Structure and luminescence properties of a Nd3+doped Bi4Ge3O12scintillation crystal: new insights from a comprehensive study

2017 ◽  
Vol 5 (12) ◽  
pp. 3079-3087 ◽  
Author(s):  
Feiyang Chen ◽  
Meng Ju ◽  
Gennady L. Gutsev ◽  
Xiaoyu Kuang ◽  
Cheng Lu ◽  
...  

We have, for the first time, identified a unique semiconducting phase of theR3 space group where impurity Nd3+ions occupy exactly the host Bi3+ion sites with trigonal symmetry.

Author(s):  
Nadezhda G. KANTYSHEVA ◽  
Inna V. Solovyova

This article is devoted to a comprehensive study of the structural and semantic features of dish names and their descriptions in German in the field of restaurant discourse. The study employs cognitive discourse analysis, elements of comparative and contextological approaches, taking into account linguocultural parameters. The relevance of the comprehensive study of the names of dishes in restaurant discourse is due to an increased interest in the parameterization of lexical units in different types of institutional discourse. The scientific novelty of this work lies in the fact that for the first time, within the framework of a restaurant menu, not only the nomination of a dish is considered, but also the structural and semantic characteristics of its description are analysed. An attempt is made to analyse a connection between the nominations of dishes and their description in the restaurant menu, as well as to determine the semantic dominants of the genre under study. It is concluded that the text of the menu as a whole presents a combination of the language for special purposes and the language of advertising. In interaction with extralinguistic factors, the nominations of dishes and their descriptions not only document the culture of food in society, but also reflect the ethnocultural picture of the world. Based on the analysis of the menu texts, it is established that structurally the names of dishes are complex words or phrases, built mainly according to the attributive model. The description of dishes performs the function of verbalizing the sensations of taste and clarifying the method of preparing dishes, characterizing the quality of dishes, their ingredients, and the intensity of taste. Evaluative parameters in descriptions are expressed at the lexical, grammatical, syntactic and stylistic levels.


Author(s):  
L. G. Vakulenko ◽  
◽  
O. D. Nikolenko ◽  
D. A. Novikov ◽  
P. A. Yan ◽  
...  

A comprehensive study of the composition of sand and silt deposits of the Yu1 horizon of the Vasyuganskaya Formation upper part of the Verkh-Tarskoye oil field has been carried out. Associations of authigenic minerals have been determined in their cement, among which the calcite is the most widespread. According to petrographic parameters, three generations of calcite have been identified for which detailed isotopicgeochemical and ultramicroscopic studies were carried out for the first time. Wide and multi directional changes in the isotopic composition of carbon and oxygen and in the chemical composition of carbonate minerals were recorded, they indicate significant variations in the conditions of diagenesis and catagenesis, primarily temperature, and different sources of CO2. Significant variations in the isotopic composition of formation waters and its relationship with the isotopic composition of carbonates have been established. Thus, a narrow interval of close δ13C values was revealed, amounting to –10.5 to –9.1 ‰ in the formation waters of group II, and from –10.7 to –9.1 ‰ in calcites of the third generation. The source of CO2 in this system should be considered a carbon dioxide, which is formed in the process of metamorphism of carbonate rocks of the Paleozoic age.


2012 ◽  
Vol 194 ◽  
pp. 5-9 ◽  
Author(s):  
Yuriy Verbovytskyy ◽  
Antonio Pereira Gonçalves

Seven new ternary RZn1+xGa3-x (R = Ce, Pr, Nd, Sm, Ho and Er) and R5Zn2Ga17 (R = Ce) phases are synthesized for the first time. Their crystal structures are solved on basis of X-ray powder diffraction data. The above mentioned compounds belong to the BaAl4 (space group I4/mmm) and Rb5Hg19 (space group I4/m) structure types. Details of the structure of the Ce5Zn2Ga17 compound and relationship with RZn2-xGa2+x (BaAl4 type) and R3Zn8-xGa3+x (La3Al11 type) are briefly discussed.


THE BULLETIN ◽  
2021 ◽  
Vol 389 (1) ◽  
pp. 252-259
Author(s):  
N. Kh.-A. Rakhmonkulova

The article analyzes international and national guarantee investment activities on the territory of the Republic of Uzbekistan and discusses the issues of the implementation of the rights and legitimate interests of foreign investors using legal guarantee obligations in the national legislation of Uzbekistan. The aim of the study is to study the international mechanism for guaranteeing the repatriation of foreign investors, a comprehensive analysis of the most important international legal mechanisms in this area. The scientific novelty of the research is determined by the fact that the raised problem became for the first time the subject of a special comprehensive study. The author carries out research based on a significant number of international legal acts in the field of international legal guarantees for investment activities, constituent documents of intergovernmental organizations-subjects of international law, conducts a comparative analysis of various aspects of guarantees for investment activities. The novelty of the article is also enhanced by the fact that the author studies in detail the problems of correlation between the international legal and national legal mechanisms for guaranteeing investment activity. In the article, based on the analysis of international legal material, for the first time are investigated: - the international legal mechanism for guaranteeing investment activities, its constituent elements; the operation of multilateral and bilateral agreements in this area; -national legal mechanism for guaranteeing investment activities; To achieve this goal, taking into account the designated subject of research, the following results were obtained in the work: • International legal guarantees have been studied and a legal description to them has been given; • The main aspects of interaction between the international and national legal mechanism for guaranteeing investment activity have been identified;


Author(s):  
Siti Norul Fadhilah Zalamin ◽  
Mohd Hafiz Mohd Zaid ◽  
Khamirul Amin Matori ◽  
Muhammad Khalis Abdul Karim ◽  
Nurul Afiqah Mohamad Yamin ◽  
...  

