Copper nanoparticles socketed in situ into copper phyllosilicate nanotubes with enhanced performance for chemoselective hydrogenation of esters

2017 ◽  
Vol 53 (51) ◽  
pp. 6933-6936 ◽  
Author(s):  
Xiaoxiao Gong ◽  
Meiling Wang ◽  
Huihuang Fang ◽  
Xiaoqi Qian ◽  
Linmin Ye ◽  
...  

Copper nanoparticles exsoluted in situ under a reducing atmosphere at elevated temperatures are socketed into the parent copper phyllosilicate nanotubes and exhibit excellent catalytic performance and superior stability for the selective hydrogenation of various esters to alcohols.

Nano Energy ◽  
2016 ◽  
Vol 26 ◽  
pp. 699-707 ◽  
Author(s):  
Shouliang Wu ◽  
Jun Liu ◽  
Dewei Liang ◽  
Hongmei Sun ◽  
Yixing Ye ◽  
...  

2016 ◽  
Vol 1 (1) ◽  
pp. 41-44 ◽  
Author(s):  
Anthony Vasileff ◽  
Sheng Chen ◽  
Shi Zhang Qiao

Nitrogen doped graphene hydrogel electrocatalysts with in situ deposited cobalt phosphate demonstrated excellent catalytic performance toward oxygen evolution in a neutral electrolyte.


RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 29042-29049 ◽  
Author(s):  
Guanzhi Cheng ◽  
Xinyi Huang ◽  
Hong Zhang ◽  
Yang Hu ◽  
Chengyou Kan

P(St-co-MAA)/CeO2 composites microspheres were fabricated by a novel and facile approach, exhibiting excellent catalytic performance in oxidative degradation.


2018 ◽  
Vol 47 (42) ◽  
pp. 15189-15196 ◽  
Author(s):  
Qun Liu ◽  
Xiaodan Hong ◽  
Xin Zhang ◽  
Xingyan You ◽  
Xin Zhao ◽  
...  

Hierarchical structured Cu2S nanorods with monoclinic and hexagonal crystal phases are in situ grown on copper sheets, showing remarkable electrochemical activity in supercapacitors and excellent catalytic performance in photocatalysis.


2019 ◽  
Vol 43 (46) ◽  
pp. 18120-18125 ◽  
Author(s):  
Ningmeng Hu ◽  
Chenghuan Yang ◽  
Liang He ◽  
Qingqing Guan ◽  
Rongrong Miao

Employing in situ DRIFTS spectra have successfully elucidated the reaction mechanism of Ni&Cu-NP/γ-Al2O3 catalyzed C2H2 semihydrogenation reaction.


Nanomaterials ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 7 ◽  
Author(s):  
Noelia Losada-Garcia ◽  
Alba Rodriguez-Otero ◽  
Jose M. Palomo

Copper nanoparticles–enzyme biohybrid is a promising material for the remediation of contaminated waters, but its function is influenced by its effect on degradation organic pollutants. This study is the first investigation into the fast degradation of a high amount of Bisphenol A (BPA) in water at neutral pH and room temperature. Four different CuNPs biohybrids with different cu species and nanoparticle sizes were used as catalysts. The biohybrid CuNPs@CALB-3, which contained Cu2O nanoparticles of around 10 nm size, showed excellent catalytic performance removing >95% BPA content (45 ppm) in an aqueous solution in 20 min in the presence of hydrogen peroxide at pH 8 using 1.5 g/L of a catalyst. The catalyst showed excellent stability and recyclability at these conditions.


Nanoscale ◽  
2014 ◽  
Vol 6 (12) ◽  
pp. 7025-7032 ◽  
Author(s):  
Shenghuan Zhang ◽  
Shili Gai ◽  
Fei He ◽  
Yunlu Dai ◽  
Peng Gao ◽  
...  

Uniform Ni/SiO2 magnetic hollow microspheres were prepared by an in situ thermal decomposition and reduction route. Tiny Au nanoparticles (5 nm) were linked to Ni/SiO2 microspheres. The as-prepared Ni/SiO2@Au catalysts exhibited excellent catalytic activity for 4-nitrophenol reduction.


2013 ◽  
Vol 458 ◽  
pp. 11-20 ◽  
Author(s):  
Xinwei Li ◽  
Hongxing Dai ◽  
Jiguang Deng ◽  
Yuxi Liu ◽  
Zhenxuan Zhao ◽  
...  

2017 ◽  
Vol 50 ◽  
pp. 72-77
Author(s):  
Xiao Fei Niu ◽  
Fu Rong Tu

The almost monodisperse cobble-like CeO2 nanostructures with many pores and a diameter of 50-100 nm have been successfully synthesized by a smart hydrothermal route. XRD, SEM, XPS, BET, and in situ DRIFT were employed to characterize the samples. The results showed that the cobble-like CeO2 owned a fluorite cubic structure and there are Ce3+ ions and oxygen vacancies in surface of samples. Its catalytic activity was investigated by selective catalytic reduction of NOx with NH3. The results showed that cobble-like CeO2 nanostructures exhibit excellent catalytic performance, which can be attributed to the much larger surface areas, novel morphology and the best redox behaviour of surface oxygen on the CeO2 surface.


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