Design of La2−xPrxNiO4+δ SOFC cathodes: a compromise between electrochemical performance and thermodynamic stability

2017 ◽  
Vol 5 (3) ◽  
pp. 1120-1132 ◽  
Author(s):  
Rakesh K. Sharma ◽  
Seng-Kian Cheah ◽  
Mónica Burriel ◽  
Laurent Dessemond ◽  
Jean-Marc Bassat ◽  
...  

A novel architecturally designed LaPrNiO4+δ IT-SOFC cathode shows the best compromise between thermodynamic stability and electrochemical properties.

2017 ◽  
Vol 41 (20) ◽  
pp. 11759-11765 ◽  
Author(s):  
Shu Huang ◽  
Jianguo Ren ◽  
Rong Liu ◽  
Min Yue ◽  
Youyuan Huang ◽  
...  

A crosslinked ionomer binder was prepared and used in graphite anodes for Li-ion batteries. These binder-based anodes exhibit enhanced electrochemical performance due to the formation of hydrogen bonds and the release of conductive Li+.


2016 ◽  
Vol 294 ◽  
pp. 21-30 ◽  
Author(s):  
Aurélie Rolle ◽  
Hussien Ahmed Abbas Mohamed ◽  
Da Huo ◽  
Edouard Capoen ◽  
Olivier Mentré ◽  
...  

2015 ◽  
Vol 17 (47) ◽  
pp. 32033-32043 ◽  
Author(s):  
Jing Wang ◽  
Yangyang Yu ◽  
Bing Li ◽  
Tao Fu ◽  
Dongquan Xie ◽  
...  

The Li2TiO3-coated LiNi0.5Co0.2Mn0.3O2 (LTO@NCM) cathode materials are synthesized via an in situ coprecipitation method to improve the electrochemical performance of NCM.


2014 ◽  
Vol 51 (1) ◽  
pp. 51-56
Author(s):  
Kyoung-Jin Lee ◽  
Jeong-Uk Seo ◽  
Ye-Sol Lim ◽  
Hae-Jin Hwang

2019 ◽  
Vol 48 (31) ◽  
pp. 11749-11762 ◽  
Author(s):  
Xueying Dong ◽  
Yifu Zhang ◽  
Qiushi Wang ◽  
Xiaorong Zhang ◽  
Meng Gao ◽  
...  

Urchin-like Ni3Si2O5(OH)4 hierarchical hollow sphere/GO composites were synthesized, which showed an enhanced electrochemical performance of 165 F g−1 at 0.5 A g−1 and 84% capacity retention after 5000 cycles.


2015 ◽  
Vol 3 (33) ◽  
pp. 17016-17021 ◽  
Author(s):  
N. Zettsu ◽  
K. Nishikawa ◽  
K. Yubuta ◽  
K. Sakurai ◽  
Y. Yamamoto ◽  
...  

Hexagonal cylindrical LiCoO2crystals surrounded by large {104} planes prepared through template-mediated flux growth exhibit fast Li+transfer and favorable electrochemical performance at high current rates.


Author(s):  
Seung-Wook Baek ◽  
Joongmyeon Bae

Samarium (Sm) is a rare earth material that shows promise for use in cathodes of intermediate temperature-operating solid oxide fuel cells (IT-SOFCs). Perovskite-structured oxide containing Sm has very attractive electrocatalytic properties, and spinel-structured oxide generally exhibits low thermal expansion, indicating its suitability for application as a SOFC cathode. In this paper, the characteristics of the various Sm-based oxide materials (Sm-Sr-(Co,Fe,Ni)-O) deposited on Sm0.2Ce0.8O1.9 (SDC) electrolyte pellets were investigated in terms of their microstructure, sinterability and electrochemical properties. The relationship between the composition and the sintering temperature was studied and discussed. Results show that the substitution of iron (Fe) and nickel (Ni) in Co-sites affects the sinterability, adhesion to the electrolyte and electrochemical activity, such that the different sintering temperatures for these compositions should be considered. The microstructure and sinterability of the cathodes were investigated using a scanning electron microscope (SEM). Area specific resistance (ASR) values for all cathode compositions were measured using AC electrochemical impedance spectroscopy (EIS).


Nanoscale ◽  
2018 ◽  
Vol 10 (22) ◽  
pp. 10554-10563 ◽  
Author(s):  
Diwen Shi ◽  
Liuyang Zhang ◽  
Nengduo Zhang ◽  
Yong-Wei Zhang ◽  
Zhi Gen Yu ◽  
...  

Greatly enhanced electrochemical performance is obtained through surface modification of ultrathin interlaced Ni(OH)2 nanosheets with Co(OH)2 quantum dots.


2018 ◽  
Vol 914 ◽  
pp. 102-108
Author(s):  
Wei Zhao ◽  
Yi Lin Liao ◽  
Shu Jun Qiu ◽  
Hai Liang Chu ◽  
Yong Jin Zou ◽  
...  

In order to investigate the effect of lanthanum on the electrochemical properties of CoB amorphous alloy, Co-Lax-B alloys (x = 0, 0.1, 0.5, and 1) were prepared by chemical reduction method. As negative electrodes in alkaline rechargeable batteries, Co-Lax-B alloys exhibit superior electrochemical properties. For Co-La0.1-B alloy, at the discharge current density of 100 mA/g, the initial discharge capacity is 830.6 mAh/g and the discharge capacity has remained around 317.3 mAh/g even after 100 cycles. Moreover, the high-rate discharge ability (HRD) of Co-La0.1-B alloy electrode at the discharge current density of 300 mA/g, 600 mA/g, and 900 mA/g is 98.16%, 95.17%, and 91.86%, respectively. The anodic polarization (AP) and the electrochemical impedance spectra (EIS) measurements indicate that the kinetics of electrochemical performance of the alloys is remarkably improved with the addition of lanthanum.


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