Confinement of an electron-capturing unit within an electron-donating framework for X-ray detection

2016 ◽  
Vol 4 (16) ◽  
pp. 3431-3436 ◽  
Author(s):  
Hao Zhang ◽  
Tianlu Sheng ◽  
Shengmin Hu ◽  
Chao Zhuo ◽  
Ruibiao Fu ◽  
...  
Keyword(s):  
Organic Complex ◽  
X Ray ◽  
Metal Organic Complex ◽  
Metal Organic

A novel X-ray-induced photochromic metal–organic complex was constructed by confining an electron-capturing unit within the cavity of an electron-donating framework.

Synthesis and Crystal Structure of a Cadmium(II) Complex with 2-(4΄-Chlorine-Benzoyl)-Benzoic Acid and 1,10-Phenanthroline

2011 ◽  
Vol 339 ◽  
pp. 313-316
Author(s):  
Xiu Mei Li ◽  
Zhi Tao Wang ◽  
Qing Wei Wang
Keyword(s):  
Benzoic Acid ◽  
Room Temperature ◽  
Supramolecular Network ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
Orthorhombic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Metal Organic Complex ◽  
Metal Organic

A new metal-organic complex Cd2(cbba)4(phen)2 (Hcbba = 2-(4΄-chlorine-benzoyl)- benzoic acid, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, fluorescence spectrum and single-crystal X-ray diffraction. The compound crystallizes in orthorhombic, space group Pbcn with a = 12.0976(4), b = 18.0925(6), c = 31.6829(10) Å, V = 6934.6(4) Å3, C80H48Cd2Cl4N4O12, Mr = 1623.82, Dc = 1.555 g/cm3, μ(MoKα) = 0.8365 mm1, F(000) = 3264, Z = 4, the final R = 0.0396 and wR = 0.0960 for 5372 observed reflections (I > 2(I)). It exhibits a 3D supramolecular network through π-π interactions and shows green luminescent property at room temperature.

Synthesis and Crystal Structure of a Fe(II,III) Complex with 2-(4΄-Chlorine-benzoyl)-benzoic acid and 3-(2-Pyridyl)pyrazole

2013 ◽  
Vol 634-638 ◽  
pp. 2592-2595
Author(s):  
Qing Wei Wang ◽  
Ting Feng Lu ◽  
Jia Guo ◽  
Xiu Mei Li
Keyword(s):  
Crystal Structure ◽  
Benzoic Acid ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Elemental Analyses ◽  
Metal Organic Complex ◽  
Metal Organic

A new metal-organic complex FeII2FeIII2(cbba)4(L)6 (Hcbba = 2-(4΄-chlorine-benzoyl) benzoic acid, L = 3-(2-pyridyl)pyrazole) 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, TG and IR spectroscopy. The compound crystallizes in monoclinic, space group Cc with a = 17.729(5), b = 15.919(5), c = 33.650(5) Å, β = 92.058(5)°, V = 9491(4) Å3, C104H68Cl4Fe4N18O12, Mr = 2126.96, Dc = 1.489 g/cm3, μ(MoKα) = 0.786 mm1, F(000) = 4344, Z = 4, the final R = 0.0559 and wR = 0.1122 for 12093 observed reflections (I > 2(I)).

A Three-Dimensional Metal-Organic Framework Displaying Guest-Dependent Spin-Crossover Behaviour

2018 ◽  
Vol 779 ◽  
pp. 110-114
Author(s):  
Feng Shao ◽  
Jia Jia Zhuang ◽  
Gang Luo ◽  
Ke Zhang ◽  
Chang Jiang Li ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Organic Complex ◽  
Single Crystal Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Metal Organic Complex ◽  
Metal Organic ◽  
3D Framework

A new three-dimensional metal-organic complex, [{Fe (NCSe)2}3(TPB)4]x(guest), was prepared with the ligand of TPB (1,3,5-tris (4-pyridyl) benzene). The X-ray single crystal diffraction studied in 100 K and 173 K shown the change of bonds and angles of the framework. The guest exchange and magnetic properties indicated that the 3D framework can be responsible to the solvent guest molecules and shows guest-dependent spin-crossover behaviour.

A Heterometallic MOC Assembled from Cobalt-bisupported Keggin Subunits

2013 ◽  
Vol 68 (11) ◽  
pp. 1214-1218 ◽  
Author(s):  
Heng Liu ◽  
Ying Guo ◽  
Rui Ran ◽  
Huiyuan Ma ◽  
Haijun Pang ◽  
...  
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Title Complex ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
X Ray ◽  
Elemental Analyses ◽  
Metal Organic Complex ◽  
Metal Organic

A heterometallic metal-organic complex (MOC), K[Co(1,10-phen)2(H2O)]2[BW12O40]·2H2O (phen=1,10-phenanthroline) (1), has been synthesized hydrothermally and characterized by elemental analyses, IR spectroscopy, and single-crystal X-ray diffraction. The complex exhibits cobaltbisupported tungstoborate units and potassium cations. The luminescence of the title complex has been investigated.

A new cobalt(II) complex nanosheet as an electroactive medium for plasmonic switching on Au nanoparticles

2021 ◽  
Author(s):  
Yurong Liu ◽  
Wenzheng Lu ◽  
Xizhe Cheng ◽  
Jianfang Wang ◽  
Wai-Yeung Raymond Wong
Keyword(s):  
High Stability ◽  
Au Nanoparticles ◽  
Organic Complex ◽  
Metal Organic Complex ◽  
Metal Organic

2D metal-organic complex nanosheets with the merits of high stability and structure tunability are an emerging topic in recent years. To extend the promising ultrathin architectures, a new Co(II) complex...

High-Performance Single-Electron Transistor Based on Metal–Organic Complex of Thiophene: First Principle Study

2017 ◽  
Vol 64 (11) ◽  
pp. 4628-4635 ◽  
Author(s):  
Anu ◽  
Archana Sharma ◽  
Md. Shahzad Khan ◽  
Anurag Srivastava ◽  
Mushahid Husain ◽  
...  
Keyword(s):  
High Performance ◽  
Single Electron ◽  
Single Electron Transistor ◽  
First Principle ◽  
Organic Complex ◽  
Metal Organic Complex ◽  
Metal Organic
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