Rationally designed two-photon absorption compounds based on benzoxazole derivatives: structure–property relationships and bio-imaging applications

2016 ◽  
Vol 4 (16) ◽  
pp. 2785-2793 ◽  
Author(s):  
Xinping Ge ◽  
Xiaoping Gan ◽  
Shun Yao ◽  
Kang Wang ◽  
Weiju Zhu ◽  
...  
Keyword(s):  
Photon Absorption ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Structure Property Relationships ◽  
Bio Imaging

Five rationally designed benzoxazole-based two photon absorption compounds were reported and their structure–property relationships were summarized clearly.

scholarly journals Uncovering Structure–Property Relationships in Push–Pull Chromophores: A Promising Route to Large Hyperpolarizability and Two-Photon Absorption

2020 ◽  
Vol 124 (29) ◽  
pp. 15739-15748
Author(s):  
Alessio Cesaretti ◽  
Paolo Foggi ◽  
Cosimo G. Fortuna ◽  
Fausto Elisei ◽  
Anna Spalletti ◽  
...  
Keyword(s):  
Photon Absorption ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Structure Property Relationships

scholarly journals Fluorescence and two-photon absorption of push–pull aryl(bi)thiophenes: structure–property relationships

2012 ◽  
Vol 11 (11) ◽  
pp. 1756 ◽  
Author(s):  
Emilie Genin ◽  
Vincent Hugues ◽  
Guillaume Clermont ◽  
Cyril Herbivo ◽  
M. Cidália R. Castro ◽  
...  
Keyword(s):  
Photon Absorption ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Structure Property Relationships

Optical Power Limiters for Nanosecond Pulses: Design of New Dendritic Chromophores with Exceptionally Large Two-Photon Cross-Sections

1999 ◽  
Vol 597 ◽  
Author(s):  
E. H. Elandaloussi ◽  
C. Spangler ◽  
M. Casstevens ◽  
D. Kumar ◽  
J. Weibel ◽  
...  
Keyword(s):  
Cross Sections ◽  
Optical Power ◽  
Optical Nonlinearity ◽  
Photon Absorption ◽  
Laser Dyes ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Structure Property Relationships ◽  
Nanosecond Pulses

AbstractOver the past five years there has been a renaissance in design studies of chromophores with the possibility of enhanced two-photon absorption (TPA). While two-photon absorption has been described for molecules such as laser dyes in solution for a number of years1, it has only been recently that researchers have attempted detailed structure-property relationships to elucidate how new chromophores with greatly enhanced two-photon cross-sections might be designed. Since the intrinsic cross-sections are related to the Im component of the third order optical nonlinearity, it should come as no surprise that much of the previous work in the literature which focused on structure-property relationships for molecules with enhanced NLO response might be applicable to the design of new TPA chromophores. In this presentation we will review our recent studies in this area, and our rationale for the applicability of dendritic strctures based on photonic-active repeat units for enhancment of two-photon absorption, particularly in the area of optical power limiting applications.

scholarly journals A difluorenyl-carbo-cyclohexadiene: prospective chromophore for two-photon absorption

2018 ◽  
Vol 6 (2) ◽  
pp. 9-17 ◽  
Author(s):  
Iaroslav Baglai ◽  
Gabriel Ramos-Ortiz ◽  
José-Luis Maldonado ◽  
Zoia Voitenko ◽  
Valérie Maraval ◽  
...  
Keyword(s):  
Cross Section ◽  
Photon Absorption ◽  
Structure Property ◽  
Green Fluorescence ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Structure Property Relationships ◽  
Cyclization Process

For the purpose of outlining structure-property relationships for two-photon absorption (2PA), a "s-locked" carbo-cyclohexadiene with two fluorenyl substituents has been envisaged for comparison with previously studied aromatic carbo-benzene and non-aromatic carbo-quinoid congeners. A representative where the C10-π-conjugated fluorenyl moieties are also connected by a C8-π-insulating 3,6‐dimethoxy‐3,6‐bis(trifluoromethyl)octa‐1,4,7‐triyn-1,8-diyl edge has thus been synthesized in four steps from known C8F triyne and C10 triynyldial, through a [8F+10] cyclization process. In spite of a relatively strong absorbance (e = 84 800 L.mol-1.cm-1 at 634 nm), the non-vanishing green fluorescence (at 533 nm) of the chromophore should allow measurements of the 2PA cross section by both the TPEF and Z-scan methods.

Small molecules of chalcone derivatives with high two-photon absorption activities in the near-IR region

2016 ◽  
Vol 4 (15) ◽  
pp. 3256-3267 ◽  
Author(s):  
Jingyun Tan ◽  
Yujin Zhang ◽  
Meirong Zhang ◽  
Xiaohe Tian ◽  
Yiming Wang ◽  
...  
Keyword(s):  
Small Molecules ◽  
Photon Absorption ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Chalcone Derivatives ◽  
Two Photon ◽  
Property Relationship ◽  
Near Ir ◽  
Structure Property Relationship

Six thiophene-based chalcone derivatives were synthesized, and their structure–property relationship was investigated systematically. Small molecules as they are, they have showed favorable Φ and σ values in the near-IR region.

Two-photon absorption of dipolar and quadrupolar oligothiophene-cored chromophores derivatives containing terminal dimesitylboryl moieties: A theoretical (DFT) structure-property investigation.

2021 ◽  
Author(s):  
Anissa Amar ◽  
Aziz ElKechai ◽  
Jean-François Halet ◽  
Frédéric Paul ◽  
Abdou Boucekkine
Keyword(s):  
Photon Absorption ◽  
Structure Property ◽  
Two Photon Absorption ◽  
Two Photon

A series of dipolar and quadrupolar dimesitylboryl (BMes2) derivatives containing different thiophene oligomers as the central conjugated bridge to which are appended BMes2 substituents at both ends have been investigated...

Thiophene-based pyridine derivatives: synthesis, crystal structures, two-photon absorption properties and bio-imaging applications in the near-IR region

2016 ◽  
Vol 40 (10) ◽  
pp. 8809-8814 ◽  
Author(s):  
Shasha Xu ◽  
Yingzhong Zhu ◽  
Rui Li ◽  
Jian Su ◽  
Shengli Li ◽  
...  
Keyword(s):  
Cross Sections ◽  
High Stability ◽  
Photon Absorption ◽  
Pyridine Derivatives ◽  
Absorption Properties ◽  
Two Photon Absorption ◽  
Two Photon ◽  
Near Ir ◽  
Bio Imaging ◽  
Low Cytotoxicity

Two novel D–π–A structural chromophores showing large 2PA active cross-sections, low cytotoxicity and high stability in near-IR bio-imaging.

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