Aggregation-induced emission in precursors to porous molecular crystals

2017 ◽  
Vol 53 (72) ◽  
pp. 10022-10025 ◽  
Author(s):  
Zhenglin Zhang ◽  
Mohamed I. Hashim ◽  
Ognjen Š. Miljanić
Keyword(s):  
Solid State ◽  
Molecular Crystals ◽  
Aggregation Induced Emission ◽  
Emission Behavior ◽  
Solid State Fluorescence

Trigonal fluorinated pyrazoles assemble into porous molecular crystals and show solid-state fluorescence. However, their emission behavior in solution is dramatically different.

Carbazole-modified thiazolo[3,2-c][1,3,5,2]oxadiazaborinines exhibiting aggregation-induced emission and mechanofluorochromism

2021 ◽  
Author(s):  
Mykhaylo A. Potopnyk ◽  
Mykola Kravets ◽  
Roman Luboradzki ◽  
Dmytro Volyniuk ◽  
Volodymyr Sashuk ◽  
...  
Keyword(s):  
Solid State ◽  
Fluorescence Properties ◽  
Aggregation Induced Emission ◽  
Donor Acceptor ◽  
Solid State Fluorescence ◽  
Active Donor

Two novel AIE-active donor–acceptor organoboron complexes with a carbazole donor unit are developed and their morphology-dependent solid-state fluorescence properties are established.

Strategy to enhance solid-state fluorescence and aggregation-induced emission enhancement effect in pyrimidine boron complexes

2015 ◽  
Vol 44 (7) ◽  
pp. 3326-3341 ◽  
Author(s):  
Yasuhiro Kubota ◽  
Kouhei Kasatani ◽  
Hiroki Takai ◽  
Kazumasa Funabiki ◽  
Masaki Matsui
Keyword(s):  
Solid State ◽  
Enhancement Effect ◽  
Strong Fluorescence ◽  
Aggregation Induced Emission ◽  
Emission Enhancement ◽  
Boron Complexes ◽  
Solid State Fluorescence

Although non-, trifluoromethyl-, and cyano-substituted derivatives showed AIEE effects, methoxy- and dimethylamino-substituted analogues resulted in relatively strong fluorescence in solution.

Similar and Different: Effect of Substitution Pattern on the Aggregation-Induced Emission Property of [4'-(bisphenylamino)[1,1']biphenyl]methylene Fluorenes

2013 ◽  
Vol 859 ◽  
pp. 329-332
Author(s):  
Zhi Chen ◽  
Yi Long Xie ◽  
Jin Xing Qiu ◽  
Zhong He Chen
Keyword(s):  
Solid State ◽  
Optical Property ◽  
Quantum Yield ◽  
Suzuki Coupling ◽  
Emission Property ◽  
Aggregate State ◽  
Substitution Pattern ◽  
Aggregation Induced Emission ◽  
Emission Behavior ◽  
Fluorescent Quantum Yield

Three isomers, [4'-(bisphenylamino)[1,1']biphen-2-yl]methylenefluorene (BAB2MF), [4'-(bisphenylamino)[1,1']biphen-3-yl]methylenefluorene (BAB3MF) and [4'-(bisphenylamino)[1,1']biphen-4-yl]methylenefluorene (BAB4MF), were synthesized through Suzuki coupling. The substitution pattern exerts a dramatic influence on the optical property. BAB3MF and BAB4MF are hardly emissive either in the solution or as solid state. On the contrary, BAB2MF emits strongly, especially in the aggregate state with a high fluorescent quantum yield of 69%. Furthermore, BAB2MF shows an aggregation-induced enhanced emission behavior. BAB2MF solid emits at 488 nm, about 60 nm blue-shifted from its solution.

Rational design of reversibly photochromic molecules with aggregation-induced emission by introducing photoactive thienyl and benzothienyl groups

2020 ◽  
Vol 8 (38) ◽  
pp. 13197-13204 ◽  
Author(s):  
Shasha Zhou ◽  
Sidan Guo ◽  
Weidong Liu ◽  
Qiaoying Yang ◽  
Huili Sun ◽  
...  
Keyword(s):  
Solid State ◽  
Rational Design ◽  
General Strategy ◽  
Aggregation Induced Emission ◽  
Photochromic Molecules ◽  
Solid State Fluorescence ◽  
Molecular Skeleton

A general strategy to design reversible photochromic molecules with solid-state fluorescence by introducing photoactive thienyl and benzothienyl groups into an AIE-active molecular skeleton was proposed.

Photophysical properties of some novel tetraphenylimidazole derived BODIPY based fluorescent molecular rotors

2020 ◽  
Vol 49 (2) ◽  
pp. 438-452 ◽  
Author(s):  
Bhupendra Kumar Dwivedi ◽  
Vishwa Deepak Singh ◽  
Yogesh Kumar ◽  
Daya Shankar Pandey
Keyword(s):  
Solid State ◽  
Photophysical Properties ◽  
Molecular Rotors ◽  
Aggregation Induced Emission ◽  
Fluorescent Molecular Rotors ◽  
Solid State Fluorescence

In this work, we present tetraphenylimidazole-based BODIPYs (HPIB1–HPIB4) as fluorescent molecular rotors exhibiting aggregation induced emission, solid state fluorescence and appreciable sensitivity towards viscosity.

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