Amorphous–amorphous transition in a porous coordination polymer

2017 ◽  
Vol 53 (52) ◽  
pp. 7060-7063 ◽  
Author(s):  
Hiroyoshi Ohtsu ◽  
Thomas D. Bennett ◽  
Tatsuhiro Kojima ◽  
David A. Keen ◽  
Yasuhiro Niwa ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Coordination Polymer ◽  
Metal Organic Framework ◽  
Amorphous State ◽  
Metal Organic ◽  
Porous Coordination Polymer ◽  
Organic Framework

The amorphous state plays a key role in porous coordination polymer and metal–organic framework phase transitions.

scholarly journals Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

2018 ◽  
Vol 19 (1) ◽  
pp. 506-512 ◽  
Author(s):  
Sylvia L. Hanna ◽  
Xuan Zhang ◽  
Ken-ichi Otake ◽  
Riki J. Drout ◽  
Peng Li ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Crystal Phase ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

Magnetic behavior of the metal organic framework [(CH3)2NH2]Co(HCOO)3

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37818-37822 ◽  
Author(s):  
K. Vinod ◽  
C. S. Deepak ◽  
Shilpam Sharma ◽  
D. Sornadurai ◽  
A. T. Satya ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Phase Transitions ◽  
Specific Heat ◽  
Single Crystals ◽  
Metal Organic Framework ◽  
Magnetic Behavior ◽  
Metal Organic ◽  
Organic Framework

In this study we examine the phase transitions in single crystals of [(CH3)2NH2]Co(HCOO)3, using magnetization and specific heat measurements as a function of temperature and magnetic field.

Double-Keggin-type Anion-templated Synthesis of a 3D Porous Coordination Polymer of Eu(III) Ions and dpdo Ligands

2008 ◽  
Vol 63 (3) ◽  
pp. 255-260 ◽  
Author(s):  
Mei Lin Wei ◽  
Rui Ping Sun ◽  
Kai Jiang
Keyword(s):  
Coordination Polymer ◽  
Self Assembly ◽  
Water Solution ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Keggin Type ◽  
Keggin Anions ◽  
Metal Organic ◽  
Porous Coordination Polymer

A porous coordination polymer, {[Eu(dpdo)4(H2O)3]H(SiMo12O40)(dpdo)0.5(CH3CN)0.5(H2O)4}n (1), (where dpdo is 4,4′-bipyridine-N,N′-dioxide) templated by double-Keggin-type polyanions has been synthesized through the self-assembly of Eu(III) ions and dpdo in acetonitrile/water solution and structurally characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. The X-ray structure analysis reveals that compound 1 exhibits a 3D non-interwoven framework with large cavities housing centro-symmetrically related shoulder-by-shoulder double-Keggin anions as guests. The result of a thermogravimetric analysis suggests that the metal-organic framework has high thermal stability.

A 2-D Metal–Organic Framework Based on Linear Trinuclear Copper Cluster Units: Syntheses, Structures and Magnetic Properties

2018 ◽  
Vol 42 (4) ◽  
pp. 198-201 ◽  
Author(s):  
Liping Wang ◽  
Erpeng Zhang ◽  
Xiaoli Zhou ◽  
Yufei Wang ◽  
Yanli Liu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Metal Organic Framework ◽  
Copper Cluster ◽  
X Ray Diffraction ◽  
X Ray ◽  
Metal Organic ◽  
Organic Framework

The coordination polymer [Cu3(tci)2(phen)2] n (H3tci = 1,3,5-tris(2-carboxyethyl)isocyanurate; phen = 1,10-phenanthroline) has been synthesised. Single-crystal X-ray diffraction studies have shown that the polymer displays a 2-D metal–organic framework based on linear trinuclear copper cluster units, and its magnetic properties indicate antiferromagnetic interactions.

Probing Time Dependent Phase Transformation in a Flexible Metal-Organic Framework with Nanoindentation

2021 ◽  
Author(s):  
Prakash Kanoo ◽  
Manish Kumar Mishra ◽  
Arpan Hazra
Keyword(s):  
Phase Transformation ◽  
Phase Transitions ◽  
Room Temperature ◽  
Metal Organic Framework ◽  
Time Dependent ◽  
Guest Molecules ◽  
Nanoindentation Technique ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Phase transformation in a flexible metal-organic framework, {[Zn4(1,4-NDC)4(1,2-BPE)2]•xSolvent}n, which loses guest molecules rapidly at room temperature, leading to several phase transitions, is examined using nanoindentation technique. Nanoindentation results reveal time...

Ultrasound-driven preparation and pair distribution function-assisted structure solution of a copper-based layered coordination polymer

2014 ◽  
Vol 43 (27) ◽  
pp. 10438-10442 ◽  
Author(s):  
M. Infas Mohideen ◽  
Phoebe K. Allan ◽  
Karena W. Chapman ◽  
Joseph A. Hriljac ◽  
Russell E. Morris
Keyword(s):  
Distribution Function ◽  
Coordination Polymer ◽  
Polymer Material ◽  
Pair Distribution Function ◽  
Function Analysis ◽  
Metal Organic Framework ◽  
Ultrasound Treatment ◽  
Structure Solution ◽  
Metal Organic ◽  
Organic Framework

Pair distribution function analysis has been used to solve the structure of a coordination polymer material formed by ultrasound treatment of a metal–organic framework.

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