An internal magnetic field strategy to reuse pulverized active materials for high performance: a magnetic three-dimensional ordered macroporous TiO2/CoPt/α-Fe2O3 nanocomposite anode

2017 ◽  
Vol 53 (38) ◽  
pp. 5298-5301 ◽  
Author(s):  
Yiping Tang ◽  
Liang Hong ◽  
Jiquan Li ◽  
Guangya Hou ◽  
Huazhen Cao ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Large Volume ◽  
High Performance ◽  
Three Dimensional ◽  
Reversible Capacity ◽  
Cyclic Stability ◽  
Active Materials ◽  
High Reversible Capacity ◽  
Ordered Macroporous ◽  
Large Volume Change

An internally magnetic field was established by CoPt for attracting pulverized ferromagnetic α-Fe2O3. Combining with the unique porous structure for accommodating large volume change, the TiO2/CoPt/α-Fe2O3 (3DOMTCF) anode demonstrated high reversible capacity and extremely promising cyclic stability.

Interpenetrating Gels as Conducting/Adhering Matrices Enabling High-Performance Silicon Anodes

2021 ◽  
Author(s):  
Tingting Xia ◽  
Chengfei Xu ◽  
Pengfei Dai ◽  
Xiaoyun Li ◽  
Riming Lin ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Performance ◽  
Electrode Materials ◽  
Three Dimensional ◽  
Electrochemical Energy Storage ◽  
Active Materials ◽  
Silicon Anodes ◽  
Weak Binding ◽  
Binding Forces

Three-dimensional (3D) conductive polymers are promising conductive matrices for electrode materials toward electrochemical energy storage. However, their fragile nature and weak binding forces with active materials could not guarantee long-term...

Scalable synthesis of Na2MVF7 (M = Mn, Fe, and Co) as high-performance cathode materials for sodium-ion batteries

2021 ◽  
Author(s):  
Jiaying Liao ◽  
Jingchen Han ◽  
Jianzhi Xu ◽  
Yichen Du ◽  
Yingying Sun ◽  
...  
Keyword(s):  
Cathode Materials ◽  
High Performance ◽  
Reversible Capacity ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
High Reversible Capacity ◽  
Scalable Synthesis

We demonstrate an economical polytetrafluoroethylene-assisted fluorination method to synthesize three binary sodium-rich fluorides Na2MVF7 (M = Mn, Fe, and Co). The optimal Na2FeVF7 cathode delivers a high reversible capacity of...

scholarly journals Synthesis of Si/Fe2O3-Anchored rGO Frameworks as High-Performance Anodes for Li-Ion Batteries

2021 ◽  
Vol 22 (20) ◽  
pp. 11041
Author(s):  
Yajing Yan ◽  
Yanxu Chen ◽  
Yongyan Li ◽  
Xiaoyu Wu ◽  
Chao Jin ◽  
...  
Keyword(s):  
High Performance ◽  
Melt Spinning ◽  
Three Dimensional ◽  
High Capacity ◽  
Reversible Capacity ◽  
High Energy ◽  
High Specific Surface Area ◽  
High Energy Density ◽  
Active Components ◽  
Li Ion

By virtue of the high theoretical capacity of Si, Si-related materials have been developed as promising anode candidates for high-energy-density batteries. During repeated charge/discharge cycling, however, severe volumetric variation induces the pulverization and peeling of active components, causing rapid capacity decay and even development stagnation in high-capacity batteries. In this study, the Si/Fe2O3-anchored rGO framework was prepared by introducing ball milling into a melt spinning and dealloying process. As the Li-ion battery (LIB) anode, it presents a high reversible capacity of 1744.5 mAh g−1 at 200 mA g−1 after 200 cycles and 889.4 mAh g−1 at 5 A g−1 after 500 cycles. The outstanding electrochemical performance is due to the three-dimensional cross-linked porous framework with a high specific surface area, which is helpful to the transmission of ions and electrons. Moreover, with the cooperation of rGO, the volume expansion of Si is effectively alleviated, thus improving cycling stability. The work provides insights for the design and preparation of Si-based materials for high-performance LIB applications.

