[FeFe] Hydrogenase active site model chemistry in a UiO-66 metal–organic framework

Sonja Pullen; Souvik Roy; Sascha Ott

doi:10.1039/c7cc01620d

[FeFe] Hydrogenase active site model chemistry in a UiO-66 metal–organic framework

Chemical Communications ◽

10.1039/c7cc01620d ◽

2017 ◽

Vol 53 (37) ◽

pp. 5227-5230 ◽

Cited By ~ 11

Author(s):

Sonja Pullen ◽

Souvik Roy ◽

Sascha Ott

Keyword(s):

Active Site ◽

Ligand Exchange ◽

Metal Organic Framework ◽

Phosphine Ligand ◽

Exchange Reactions ◽

Site Model ◽

Active Site Model ◽

Metal Organic ◽

Organic Framework

CO→phosphine ligand exchange reactions on [FeFe(dcbdt)(CO)6] incorporated in UiO-66(Zr) afford selectively the disubstituted UiO-66–[FeFe(dcbdt)(CO)4(PX3)2] which can be protonated quantitatively to afford the bridging hydride UiO-66–[FeFe(dcbdt)(μ-H)(CO)4(PX3)2].

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Enhancing the peroxidase-like activity of MIL-88B by ligand exchange with polydopamine

Dalton Transactions ◽

10.1039/d1dt03832j ◽

2022 ◽

Author(s):

Changzhi Hu ◽

Yuhao Xiong ◽

Ling Liang ◽

Weiyuan Zuo ◽

Fanggui Ye ◽

...

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Active Surfaces ◽

Metal Organic ◽

Organic Framework

Metal-organic framework (MOF) as nanozymes has been widely used in biosensing. However, MOF has inherent defects of easy agglomeration, leading to stacking of active surfaces. In addition, the low conductivity...

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Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66

Chemistry of Materials ◽

10.1021/acs.chemmater.6b02749 ◽

2016 ◽

Vol 28 (20) ◽

pp. 7190-7193 ◽

Cited By ~ 88

Author(s):

Greig C. Shearer ◽

Jenny G. Vitillo ◽

Silvia Bordiga ◽

Stian Svelle ◽

Unni Olsbye ◽

...

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Metal Organic ◽

Organic Framework

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Surface‐Deactivated Core–Shell Metal–Organic Framework by Simple Ligand Exchange for Enhanced Size Discrimination in Aerobic Oxidation of Alcohols

Chemistry - A European Journal ◽

10.1002/chem.202000933 ◽

2020 ◽

Vol 26 (34) ◽

pp. 7568-7572 ◽

Cited By ~ 8

Author(s):

Seongwoo Kim ◽

Jooyeon Lee ◽

Sungeun Jeoung ◽

Hoi Ri Moon ◽

Min Kim

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Aerobic Oxidation ◽

Core Shell ◽

Size Discrimination ◽

Oxidation Of Alcohols ◽

Metal Organic ◽

Organic Framework

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Active-Site Modulation in an Fe-Porphyrin-Based Metal–Organic Framework through Ligand Axial Coordination: Accelerating Electrocatalysis and Charge-Transport Kinetics

Journal of the American Chemical Society ◽

10.1021/jacs.9b11355 ◽

2020 ◽

Vol 142 (4) ◽

pp. 1933-1940 ◽

Cited By ~ 19

Author(s):

Itamar Liberman ◽

Ran Shimoni ◽

Raya Ifraemov ◽

Illya Rozenberg ◽

Chanderpratap Singh ◽

...

