Metal–organic frameworks at interfaces of hybrid perovskite solar cells for enhanced photovoltaic properties

2018 ◽  
Vol 54 (10) ◽  
pp. 1253-1256 ◽  
Author(s):  
Deli Shen ◽  
Aiying Pang ◽  
Yafeng Li ◽  
Jie Dou ◽  
Mingdeng Wei
Keyword(s):  
Grain Size ◽  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Photovoltaic Properties ◽  
Hybrid Perovskite ◽  
Metal Organic

A ZIF-8 modified interface increases the grain size of perovskite crystals, resulting in a maximum PCE of 16.99%.

scholarly journals Metal-Organic Framework Materials for Perovskite Solar Cells

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2061
Author(s):  
Do Yeon Heo ◽  
Ha Huu Do ◽  
Sang Hyun Ahn ◽  
Soo Young Kim
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Metal Organic Framework ◽  
Perovskite Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Hole Transport ◽  
Framework Materials ◽  
Hybrid Perovskite ◽  
Hole Transport Layers ◽  
Metal Organic

Metal-organic frameworks (MOFs) and MOF-derived materials have been used for several applications, such as hydrogen storage and separation, catalysis, and drug delivery, owing to them having a significantly large surface area and open pore structure. In recent years, MOFs have also been applied to thin-film solar cells, and attractive results have been obtained. In perovskite solar cells (PSCs), the MOF materials are used in the form of an additive for electron and hole transport layers, interlayer, and hybrid perovskite/MOF. MOFs have the potential to be used as a material for obtaining PSCs with high efficiency and stability. In this study, we briefly explain the synthesis of MOFs and the performance of organic and dye-sensitized solar cells with MOFs. Furthermore, we provide a detailed overview on the performance of the most recently reported PSCs using MOFs.

Multifunctional Anionic Metal-organic Frameworks Enhancing Stability of Perovskite Solar Cells

2021 ◽  
pp. 133587
Author(s):  
Chi Li ◽  
Junming Qiu ◽  
Mengqi Zhu ◽  
Zhibin Cheng ◽  
Jindan Zhang ◽  
...  
Keyword(s):  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Metal Organic

Fabrication of lead iodide perovskite solar cells by incorporating zirconium, indium and zinc metal-organic frameworks

Solar Energy ◽  
2021 ◽  
Vol 214 ◽  
pp. 138-148
Author(s):  
Mahsa Seifpanah Sowmehesaraee ◽  
Maryam Ranjbar ◽  
Mohammad Abedi ◽  
Seyed Ahmad Mozaffari
Keyword(s):  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Lead Iodide ◽  
Zinc Metal ◽  
Metal Organic

scholarly journals Mesoporous perovskite solar cells with Al- and Zn-based metal-organic frameworks

2021 ◽  
Vol 2015 (1) ◽  
pp. 012042
Author(s):  
A.D. Furasova ◽  
G. Hix ◽  
S.V. Makarov ◽  
A. Di Carlo
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Metal Organic ◽  
Halide Perovskites ◽  
Photovoltaic Parameters ◽  
Photovoltaic Technology ◽  
Lead Halide ◽  
Thin Film Devices

Abstract The improvement of lead halide perovskites solar cells (PSC) by hydrophobic metal-organic frameworks (MOF) is one of the promising tools for modern photovoltaic technology to achieve stable and efficient thin-film devices. To show the MOF applicability for PSC, we incorporate two types of MOF: NH2-MIL-53(Al) and basolite Z1200 in n-i-p mesoporous MAPbI3 based solar cells that can add 2.2% efficiency by increasing main photovoltaic parameters. The simplicity of the proposed MOF’s integration allows to use and adopt this approach to incorporate other frameworks for thin-film perovskite devices.