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Sam Fernando ◽  
Kriengsak Panuwatwanich ◽  
David Thorpe

PurposeThis study aims to investigate and model the complex dynamics of innovation enablers in construction projects aiming to develop a framework identifying actions for clients to promote innovation.Design/methodology/approachThrough a comprehensive literature review, a conceptual model was previously derived to explain the client-driven enablers in promoting innovation. This was tested using the data from 131 Australian construction projects. Statistical analysis was conducted on the data using factor analysis and correlation analysis to test the model, which was validated using the case study approach. The testing and validating aspects are explained in this paper.FindingsThe constructs of the recommended model are idea harnessing, relationship enhancement, incentivization and project team fitness.Research limitations/implicationsThe difficulty of analyzing the complex dynamics happening within projects in relation to innovation has been a barrier to progress research in this area. The introduction of this model would pave the way for researchers to explore this area with ease.Originality/valueAs revealed in the detailed literature review undertaken, this is the first time that a comprehensive study has been conducted to identify client-led innovation enablers for construction projects. The results would benefit industry practitioners to achieve enhanced project outcomes in construction projects through innovation.


2009 ◽  
Vol 62 (8) ◽  
pp. 927 ◽  
Author(s):  
Tung A. Hoang ◽  
H. Ming Ang ◽  
Andrew L. Rohl

A comprehensive study of the effects of nine organic additives on the formation of calcium sulfate scale in a pipe system was conducted using a multiple pipe flow system. Several factors that influence the inhibitory capability of phosphonic and carboxylic additives such as their chemical structure, their concentration, and the run time were closely scrutinized. Results showed that the organic additives influence the deposition of calcium sulfate on the walls of a pipe flow system at various levels. The superiority of the phosphonic additives, especially N,N,N′,N′-ethylenediaminetetramethylenephosphonic acid (EDTP) and nitrilotrimethylenephosphonic acid (NTMP), to other organic compounds with respect to scale prevention is discussed thoroughly. For the first time, it was demonstrated that a solution with a given concentration of inhibitor that is continuously refreshed in a pipe reactor becomes less effective over time. The morphology of the scales formed in the presence of different additives is also studied, using scanning electron microscopy.


2010 ◽  
Vol 2010 ◽  
pp. 1-7 ◽  
Author(s):  
Xiaoting Zhang ◽  
Tomokatsu Hayakawa ◽  
Masayuki Nogami ◽  
Yukari Ishikawa

GdF3:Eu3+nanophosphors with hexagonal or orthorhombic structure have been succeeded to be selectively synthesized at room temperature for the first time via a simple soft chemical route. The structure and morphology of GdF3:Eu3+nanophosphors were controlled by using different fluoride precursors. Hexagonal GdF3:Eu3+nanocrystals were formed when NaBF4was used as a fluoride precursor, while orthorhombic GdF3:Eu3+nanocrystals were obtained with NaF or NH4F fluoride precursor. It was also experimentally revealed that hexagonal GdF3:Eu3+nanophosphors emitted essentially stronger Eu3+luminescence than orthorhombic ones did. The formation mechanism of GdF3nanocrystals and the possible reasons of the strong PL in hexagonal were discussed.


2006 ◽  
Vol 61 (7) ◽  
pp. 779-784 ◽  
Author(s):  
Ol’ga Stel’makhovych ◽  
Yurij Kuz’ma

The crystal structures of several new compounds have been determined using X-ray analysis. The intermetallic compound HoZn5Al3 (a = 8.586(3), c = 16.538(5) Å , RF = 0.0413, RW = 0.0521) has its own structure type (space group I4/mmm), which has been found for the first time. The following compounds are isostructural with the previous one: YZn5.52Al2.48 (a = 8.6183(1), c = 16.5048(3) Å , RI = 0.078, RP = 0.116), DyZn4.96Al3.04 (a = 8.5887(1), c = 16.5002(3) Å , RI = 0.077, RP = 0.114), ErZn5.37Al2.63 (a = 8.5525(2), c =16.3997(5) Å , RI = 0.081, RP = 0.111), TmZn5.64Al2.36 (a = 8.70429(8), c = 16.3943(4) Å , RI = 0.088, RP = 0.095), LuZn5.58Al2.42 (a = 8.5616(1), c= 16.3052(3) Å , RI =0.081, RP =0.101). The intermetallic compound Yb4Zn20.3Al12.7 (a = 8.6183(1), c = 16.5048(3) Å , RI = 0.085, RP = 0.112) adopts the Yb8Cu17Al49 - type structure (space group I4/mmm). The relationship between the HoZn5Al3-type and the Yb8Cu17Al49-type structures is discussed.


2018 ◽  
Vol 42 (8) ◽  
pp. 5955-5966 ◽  
Author(s):  
Huize Zhang ◽  
Wenqian Li ◽  
Xi Yan ◽  
Wanlin Cai ◽  
Ming Li ◽  
...  

Iridium(iii) complexes that use o-carborane as a chelating ligand have been theoretically investigated for the first time. The superior properties of complexes will potentially promote the discovery of efficient blue-emitting complexes.


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