EXCELLENT CYCLING PERFORMANCE OF THREE-DIMENSIONAL-ORDERED MACROPOROUS NiFe2O4 AS ANODE MATERIAL FOR LITHIUM ION BATTERIES

2011 ◽  
Vol 04 (04) ◽  
pp. 327-331 ◽  
Author(s):  
TIANJING ZHANG ◽  
HUJUN CAO ◽  
JUANJUAN PENG ◽  
QIZHEN XIAO ◽  
ZHAOHUI LI ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Nickel Ferrite ◽  
Colloidal Crystal ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cyclic Voltammogram ◽  
Electrochemical Characteristics ◽  
Ordered Macroporous

Three-dimensional ordered macroporous (3DOM) nickel ferrite ( NiFe2O4 ) anode material is synthesized via colloidal crystal template. A Close-packed poly(methyl methacrylate) (PMMA) spheres is used as template. Scanning electron microscopy observations reveal that the obtained 3DOM NiFe2O4 material has uniform spherical macropores with diameter about 140-nm and 20-nm size walls. The cyclic voltammogram and galvanostatic test are employed to evaluate the electrochemical characteristics of the as-prepared NiFe2O4 . It shows high initial discharge capacity (up to 1370 mAh g-1) and reversible capacity of 670 mAh g-1 at the current density of 0.2 mA cm-2. The results suggest that 3DOM nickel ferrite is a good candidate for anode material of lithium ion batteries.

scholarly journals 3D Porous Ti3C2 MXene/NiCo-MOF Composites for Enhanced Lithium Storage

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 695 ◽  
Author(s):  
Yijun Liu ◽  
Ying He ◽  
Elif Vargun ◽  
Tomas Plachy ◽  
Petr Saha ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
High Current Density ◽  
Composite Films ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Energy Storage Devices ◽  
Lithium Storage ◽  
Hierarchical Porous

To improve Li storage capacity and the structural stability of Ti3C2 MXene-based electrode materials for lithium-ion batteries (LIBs), a facile strategy is developed to construct three-dimensional (3D) hierarchical porous Ti3C2/bimetal-organic framework (NiCo-MOF) nanoarchitectures as anodes for high-performance LIBs. 2D Ti3C2 nanosheets are coupled with NiCo-MOF nanoflakes induced by hydrogen bonds to form 3D Ti3C2/NiCo-MOF composite films through vacuum-assisted filtration technology. The morphology and electrochemical properties of Ti3C2/NiCo-MOF are influenced by the mass ratio of MOF to Ti3C2. Owing to the interconnected porous structures with a high specific surface area, rapid charge transfer process, and Li+ diffusion rate, the Ti3C2/NiCo-MOF-0.4 electrode delivers a high reversible capacity of 402 mAh g−1 at 0.1 A g−1 after 300 cycles; excellent rate performance (256 mAh g−1 at 1 A g−1); and long-term stability with a capacity retention of 85.7% even after 400 cycles at a high current density, much higher than pristine Ti3C2 MXene. The results highlight that Ti3C2/NiCo-MOF have great potential in the development of high-performance energy storage devices.

scholarly journals Supercooled liquid sulfur maintained in three-dimensional current collector for high-performance Li-S batteries

2020 ◽  
Vol 6 (21) ◽  
pp. eaay5098 ◽  
Author(s):  
Guangmin Zhou ◽  
Ankun Yang ◽  
Guoping Gao ◽  
Xiaoyun Yu ◽  
Jinwei Xu ◽  
...  
Keyword(s):  
High Performance ◽  
Critical Role ◽  
Three Dimensional ◽  
Current Collector ◽  
Reversible Capacity ◽  
Supercooled Liquid ◽  
High Energy ◽  
Liquid Sulfur ◽  
Sulfur Species ◽  
Solid Liquid

