One-dimensional polymeric polybromotellurates(iv): structural and theoretical insights into halogen⋯halogen contacts

CrystEngComm ◽  
2017 ◽  
Vol 19 (39) ◽  
pp. 5934-5939 ◽  
Author(s):  
Andrey N. Usoltsev ◽  
Sergey A. Adonin ◽  
Alexander S. Novikov ◽  
Denis G. Samsonenko ◽  
Maxim N. Sokolov ◽  
...  
Keyword(s):  
Organic Cations ◽  
Supramolecular Polymers ◽  
One Dimensional

Reactions of TeO2and Br2in concentrated HBr in the presence of various organic cations resulted in the formation of one-dimensional supramolecular polymers with the structure cation2{[TeBr6](Br2)}.

scholarly journals Supramolecular polymers for organocatalysis in water

2015 ◽  
Vol 13 (28) ◽  
pp. 7711-7719 ◽  
Author(s):  
Laura N. Neumann ◽  
Matthew B. Baker ◽  
Christianus M. A. Leenders ◽  
Ilja K. Voets ◽  
René P. M. Lafleur ◽  
...  
Keyword(s):  
Aldol Reactions ◽  
Supramolecular Polymers ◽  
One Dimensional

An l-proline-functionalised benzene-1,3,5-tricarboxamide derivative self-assembles in water into well-defined, one-dimensional, helical, supramolecular polymers that efficiently catalyse aldol reactions.

Supramolecular self-assembly and photovoltaic property of soluble fluorogallium phthalocyanine

RSC Advances ◽  
2014 ◽  
Vol 4 (56) ◽  
pp. 29485-29492 ◽  
Author(s):  
Jian Zhang ◽  
Yaowen Li ◽  
Laibing Wang ◽  
Michiya Fujiki ◽  
Xiaopeng Li ◽  
...  
Keyword(s):  
Solid State ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Self Assembly ◽  
Power Conversion ◽  
Photovoltaic Property ◽  
Supramolecular Polymers ◽  
One Dimensional ◽  
Coating Technique

Fluorogallium tetra-tert-butylphthalocyanine (ttbPcGaF) can self-organize into well-ordered cofacial structures to obtain one-dimensional (1D) supramolecular polymers in the solid state using a solution-coating technique. The ttbPcGaF-based BHJ OSC provided a profoundly improved power conversion efficiency (PCE) of 0.41%.

catena-Poly[1,4-dihydroxy-1,4-diazoniabicyclo[2.2.2]octane [aquatri-μ-chlorido-trichloridodicuprate(II)]]

2013 ◽  
Vol 69 (4) ◽  
pp. 380-383 ◽  
Author(s):  
Wei-Qiang Liao ◽  
Qin-Qin Zhou ◽  
Yi Zhang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Chloride Ion ◽  
Distinct Type ◽  
Chloride Ions ◽  
Organic Cations ◽  
Two Dimensional ◽  
One Dimensional ◽  
Compound C

The title compound, {(C6H14N2O2)[Cu2Cl6(H2O)]}n, consists of 1,4-dihydroxy-1,4-diazoniabicyclo[2.2.2]octane dications and one-dimensional inorganic anionic {[Cu2Cl6(H2O)]2−}nchains in which both five-coordinate [CuCl3(H2O)]−and five-coordinate [CuCl3]−units exist. These two distinct type of unit are linked together by one chloride ion and are bridged across centres of inversion to further units of their own type through two chloride ions, giving rise to novel polymeric zigzag chains parallel to thecaxis. The chains are connected by O—H...Cl hydrogen bonds to produceR24(16) ring motifs, resulting in two-dimensional layers parallel to theacplane. These layers are linked into a three-dimensional framework with the organic cationsviaO—H...Cl hydrogen bonds. Hydrogen bonding between the chains, and between the chains and the organic cations, provides stability to the crystal structure.

scholarly journals Investigation of the Amide Linkages on Cooperative Supramolecular Polymerization of Organoplatinum(II) Complexes

Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2832
Author(s):  
Mingliang Gui ◽  
Yifei Han ◽  
Hua Zhong ◽  
Rui Liao ◽  
Feng Wang
Keyword(s):  
Rational Design ◽  
Structural Parameters ◽  
Supramolecular Polymers ◽  
Chirality Transfer ◽  
Polymeric Systems ◽  
One Dimensional ◽  
Thermo Stability ◽  
Conjugated Compounds ◽  
Supramolecular Polymerization ◽  
Hydrogen Bonding Strength

Cooperative supramolecular polymerization of π-conjugated compounds into one-dimensional nanostructures has received tremendous attentions in recent years. It is commonly achieved by incorporating amide linkages into the monomeric structures, which provide hydrogen bonds for intermolecular non-covalent complexation. Herein, the effect of amide linkages is elaborately studied, by comparing supramolecular polymerization behaviors of two structurally similar monomers with the same platinum(II) acetylide cores. As compared to the N-phenyl benzamide linkages, N-[(1S)-1-phenylethyl] benzamide linkages give rise to effective chirality transfer behaviors due to the closer distances between the chiral units and the platinum(II) acetylide core. They also provide stronger intermolecular hydrogen bonding strength, which consequently brings higher thermo-stability and enhanced gelation capability for the resulting supramolecular polymers. Supramolecular polymerization is further strengthened by varying the monomers from monotopic to ditopic structures. Hence, with the judicious modulation of structural parameters, the current study opens up new avenues for the rational design of supramolecular polymeric systems.

