scholarly journals Nontoxic organic solvents identified using an a priori approach with Hansen solubility parameters

2017 ◽  
Vol 53 (29) ◽  
pp. 4096-4099 ◽  
Author(s):  
Daisuke Nakamura ◽  
Minoru Hirano ◽  
Riichiro Ohta
Keyword(s):  
Organic Solvents ◽  
A Priori ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Hansen Solubility

Nontoxicity/cytotoxicity of organic solvents is determined using Hansen solubility parameters.

Solubility of Oxygen in Organic Solvents and Calculation of the Hansen Solubility Parameters of Oxygen

2014 ◽  
Vol 53 (49) ◽  
pp. 19331-19337 ◽  
Author(s):  
Takashi Sato ◽  
Yuzo Hamada ◽  
Masaru Sumikawa ◽  
Sadao Araki ◽  
Hideki Yamamoto
Keyword(s):  
Organic Solvents ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Solubility Of Oxygen ◽  
Hansen Solubility

scholarly journals Solvent Effects on Gelation Behavior of the Organogelator Based on L-Phenylalanine Dihydrazide Derivatives

Materials ◽  
2019 ◽  
Vol 12 (12) ◽  
pp. 1890 ◽  
Author(s):  
Yang Yu ◽  
Ning Chu ◽  
Qiaode Pan ◽  
Miaomiao Zhou ◽  
Sheng Qiao ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Self Assembly ◽  
Solubility Parameters ◽  
Ordered Structure ◽  
Hansen Solubility Parameters ◽  
Nmr Studies ◽  
Low Concentrations ◽  
Gelation Behavior ◽  
Hoff Equation ◽  
Hansen Solubility

A series of organogelators based on L-phenylalanine has been synthesized and their gelation properties in various organic solvents were investigated. The results showed that these organogelators were capable of forming stable thermal and reversible organogels in various organic solvents at low concentrations, and the critical gel concentration (CGC) of certain solvents was less than 1.0 wt%. Afterward, the corresponding enthalpies (ΔHg) were extracted by using the van ’t Hoff equation, as the gel–sol temperature (TGS) was the function of the gelator concentration. The study of gelling behaviors suggested that L-phenylalanine dihydrazide derivatives were excellent gelators in solvents, especially BOC–Phe–OdHz (compound 4). The effects of the solvent on the self-assembly of gelators were analyzed by the Kamlet–Taft model, and the gelation ability of compound 4 in a certain organic solvent was described by Hansen solubility parameters and a Teas plot. Morphological investigation proved that the L-phenylalanine dihydrazide derivatives could assemble themselves into an ordered structure such as a fiber or sheet. Fourier-transform infrared spectroscopy (FTIR) and hydrogen nuclear magnetic resonance (1H NMR) studies indicated that hydrogen bonding, π–π stacking, and van der Waals forces played important roles in the formation of a gel.

Insights into organogelation and its kinetics from Hansen solubility parameters. Toward a priori predictions of molecular gelation

Soft Matter ◽  
2014 ◽  
Vol 10 (15) ◽  
pp. 2632 ◽  
Author(s):  
Kevin K. Diehn ◽  
Hyuntaek Oh ◽  
Reza Hashemipour ◽  
Richard G. Weiss ◽  
Srinivasa R. Raghavan
Keyword(s):  
A Priori ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Hansen Solubility

Measurement of Hansen Solubility Parameters of Third-Degree Burn Eschar

Burns ◽  
2021 ◽  
Author(s):  
Maryam Hosseini ◽  
Michael S. Roberts ◽  
Reza Aboofazeli ◽  
Hamid R. Moghimi
Keyword(s):  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Degree Burn ◽  
Hansen Solubility
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