In lithium-sulfur (Li-S) chemistry, the electrically/ionically insulating nature of sulfur and Li2S leads to sluggish electron/ion transfer kinetics for sulfur species conversion. Sulfur and Li2S are recognized as solid at room temperature, and solid-liquid phase transitions are the limiting steps in Li-S batteries. Here, we visualize the distinct sulfur growth behaviors on Al, carbon, Ni current collectors and demonstrate that (i) liquid sulfur generated on Ni provides higher reversible capacity, faster kinetics, and better cycling life compared to solid sulfur; and (ii) Ni facilitates the phase transition (e.g., Li2S decomposition). Accordingly, light-weight, 3D Ni-based current collector is designed to control the deposition and catalytic conversion of sulfur species toward high-performance Li-S batteries. This work provides insights on the critical role of the current collector in determining the physical state of sulfur and elucidates the correlation between sulfur state and battery performance, which will advance electrode designs in high-energy Li-S batteries.

Three-dimensional ordered macroporous In2O3-supported Au for high-performance ethanol sensing

RSC Advances ◽  
2015 ◽  
Vol 5 (120) ◽  
pp. 99018-99022 ◽  
Author(s):  
Fubo Gu ◽  
Rui Nie ◽  
Ziwei Tian ◽  
Dongmei Han ◽  
Zhihua Wang
Keyword(s):  
High Performance ◽  
Three Dimensional ◽  
Good Reproducibility ◽  
Ethanol Sensitivity ◽  
Ordered Macroporous ◽  
Ethanol Sensing ◽  
High Ethanol

Au loaded three-dimensional ordered macroporous In2O3 was synthesized, and exhibited high ethanol sensitivity, improved selectivity and good reproducibility.

Hierarchical WO3@SnO2core–shell nanowire arrays on carbon cloth: a new class of anode for high-performance lithium-ion batteries

2014 ◽  
Vol 2 (20) ◽  
pp. 7367-7372 ◽  
Author(s):  
Lina Gao ◽  
Fengyu Qu ◽  
Xiang Wu
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Nanowire Array ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Nanowire Arrays ◽  
Carbon Cloth ◽  
New Class ◽  
High Reversible Capacity

Hybrid WO3@SnO2nanowire array/carbon cloth electrodes exhibit a high reversible capacity of 1000 mA h g−1after 200 cycles.

scholarly journals Three-Dimensional Carbon-Coated LiFePO4 Cathode with Improved Li-Ion Battery Performance

Coatings ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1137
Author(s):  
Can Wang ◽  
Xunlong Yuan ◽  
Huiyun Tan ◽  
Shuofeng Jian ◽  
Ziting Ma ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Three Dimensional ◽  
High Capacity ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Economic Benefits ◽  
Synthesis Process ◽  
Carbon Coated

LiFePO4 (LFPO)has great potential as the cathode material for lithium-ion batteries; it has a high theoretical capacity (170 m·A·h·g−1), high safety, low toxicity and good economic benefits. However, low conductivity and a low diffusion rate inhibit its future development. To overcome these weaknesses, three-dimensional carbon-coated LiFePO4 that incorporates a high capacity, superior conductivity and low volume expansion enables faster electron transport channels. The use of Cetyltrimethyl Ammonium Bromid (CTAB) modification only requires a simple water bath and sintering, without the need to add a carbon source in the LFPO synthesis process. In this way, the electrode shows excellent reversible capacity, as high as 159.8 m·A·h·g−1 at 2 C, superior rate capability with 97.3 m·A·h·g−1at 5 C and good cycling ability, preserving ~84.2% capacity after 500 cycles. By increasing the ion transport rate and enhancing the structural stability of LFPO nanoparticles, the LFPO-positive electrode achieves excellent initial capacity and cycle life through cost-effective and easy-to-implement carbon coating. This simple three-dimensional carbon-coated LiFePO4 provides a new and simple idea for obtaining comprehensive and high-performance electrode materials in the field of lithium cathode materials.

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