Mixed Cu(i)/Au(i) coordination polymers as reversible turn-on vapoluminescent sensors for volatile thioethers

2017 ◽  
Vol 53 (48) ◽  
pp. 6500-6503 ◽  
Author(s):  
Bryton R. Varju ◽  
Jeffrey S. Ovens ◽  
Daniel B. Leznoff

Cu(i)-doping transforms an inactive Cu(i)/Au(i) coordination polymer into an emissive, reversible solid state sensor for dimethyl- and diethyl sulphide.

CrystEngComm ◽  
2020 ◽  
Vol 22 (5) ◽  
pp. 888-894 ◽  
Author(s):  
Ashkan Kianimehr ◽  
Kamran Akhbari ◽  
Jonathan White ◽  
Anukorn Phuruangrat

Two new Na and K coordination polymers with halogen bond, metallophilic and hydrogen bonding interactions were synthesized. These two compounds were synthesized sonochemically and solid-state conversions of them to each other were investigated.


CrystEngComm ◽  
2015 ◽  
Vol 17 (8) ◽  
pp. 1839-1847 ◽  
Author(s):  
Meng Kang ◽  
Guo-Ping Yang ◽  
Lei Hou ◽  
Wei-Ping Wu ◽  
Yun-Long Wu ◽  
...  

Four multi-dimensional nickel-based coordination polymers have been prepared, and their solvent-mediated and solid-state structural transformations have been observed and studied systematically.


RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17265-17267 ◽  
Author(s):  
Lida Hashemi ◽  
Ali Morsali

Reversible anion-exchange of 2D lead(ii) coordination polymers from [Pb(4-bpdb)Br2]n (1) to [Pb(4-bpdb)Cl2]n (2) by solid state anion-replacement has been studied.


2018 ◽  
Vol 54 (76) ◽  
pp. 10695-10697 ◽  
Author(s):  
Yasuchika Hasegawa ◽  
Yui Miura ◽  
Yuichi Kitagawa ◽  
Satoshi Wada ◽  
Takayuki Nakanishi ◽  
...  

A spiral-type chiral Eu(iii) coordination polymer showed strong luminescence, effective CD and CPL properties compared with a mono-nuclear chiral Eu(iii) complex in the solid state.


2020 ◽  
Vol 49 (31) ◽  
pp. 10858-10865 ◽  
Author(s):  
Fei-Long Hu ◽  
Zhen Qin ◽  
Meng-Fan Wang ◽  
Xue Wan Kang ◽  
Yong-Li Qin ◽  
...  

Two isomeric photoproducts are regioselectively obtained by [2 + 2] cycloaddition of 1,4-bis[2-(4-pyridyl)ethenyl]-benzene within different coordination polymers.


RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 100743-100747 ◽  
Author(s):  
Baoxia Liu ◽  
Yankai Huang ◽  
Qi Shen ◽  
Xu Zhu ◽  
Yuanqiang Hao ◽  
...  

Metal–organic coordination polymers (MOCPs) have emerged as a new family of functional nanomaterials.


2018 ◽  
Vol 61 (4) ◽  
Author(s):  
Rupinder Kaur ◽  
Manmohan Chhibber ◽  
Partha Mahata ◽  
Susheel K. Mittal

The fluorescent properties of a coordination polymer (CP), <strong>1</strong>, were used as turn-on and turn-off detector for nitroaromatics and organophosporus pesticides respectively. Compound 1 exhibits exceptionally high efficiency for the detection of 2,4,6-trinitrophenol (TNP) through luminescence quenching with a quenching constant [KSV] value of 2.30 X 10<sup>5</sup> M<sup>-1</sup>, highest among the known coordination polymers. Minimum detection limit achieved by the proposed method was 43 ppb. This emission property of <strong>1</strong> was also used successfully to detect triazophos and chlorpyrifos, aromatic organophosphorus pesticides, which enhanced the emission intensity by 238% and a red shift of ~70 nm in case of former. Non aromatic pesticides like malathion and acephate did not show any increase in the emission intensity. Minimum detection limits for triazophos and chlorpyrifos, aromatic organophosphorus pesticides, were 0.6 and 0.7 ppm respectively.


2018 ◽  
Vol 79 ◽  
pp. 255-258 ◽  
Author(s):  
Mehboobali Pannipara ◽  
Abdullah G. Al-Sehemi ◽  
Mohammed Assiri ◽  
Abul Kalam

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