Keyword(s):

Charge Transport ◽

Active Site ◽

Metal Organic Framework ◽

Transport Kinetics ◽

Axial Coordination ◽

Metal Organic ◽

Organic Framework

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Orthogonal Ternary Functionalization of a Mesoporous Metal–Organic Framework via Sequential Postsynthetic Ligand Exchange

Journal of the American Chemical Society ◽

10.1021/jacs.5b06780 ◽

2015 ◽

Vol 137 (33) ◽

pp. 10508-10511 ◽

Cited By ~ 62

Author(s):

Chong Liu ◽

Tian-Yi Luo ◽

Evan S. Feura ◽

Chen Zhang ◽

Nathaniel L. Rosi

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Metal Organic ◽

Mesoporous Metal ◽

Organic Framework

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Cover Feature: Surface‐Deactivated Core–Shell Metal–Organic Framework by Simple Ligand Exchange for Enhanced Size Discrimination in Aerobic Oxidation of Alcohols (Chem. Eur. J. 34/2020)

Chemistry - A European Journal ◽

10.1002/chem.202001526 ◽

2020 ◽

Vol 26 (34) ◽

pp. 7514-7514 ◽

Cited By ~ 1

Author(s):

Seongwoo Kim ◽

Jooyeon Lee ◽

Sungeun Jeoung ◽

Hoi Ri Moon ◽

Min Kim

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Aerobic Oxidation ◽

Core Shell ◽

Size Discrimination ◽

Oxidation Of Alcohols ◽

Metal Organic ◽

Organic Framework

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In Situ Generation of an N‐Heterocyclic Carbene Functionalized Metal–Organic Framework by Postsynthetic Ligand Exchange: Efficient and Selective Hydrosilylation of CO 2

Angewandte Chemie International Edition ◽

10.1002/anie.201813064 ◽

2019 ◽

Vol 58 (9) ◽

pp. 2844-2849 ◽

Cited By ~ 26

Author(s):

Xu Zhang ◽

Jiao Sun ◽

Guangfeng Wei ◽

Zhipan Liu ◽

Huimin Yang ◽

...

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Metal Organic ◽

In Situ Generation ◽

Organic Framework

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Reversible Ligand Exchange in a Metal–Organic Framework (MOF): Toward MOF-Based Dynamic Combinatorial Chemical Systems

The Journal of Physical Chemistry A ◽

10.1021/jp401039k ◽

2013 ◽

Vol 117 (18) ◽

pp. 3771-3776 ◽

Cited By ~ 48

Author(s):

Adam F. Gross ◽

Elena Sherman ◽

Sky L. Mahoney ◽

John J. Vajo

Keyword(s):

Ligand Exchange ◽

Metal Organic Framework ◽

Chemical Systems ◽

Metal Organic ◽

Organic Framework

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Mimicking the Electron Transport Chain and Active Site of [FeFe] Hydrogenases in One Metal–Organic Framework: Factors That Influence Charge Transport

Journal of the American Chemical Society ◽

10.1021/jacs.1c01361 ◽

2021 ◽

Author(s):

Ashleigh T. Castner ◽

Ben A. Johnson ◽

Seth M. Cohen ◽

Sascha Ott

Keyword(s):

Electron Transport ◽

Charge Transport ◽

Active Site ◽

Electron Transport Chain ◽

Metal Organic Framework ◽

Transport Chain ◽

Metal Organic ◽

Organic Framework

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Functionalization of robust Zr(iv)-based metal–organic framework films via a postsynthetic ligand exchange

Chemical Communications ◽

10.1039/c4cc08218d ◽

2015 ◽

Vol 51 (1) ◽

pp. 66-69 ◽

Cited By ~ 81

Author(s):

Honghan Fei ◽

Sonja Pullen ◽

Andreas Wagner ◽

Sascha Ott ◽

Seth M. Cohen

Keyword(s):

Glass Substrate ◽

Ligand Exchange ◽

Metal Organic Framework ◽

High Crystallinity ◽

Conductive Glass ◽

Metal Organic ◽

Organic Framework

A facile and efficient fabrication approach for homogeneous, crack-free UiO-66 films with exceptionally high crystallinity and tunable thickness on a transparent and conductive glass substrate is reported.

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