scholarly journals Suppressing the chromium disproportionation reaction in O3-type layered cathode materials for high capacity sodium-ion batteries

2017 ◽  
Vol 5 (11) ◽  
pp. 5442-5448 ◽  
Author(s):  
Ming-Hui Cao ◽  
Yong Wang ◽  
Zulipiya Shadike ◽  
Ji-Li Yue ◽  
Enyuan Hu ◽  
...  

The reversible multi-electron oxidation/reduction process of Cr3+/Cr4.2+ with a large reversible capacity can be achieved in a novel O3-type NaCr1/3Fe1/3Mn1/3O2. The disproportionation reaction of Cr4+ to Cr3+ and Cr6+ can be effectively suppressed by Fe3+ and Mn4+ substitution.

2020 ◽  
Vol 8 (45) ◽  
pp. 23820-23826
Author(s):  
Zhaoguo Liu ◽  
Kezhu Jiang ◽  
Shiyong Chu ◽  
Jianghua Wu ◽  
Hang Xu ◽  
...  

Manganese-based layered cathode materials for sodium-ion batteries are attractive on account of the superiorities of high capacity and cost effectiveness.


2021 ◽  
Vol 23 (3) ◽  
pp. 2038-2045
Author(s):  
Kyoungmin Min ◽  
Young-Han Shin

Prevention of the degradation of sodium-based layered cathode materials is the key to developing high-performance and high-stability sodium-ion batteries.


2021 ◽  
Author(s):  
Jiaying Liao ◽  
Jingchen Han ◽  
Jianzhi Xu ◽  
Yichen Du ◽  
Yingying Sun ◽  
...  

We demonstrate an economical polytetrafluoroethylene-assisted fluorination method to synthesize three binary sodium-rich fluorides Na2MVF7 (M = Mn, Fe, and Co). The optimal Na2FeVF7 cathode delivers a high reversible capacity of...


2015 ◽  
Vol 8 (12) ◽  
pp. 3531-3538 ◽  
Author(s):  
Jun Liu ◽  
Peter Kopold ◽  
Chao Wu ◽  
Peter A. van Aken ◽  
Joachim Maier ◽  
...  

Uniform yolk–shell Sn4P3@C nanospheres exhibit very high reversible capacity, superior rate capability and stable cycling performance for Na-ion batteries.


2021 ◽  
Author(s):  
Francielli Genier ◽  
Shreyas Pathreeker ◽  
Robson Schuarca ◽  
Mohammad Islam ◽  
Ian Hosein

Deriving battery grade materials from natural sources is a key element to establishing sustainable energy storage technologies. In this work, we present the use of avocado peels as a sustainable source for conversion into hard carbon based anodes for sodium ion batteries. The avocado peels are simply washed and dried then proceeded to a high temperature conversion step. Materials characterization reveals conversion of the avocado peels in high purity, highly porous hard carbon powders. When prepared as anode materials they show to the capability to reversibly store and release sodium ions. The hard carbon-based electrodes exhibit excellent cycling performance, namely, a reversible capacity of 352.55 mAh/g at 0.05 A/g, rate capability up to 86 mAh/g at 3500 mA/g, capacity retention of >90%, and 99.9% coulombic efficiencies after 500 cycles. This study demonstrates avocado derived hard carbon as a sustainable source that can provide excellent electrochemical and battery performance as anodes in sodium ion batteries.


2019 ◽  
Vol 11 (34) ◽  
pp. 30894-30901 ◽  
Author(s):  
Taesoon Hwang ◽  
Jung-Hyun Lee ◽  
Seung Hyun Choi ◽  
Rye-Gyeong Oh ◽  
Duho Kim ◽  
...  

2021 ◽  
Vol 8 (3) ◽  
pp. 426-426
Author(s):  
Dumindu P. Siriwardena ◽  
Joseph F. S. Fernando ◽  
Tony Wang ◽  
Konstantin L. Firestein ◽  
Chao Zhang ◽  
...  

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