Excitonic recombination dynamics mediated by polymorph transformation in cadmium sulfide nanocrystals

2016 ◽  
Vol 4 (28) ◽  
pp. 6784-6789 ◽  
Author(s):  
Pan Wang ◽  
Zhifang Li ◽  
Tianye Yang ◽  
Zhiyang Wang ◽  
Pinwen Zhu ◽  
...  

The excitonic recombination dynamics could be mediated by the different bandgaps and wave function overlaps in polymorphic CdS nanocrystals.

2018 ◽  
Vol 54 (5) ◽  
pp. 495-498 ◽  
Author(s):  
Jia-Shiang Chen ◽  
Huidong Zang ◽  
Mingxing Li ◽  
Mircea Cotlet

The kinetics of PL blinking for isolated PbS/CdS nanocrystals changes with the photon excitation energy, with PL blinking increasing in frequency and changing from a two-state to a multistate on/off switching when the excitation energy changes from 1Sh–1Se (≈1.4 eV) to 1Ph–1Pe (≈2.4 eV).


2014 ◽  
Vol 52 ◽  
pp. 128-133 ◽  
Author(s):  
Saravanan L ◽  
Jayavel R ◽  
Pandurangan A ◽  
Liu Jih-Hsin ◽  
Miao Hsin-Yuan

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Kirill Svit ◽  
Konstantin Zhuravlev ◽  
Sergey Kireev ◽  
Karl K. Sabelfeld

Abstract A stochastic model of nanocrystals clusters formation is developed and applied to simulate an aggregation of cadmium sulfide nanocrystals upon evaporation of the Langmuir–Blodgett matrix. Simulations are compared with our experimental results. The stochastic model suggested governs mobilities both of individual nanocrystals and its clusters (arrays). We give a comprehensive analysis of the patterns simulated by the model, and study an influence of the surrounding medium (solvent) on the aggregation processes. In our model, monomers have a finite probability of separation from the cluster which depends on the temperature and binding energy between nanocrystals, and can also be redistributed in the composition of the cluster, leading to its compaction. The simulation results obtained in this work are compared with the experimental data on the aggregation of CdS nanocrystals upon evaporation of the Langmuir–Blodgett matrix. This system is a typical example from real life and is noteworthy in that the morphology of nanocrystals after evaporation of the matrix cannot be described exactly by a model based only on the motion of individual nanocrystals or by a cluster-cluster aggregation model.


2020 ◽  
Vol 187 (6) ◽  
Author(s):  
Tao Xie ◽  
Xufeng Zhong ◽  
Zhengjie Liu ◽  
Chenggen Xie

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