scholarly journals Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding

2017 ◽  
Vol 53 (88) ◽  
pp. 12048-12051 ◽  
Author(s):  
A. F. R. Kilpatrick ◽  
J. C. Green ◽  
Z. R. Turner ◽  
J.-C. Buffet ◽  
D. O’Hare
Keyword(s):  
Electronic Structure ◽  
Chloride Complex ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Aromatic Solvent ◽  
Structure And Bonding

Reduction of a permethylpentalene zirconium(iv) chloride complex [η8-Pn*Zr(μ-Cl)3/2]2(μ-Cl)2Li·THFxwith KC8in benzene results in activation of the aromatic solvent to yield an “inverted sandwich” complex, [η8-Pn*Zr]2(μ-η6:η6-C6H6) (1).

Electronic structure and bonding studies on triple-decker sandwich complexes with a P6middle ring

2007 ◽  
Vol 28 (1) ◽  
pp. 310-319 ◽  
Author(s):  
Dandamudi Usha Rani ◽  
Dasari L. V. K. Prasad ◽  
John F. Nixon ◽  
Eluvathingal D. Jemmis
Keyword(s):  
Electronic Structure ◽  
Sandwich Complexes ◽  
Structure And Bonding

Electronic structure and bonding in tetradecker sandwich complexes

1990 ◽  
Vol 112 (2) ◽  
pp. 722-727 ◽  
Author(s):  
Eluvathingal D. Jemmis ◽  
A. Chandrasekhar Reddy
Keyword(s):  
Electronic Structure ◽  
Sandwich Complexes ◽  
Structure And Bonding

Bis(monoazacrown ethers) with an electron-donating substituent at the hinge: A pronounced participation of hydroxyl group in formation of sodium ion sandwich complexes

1989 ◽  
Vol 54 (4) ◽  
pp. 1043-1054 ◽  
Author(s):  
Jiří Závada ◽  
Juraj Koudelka ◽  
Petr Holý ◽  
Martin Bělohradský ◽  
Ivan Stibor
Keyword(s):  
Complex Formation ◽  
Sandwich Structure ◽  
Sodium Ion ◽  
Hydroxyl Group ◽  
Complex Stability ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Marked Enhancement ◽  
Stability Data ◽  
Potentiometric Data

Sodium ion complex formation has been investigated potentiometrically in four homologous bis(crown) series I-IV differing by the nature of substituent placed at the linking trimethylene chain (X = OH, OCH3, OCH2C6H5 and H respectively). A marked enhancement of the complex stability has been observed in the bis(crown) series I and attributed to participation of the lateral hydroxyl group in the sandwich complex formation. Evidence in support of the sandwich structure has been provided (i) by analysis of the potentiometric data indicating a 1:1 complex stoichiometry and (ii) by a comparison of the complex stability data from the bis(crown) series I with the corresponding values from related monocyclic ligand series V, VI and VII revealing a pronounced cooperation of both macrorings in the sodium ion-bis(crown) I complex formation.

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

Electronic structure and bonding of hydrogen in a screw dislocated bcc Fe

2001 ◽  
Vol 172 (1-2) ◽  
pp. 8-17 ◽  
Author(s):  
A. Juan ◽  
B. Irigoyen ◽  
S. Gesari
Keyword(s):  
Electronic Structure ◽  
Structure And Bonding

Electronic structure and bonding in titanium carbosulphide

2000 ◽  
Vol 80 (3) ◽  
pp. 379-394 ◽  
Author(s):  
Bala Ramalingam ◽  
Jan Vanek ◽  
J. M. Maclaren ◽  
M. E. Mchenry ◽  
W. M. Garrisonjr
Keyword(s):  
Electronic Structure ◽  
Structure And Bonding

Electronic Structure and Bonding Properties of the ZrO2/Ni Interface

2002 ◽  
Vol 224-226 ◽  
pp. 355-358 ◽  
Author(s):  
Xiaoping Han ◽  
Yao Zhang ◽  
Sheng Kai Gong ◽  
Hui Bin Xu
Keyword(s):  
Electronic Structure ◽  
Bonding Properties ◽  
Structure And Bonding

Electronic structure and bonding in CaH2: Experiment and theory

1984 ◽  
Vol 51 (10) ◽  
pp. 805-808 ◽  
Author(s):  
J.H. Weaver ◽  
M. Gupta ◽  
D.T. Peterson
Keyword(s):  
Electronic Structure ◽  
Structure And Bonding
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