):  
Kaustuv Banerjee ◽  
Kumar Biradha

The ligands containing chelating as well as exodentate functional groups were shown to form functional coordination polymers and heterometallic gels.


Proceedings ◽  
2019 ◽  
Vol 29 (1) ◽  
pp. 78
Author(s):  
Diana-Ioana Eftemie ◽  
Andrei A. Pătraşcu ◽  
Cătălin Maxim ◽  
Delia-Laura Popescu

Coordination compounds of organotin(IV) with diverse dimensionalities are obtained due to the ability of the tin atoms to have different coordination numbers, such as 4, 5, 6, or 7 [1]. [...]


1997 ◽  
Vol 52 (1) ◽  
pp. 125-134 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Roland Harbig ◽  
Oliver Struck ◽  
Frank Hampel ◽  
Eva Maria Peters ◽  
...  

Reaction of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a or 2b leads to the formation of the corresponding lD-coordination polymer 1∞[CuL2] 3a and pseudo 1D-coordination polymer [CuL2]2 3b, respectively. On the contrary, reaction of 2c with methanolic copper(II) acetate solution yields OH-bridged 1D-coordination polymer 1∞[CuL2(MeOH)2 3c. Single-crystal X-ray diffraction of the supramolecular species 3 established unequivocally the structures of the stairlike coordination compounds. Reaction of a methanolic copper(II) acetate solution with amidotetrazole derivative 6 leads to the formation of the lD-coordination polymer 1∞ [CuL2] 7. The structure of 7 has been established by X-ray structure analysis


2004 ◽  
Vol 44 (5) ◽  
pp. 803-806 ◽  
Author(s):  
Slobodan Novokmet ◽  
Mohammad S. Alam ◽  
Viatcheslav Dremov ◽  
Frank W. Heinemann ◽  
Paul Müller ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ioannis Mylonas-Margaritis ◽  
Julia Mayans ◽  
Wenming Tong ◽  
Pau Farras Costa ◽  
Albert Escuer ◽  
...  

The development of synthetic approaches towards new coordination polymers has attracted a significant interest due to their fascinating physical properties, as well as their use in a wide range of...


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