scholarly journals Direct detection of circular polarized light in helical 1D perovskite-based photodiode

2020 ◽  
Vol 6 (46) ◽  
pp. eabd3274
Author(s):  
A. Ishii ◽  
T. Miyasaka
Keyword(s):  
Direct Detection ◽  
Polarized Light ◽  
Organic Cations ◽  
Circularly Polarized Light ◽  
Circularly Polarized ◽  
One Dimensional ◽  
Left Handed ◽  
Plasmonic Metamaterials ◽  
Halide Perovskites ◽  
Lead Halide

Detection of circularly polarized light (CPL) has a high potential for development of various optical technologies. Conventional photodetectors require optical polarizers on the device to detect polarized light, and this causes substantial losses of sensitivity and resolution in light detection. Here, we report direct CPL detection by a photodiode using a helical one-dimensional (1D) structure of lead halide perovskites composed of naphthylethylamine-based chiral organic cations. The 1D structure with face-sharing (PbI6)4− octahedral chains whose helicity is largely affected by chiral cations shows intense circular dichroism (CD) signals over 3000 mdeg at 395 nm with the highly anisotropy factor (gCD) of 0.04. This high CD enables photocurrent detection with effective discrimination between left-handed and right-handed CPLs. The CPL detector based on this 1D perovskite achieved the highest polarization discrimination ratio of 25.4, which largely surpasses the direct detecting CPL devices (<4) using chiral plasmonic metamaterials and organic materials.

scholarly journals Fluorescent supramolecular polymers of barbiturate dyes with thiophene-cored twisted π-systems

2022 ◽  
Author(s):  
Maika Kawaura ◽  
Takumi Aizawa ◽  
Sho Takahashi ◽  
Hiroshi Miyasaka ◽  
Hikaru Sotome ◽  
...  
Keyword(s):  
Supramolecular Polymers ◽  
Conjugated Molecules ◽  
One Dimensional ◽  
Emission Efficiency ◽  
Supramolecular Polymerization ◽  
One Dimensional Nanostructures

Because supramolecular polymerization of emissive p-conjugated molecules depends strongly on p–pstacking interaction, the formation of well-defined one-dimensional nanostructures often results in decrease or only small increase of emission efficiency. This is also true...

scholarly journals Supramolecular polymerization of sulfated dendritic peptide amphiphiles into multivalent L-selectin binders

2021 ◽  
Vol 17 ◽  
pp. 97-104
Author(s):  
David Straßburger ◽  
Svenja Herziger ◽  
Katharina Huth ◽  
Moritz Urschbach ◽  
Rainer Haag ◽  
...  
Keyword(s):  
Self Assembly ◽  
Supramolecular Polymers ◽  
Supramolecular Polymer ◽  
Peptide Amphiphile ◽  
One Dimensional ◽  
Cryogenic Transmission Electron Microscopy ◽  
Naturally Occurring ◽  
Selectin Ligands ◽  
Transmission Electron ◽  
Supramolecular Polymerization

The synthesis of a sulfate-modified dendritic peptide amphiphile and its self-assembly into one-dimensional rod-like architectures in aqueous medium is reported. The influence of the ionic strength on the supramolecular polymerization was probed via circular dichroism spectroscopy and cryogenic transmission electron microscopy. Physiological salt concentrations efficiently screen the charges of the dendritic building block equipped with eight sulfate groups and trigger the formation of rigid supramolecular polymers. Since multivalent sulfated supramolecular structures mimic naturally occurring L-selectin ligands, the corresponding affinity was evaluated using a competitive SPR binding assay and benchmarked to an ethylene glycol-decorated supramolecular polymer.

scholarly journals Supramolecular fibrillation of peptide amphiphiles induces environmental responses in aqueous droplets

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Richard Booth ◽  
Ignacio Insua ◽  
Sahnawaz Ahmed ◽  
Alicia Rioboo ◽  
Javier Montenegro
Keyword(s):  
Self Assembly ◽  
Chemical Exchange ◽  
Peptide Amphiphiles ◽  
Supramolecular Polymers ◽  
Functional Responses ◽  
One Dimensional ◽  
Molecular Ordering ◽  
Physico Chemical ◽  
Environmental Responses

AbstractOne-dimensional (1D) supramolecular polymers are commonly found in natural and synthetic systems to prompt functional responses that capitalise on hierarchical molecular ordering. Despite amphiphilic self-assembly being significantly studied in the context of aqueous encapsulation and autopoiesis, very little is currently known about the physico-chemical consequences and functional role of 1D supramolecular polymerisation confined in aqueous compartments. Here, we describe the different phenomena that resulted from the chemically triggered supramolecular fibrillation of synthetic peptide amphiphiles inside water microdroplets. The confined connection of suitable dormant precursors triggered a physically autocatalysed chemical reaction that resulted in functional environmental responses such as molecular uptake, fusion and chemical exchange. These results demonstrate the potential of minimalistic 1D supramolecular polymerisation to modulate the behaviour of individual aqueous entities with their environment and within communities.

scholarly journals Molecular modelling of supramolecular one dimensional polymers

RSC Advances ◽  
2018 ◽  
Vol 8 (40) ◽  
pp. 22659-22669 ◽  
Author(s):  
Divya B. Korlepara ◽  
S. Balasubramanian
Keyword(s):  
Molecular Modelling ◽  
Computational Modelling ◽  
Supramolecular Polymers ◽  
One Dimensional ◽  
Modelling Approaches

Hierarchical computational modelling approaches for the study of supramolecular polymers is reviewed.

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