Solution-based sequential modification of LiCoO2particle surfaces with iron(ii) oxalate nanolayers

CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4175-4181
Author(s):  
Yuki Kishimoto ◽  
So Yubuchi ◽  
Akitoshi Hayashi ◽  
Masahiro Tatsumisago ◽  
Rie Makiura

Facile creation of hybrid metal oxide-core/MOF-shell structures is achieved by stepwise solution-based modification of the core surface with a framework compound.

2021 ◽  
Vol 5 (8) ◽  
pp. 3404-3412
Author(s):  
Jian Yeo ◽  
Gihyun Lee ◽  
Sujeong Lee ◽  
Moonhyun Oh

Yolk–shell and core–shell hybrid metal oxide double layers with varied metal compositions are rationally constructed via simple calcination of silica-templated coordination polymer double layers.


Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 867
Author(s):  
Lin Guo ◽  
Zhu Mao ◽  
Sila Jin ◽  
Lin Zhu ◽  
Junqi Zhao ◽  
...  

Surface-enhanced Raman scattering (SERS) is a powerful tool in charge transfer (CT) process research. By analyzing the relative intensity of the characteristic bands in the bridging molecules, one can obtain detailed information about the CT between two materials. Herein, we synthesized a series of Au nanorods (NRs) with different length-to-diameter ratios (L/Ds) and used these Au NRs to prepare a series of core–shell structures with the same Cu2O thicknesses to form Au NR–4-mercaptobenzoic acid (MBA)@Cu2O core–shell structures. Surface plasmon resonance (SPR) absorption bands were adjusted by tuning the L/Ds of Au NR cores in these assemblies. SERS spectra of the core-shell structure were obtained under 633 and 785 nm laser excitations, and on the basis of the differences in the relative band strengths of these SERS spectra detected with the as-synthesized assemblies, we calculated the CT degree of the core–shell structure. We explored whether the Cu2O conduction band and valence band position and the SPR absorption band position together affect the CT process in the core–shell structure. In this work, we found that the specific surface area of the Au NRs could influence the CT process in Au NR–MBA@Cu2O core–shell structures, which has rarely been discussed before.


2021 ◽  
Author(s):  
Hannah Rogers ◽  
Ciaran Beggan ◽  
Kathryn Whaler

<p>Spherical Slepian functions (or ‘Slepian functions’) are mathematical functions which can be used to decompose potential fields, as represented by spherical harmonics, into smaller regions covering part of a spherical surface. This allows a spatio-spectral trade-off between aliasing of the signal at the boundary edges while constraining it within a region of interest. While Slepian functions have previously been applied to geodetic and crustal magnetic data, this work further applies Slepian functions to flows on the core-mantle boundary. There are two main reasons for restricting flow models to certain parts of the core surface. Firstly, we have reason to believe that different dynamics operate in different parts of the core (such as under LLSVPs) while, secondly, the modelled flow is ambiguous over certain parts of the surface (when applying flow assumptions). Spherical Slepian functions retain many of the advantages of our usual flow description, concerning for example the boundary conditions it must satisfy, and allowing easy calculation of the power spectrum, although greater initial computational effort is required.</p><p><br>In this work, we apply Slepian functions to core flow models by directly inverting from satellite virtual observatory magnetic data into regions of interest. We successfully demonstrate the technique and current short comings by showing whole core surface flow models, flow within a chosen region, and its corresponding complement. Unwanted spatial leakage is generated at the region edges in the separated flows but to less of an extent than when using spherical Slepian functions on existing flow models. The limited spectral content we can infer for core flows is responsible for most, if not all, of this leakage. Therefore, we present ongoing investigations into the cause of this leakage, and to highlight considerations when applying Slepian functions to core surface flow modelling.</p>


2018 ◽  
Vol 16 (1) ◽  
Author(s):  
Christopher Poon ◽  
Juan Gallo ◽  
Johan Joo ◽  
Timothy Chang ◽  
Manuel Bañobre-López ◽  
...  

2013 ◽  
Vol 26 ◽  
pp. 23-30 ◽  
Author(s):  
Angela S. Wochnik ◽  
Anna Frank ◽  
Christoph Heinzl ◽  
Jonas Häusler ◽  
Julian Schneider ◽  
...  

1994 ◽  
Vol 31 (02) ◽  
pp. 106-115
Author(s):  
C. Chryssostomidis ◽  
N.A. Papadakis

This paper examines the buckling phenomenon of sandwich cylindrical shell structures subjected to hydrostatic pressure. Global bifurcation buckling is considered, and the effect of discrete ring stiffeners on the critical pressure is analyzed. The local buckling problem is discussed, including the influence of the shape and the thickness of the core stiffeners on the critical load. Finally, the paper treats the sensitivity of local and global buckling on the thickness distribution between the inner and outer shells of the sandwich structure.


2019 ◽  
Vol 7 (5) ◽  
pp. 1280-1291 ◽  
Author(s):  
Alaka Panda ◽  
R. Govindaraj ◽  
R. Mythili ◽  
G. Amarendra

Bismuth and iron oxides subjected to ball milling followed by controlled annealing treatments showed the formation of core–shell nanostructures with Bi2Fe4O9 as the core and a shell of BiFeO3 and Bi25FeO40 phases as deduced based on the analysis of transmission electron microscopy results.


2007 ◽  
Vol 119 ◽  
pp. 17-20
Author(s):  
Gil Pyo Kim ◽  
Seung Bum Yoon ◽  
Young Soo Jung ◽  
Jae Hoon Ahn ◽  
Sung Hyeon Baeck ◽  
...  

Nanoparticles (Au, Pt, Ru) supported on metal oxides (TiO2, Heteropoly Acid) were prepared by PS-PVP block copolymer encapsulation method. It was confirmed by XPS analysis that the oxidation state of metal is 0 after calcination, which indicates the complete removal of polymer. Synthesized catalysts were characterized by TEM, SEM-EDS, and UV-VIS spectroscopy and it was observed that synthesis and calcination conditions, and the interaction between nanoparticle and metal oxide affected significantly the particle size of metal on the surface of metal oxide. When two different metal precursors were diffused into the core of inversed micelles, nano alloy could be synthesized and the composition of nano alloy was controlled by varying the ratio between the two metal precursors.


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