Layered perovskite LiEuTiO4 as a 0.8 V lithium intercalation electrode

2017 ◽  
Vol 53 (55) ◽  
pp. 7800-7803 ◽  
Author(s):  
Jun Huang ◽  
Kaihua Yang ◽  
Zhengxi Zhang ◽  
Li Yang ◽  
Shin-ichi Hirano
Keyword(s):  
Energy Density ◽  
Lithium Intercalation ◽  
Layered Perovskite ◽  
Potential Plateau

Lithium intercalation into LiEuTiO4 with a 0.8 V potential plateau considering both the energy density and tolerance of lithium plating.

Superconductivity of Layered Perovskite Synthesized by Soft Chemistry

2007 ◽  
Vol 350 ◽  
pp. 163-166
Author(s):  
Takashi Teranishi ◽  
Sachi Takezawa ◽  
Kenji Toda ◽  
Hironori Ishikawa ◽  
Kenji Sato ◽  
...  
Keyword(s):  
Magnetic Susceptibility ◽  
Ion Exchange ◽  
Sodium Azide ◽  
Parent Compound ◽  
Intercalation Compound ◽  
Type Structure ◽  
Lithium Intercalation ◽  
Layered Perovskite ◽  
Soft Chemistry ◽  
Intercalation Reaction

Reduced niobates, MLixCa2Nb3O10 (M = Rb, K and Na) and KNaxCa2Nb3O10 were synthesized by intercalation reaction with n-butyllithium or sodium azide. Ruddlesden-Popper type structure of sodium intercalation compound, KNaCa2Nb3O10, differ from that of the parent compound and lithium intercalation compound, KLiCa2Nb3O10. The magnetic susceptibility measurements showed that the sodium intercalation compound became superconductor with transition temperatures below 3.5 K. New lithium intercalation compound Na0.1Li0.8Ca2.45Nb3O10, for an ion exchange compound, Na0.1Ca2.45Nb3O10, with KCa2Nb3O10 type structure show the diamagnetic signals below 5 K.

Structural Change in Lithium Intercalation of Layered Perovskite LiLaNb2O7

1994 ◽  
Vol 23 (1) ◽  
pp. 161-164 ◽  
Author(s):  
Mineo Sato ◽  
Tetsuro Jin ◽  
Hirokazu Ueda
Keyword(s):  
Structural Change ◽  
Lithium Intercalation ◽  
Layered Perovskite

Fine-scale taxonomic and temporal variability in the energy density of invertebrate prey of juvenile Chinook salmon Oncorhynchus tshawytscha

2020 ◽  
Vol 655 ◽  
pp. 185-198
Author(s):  
J Weil ◽  
WDP Duguid ◽  
F Juanes
Keyword(s):  
Energy Density ◽  
Chinook Salmon ◽  
Temporal Variability ◽  
Energy Content ◽  
Single Point ◽  
Single Species ◽  
Fine Scale ◽  
Temporal Differences ◽  
Juvenile Chinook Salmon ◽  
Juvenile Chinook

Variation in the energy content of prey can drive the diet choice, growth and ultimate survival of consumers. In Pacific salmon species, obtaining sufficient energy for rapid growth during early marine residence is hypothesized to reduce the risk of size-selective mortality. In order to determine the energetic benefit of feeding choices for individuals, accurate estimates of energy density (ED) across prey groups are required. Frequently, a single species is assumed to be representative of a larger taxonomic group or related species. Further, single-point estimates are often assumed to be representative of a group across seasons, despite temporal variability. To test the validity of these practices, we sampled zooplankton prey of juvenile Chinook salmon to investigate fine-scale taxonomic and temporal differences in ED. Using a recently developed model to estimate the ED of organisms using percent ash-free dry weight, we compared energy content of several groups that are typically grouped together in growth studies. Decapod megalopae were more energy rich than zoeae and showed family-level variability in ED. Amphipods showed significant species-level variability in ED. Temporal differences were observed, but patterns were not consistent among groups. Bioenergetic model simulations showed that growth rate of juvenile Chinook salmon was almost identical when prey ED values were calculated on a fine scale or on a taxon-averaged coarse scale. However, single-species representative calculations of prey ED yielded highly variable output in growth depending on the representative species used. These results suggest that the latter approach may yield significantly biased results.

A HIGH ENERGY DENSITY ZINC/OXYGEN BATTERY SYSTEM

1966 ◽  
Author(s):  
S. CHODOSH ◽  
E. KATSOULIS ◽  
M. ROSANSKY
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Battery System

Superionic Lithium Intercalation through 2 nm x 2 nm Columns in the Crystallographic Shear Phase Nb18W8O69

2019 ◽  
Author(s):  
Kent Griffith ◽  
Clare Grey
Keyword(s):  
High Performance ◽  
Rate Capability ◽  
Block Size ◽  
Lithium Intercalation ◽  
Resonance Spectroscopy ◽  
Complex Metal Oxides ◽  
Battery Electrode ◽  
Crystallographic Shear ◽  
Battery Material ◽  
First Time

Nb18W8O69 (9Nb2O5×8WO3) is the tungsten-rich end-member of the Wadsley–Roth crystallographic shear (cs) structures within the Nb2O5–WO3 series. It has the largest block size of any known, stable Wadsley–Roth phase, comprising 5 ´ 5 units of corner-shared MO6 octahedra between the shear planes, giving rise to 2 nm ´ 2 nm blocks. Rapid lithium intercalation is observed in this new candidate battery material and 7Li pulsed field gradient nuclear magnetic resonance spectroscopy – measured in a battery electrode for the first time at room temperature – reveals superionic lithium conductivity. In addition to its promising rate capability, Nb18W8O69 adds a piece to the larger picture of our understanding of high-performance Wadsley–Roth complex metal oxides.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

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