Nanocrystalline Titanium Metal–Organic Frameworks for Highly Efficient and Flexible Perovskite Solar Cells

ACS Nano ◽  
2018 ◽  
Vol 12 (5) ◽  
pp. 4968-4975 ◽  
Author(s):  
UnJin Ryu ◽  
Seohyeon Jee ◽  
Joon-Suh Park ◽  
Il Ki Han ◽  
Ju Ho Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Titanium Metal ◽  
Highly Efficient ◽  
Metal Organic ◽  
Nanocrystalline Titanium

Research Progress of Metal-organic Frameworks in Organic Perovskite Solar Cells

2021 ◽  
Vol 42 (11) ◽  
pp. 1722-1738
Author(s):  
Rui-fu HE ◽  
◽  
Fei-fan ZHOU ◽  
Jun-le QU ◽  
Jun SONG ◽  
...  
Keyword(s):  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Research Progress ◽  
Metal Organic

scholarly journals Correction to Nanocrystalline Titanium Metal–Organic Frameworks for Highly Efficient and Flexible Perovskite Solar Cells

ACS Nano ◽  
2018 ◽  
Vol 12 (7) ◽  
pp. 7416-7416 ◽  
Author(s):  
UnJin Ryu ◽  
Seohyeon Jee ◽  
Joon-Suh Park ◽  
Il Ki Han ◽  
Ju Ho Lee ◽  
...  
Keyword(s):  
Solar Cells ◽  
Metal Organic Frameworks ◽  
Perovskite Solar Cells ◽  
Titanium Metal ◽  
Highly Efficient ◽  
Metal Organic ◽  
Nanocrystalline Titanium

Fast Thermal Annealing of CH3NH3PbI3-xClx Films for Improving Hybrid Photovoltaics

2017 ◽  
Vol 727 ◽  
pp. 923-928
Author(s):  
Jian Hong Zhao ◽  
Lei Ming Yu ◽  
Tao Yu Zou ◽  
Zhen Fang Qiao ◽  
Li Luo ◽  
...  
Keyword(s):  
Grain Size ◽  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Heterojunction Solar Cells ◽  
Perovskite Materials ◽  
Hybrid Perovskite ◽  
Temperature Solution ◽  
One Step ◽  
Hybrid Photovoltaics

Organic-inorganic hybrid perovskite materials offer the potential for realization of low-cost and flexible next-generation solar cells fabricated by low-temperature solution processing. Although efficiencies of perovskite solar cells have dramatically improved up to 22.1% within the past 6 years, there is still considerable room for further improvement in device efficiency through development of smooth and large grain size perovskite films. Commonly, the smooth perovskite layers and large grains are alternative to CH3NH3PbI3-xClx. However, the previous one-step fabrication of CH3NH3PbI3-xClx using PbCl2 needs long annealing time. Herein, the active layer, a noncontinuous CH3NH3PbI3-xClx film with micrometre-level crystalline grain, was fabricated using a one-step spin-coating process followed by high-temperature annealing and exhibited an increased efficiency of 9.93%. This finding enables the formation of larger grain size perovskite films and the demonstration of efficient perovskite heterojunction solar cells.

scholarly journals Application of Metal-Organic Frameworks and Covalent Organic Frameworks as (Photo)Active Material in Hybrid Photovoltaic Technologies

Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5602
Author(s):  
Onur Yildirim ◽  
Matteo Bonomo ◽  
Nadia Barbero ◽  
Cesare Atzori ◽  
Bartolomeo Civalleri ◽  
...  
Keyword(s):  
Solar Cells ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
Active Material ◽  
High Surface Area ◽  
Perovskite Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Building Blocks ◽  
Covalent Organic Frameworks ◽  
Metal Organic

Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are two innovative classes of porous coordination polymers. MOFs are three-dimensional materials made up of secondary building blocks comprised of metal ions/clusters and organic ligands whereas COFs are 2D or 3D highly porous organic solids made up by light elements (i.e., H, B, C, N, O). Both MOFs and COFs, being highly conjugated scaffolds, are very promising as photoactive materials for applications in photocatalysis and artificial photosynthesis because of their tunable electronic properties, high surface area, remarkable light and thermal stability, easy and relative low-cost synthesis, and structural versatility. These properties make them perfectly suitable for photovoltaic application: throughout this review, we summarize recent advances in the employment of both MOFs and COFs in emerging photovoltaics, namely dye-sensitized solar cells (DSSCs) organic photovoltaic (OPV) and perovskite solar cells (PSCs). MOFs are successfully implemented in DSSCs as photoanodic material or solid-state sensitizers and in PSCs mainly as hole or electron transporting materials. An innovative paradigm, in which the porous conductive polymer acts as standing-alone sensitized photoanode, is exploited too. Conversely, COFs are mostly implemented as photoactive material or as hole transporting material in PSCs.

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