A copper-based sorbent with oxygen-vacancy defects from mechanochemical reduction for carbon disulfide absorption

2016 ◽  
Vol 4 (43) ◽  
pp. 17207-17214 ◽  
Author(s):  
Haipeng Chen ◽  
Shixue Zhou ◽  
Zongying Han ◽  
Yaoyao Jiang ◽  
Hao Yu ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Carbon Disulfide ◽  
Particle Surface ◽  
Vacancy Defects ◽  
Trapping Sites

Mechanochemical reduction of CuO can generate Ovacdefects on the particle surface and they act as trapping sites for CS2absorption.

scholarly journals Charge-Transfer Induced by the Oxygen Vacancy Defects in the Ag/MoO3 Composite System

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1292
Author(s):  
Qi Chu ◽  
Jingmeng Li ◽  
Sila Jin ◽  
Shuang Guo ◽  
Eungyeong Park ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Oxygen Vacancy ◽  
Composite System ◽  
Wide Band ◽  
Utilization Rate ◽  
Wide Band Gap ◽  
Interesting Phenomenon ◽  
Vacancy Defects ◽  
Characterization Methods ◽  
Surface Enhanced Raman

In this paper, an Ag/MoO3 composite system was cosputtered by Ar plasma bombardment on a polystyrene (PS) colloidal microsphere array. The MoO3 formed by this method contained abundant oxygen vacancy defects, which provided a channel for charge transfer in the system and compensated for the wide band gap of MoO3. Various characterization methods strongly demonstrated the existence of oxygen vacancy defects and detected the properties of oxygen vacancies. 4-Aminothiophenol (p-aminothiophenol, PATP) was used as a candidate surface-enhanced Raman scattering (SERS) probe molecule to evaluate the contribution of the oxygen vacancy defects in the Ag/MoO3 composite system. Interestingly, oxygen vacancy defects are a kind of charge channel, and their powerful effect is fully reflected in their SERS spectra. Increasing the number of charge channels and increasing the utilization rate of the channels caused the frequency of SERS characteristic peaks to shift. This interesting phenomenon opens up a new horizon for the study of SERS in oxygen-containing semiconductors and provides a powerful reference for the study of PATP.

Oxygen vacancy defects in Ta2O5 showing long-range atomic re-arrangements

2014 ◽  
Vol 104 (11) ◽  
pp. 112906 ◽  
Author(s):  
Yuzheng Guo ◽  
John Robertson
Keyword(s):  
Oxygen Vacancy ◽  
Long Range ◽  
Vacancy Defects

Facile Removal of Bulk Oxygen Vacancy Defects in Metal Oxides Driven by Hydrogen-Dopant Evaporation

2021 ◽  
pp. 9579-9583
Author(s):  
Min Hu ◽  
Qing Zhu ◽  
Yuan Zhao ◽  
Guozhen Zhang ◽  
Chongwen Zou ◽  
...  
Keyword(s):  
Oxygen Vacancy ◽  
Metal Oxides ◽  
Vacancy Defects ◽  
Bulk Oxygen

Low-valence or tetravalent cation doping of manganese oxide octahedral molecular sieve (K-OMS-2) materials for nitrogen oxide emission abatement

2019 ◽  
Vol 9 (15) ◽  
pp. 4108-4117 ◽  
Author(s):  
Xiaomin Wu ◽  
Xiaolong Yu ◽  
Ziyi Chen ◽  
Zhiwei Huang ◽  
Guohua Jing
Keyword(s):  
Catalytic Activity ◽  
Oxygen Vacancy ◽  
Manganese Oxide ◽  
Nitrogen Oxide ◽  
Molecular Sieve ◽  
Oxide Catalysts ◽  
Nitrogen Oxide Emission ◽  
Vacancy Defects ◽  
Cation Doping ◽  
Tetravalent Cation

Substitutionally doped oxide catalysts with abundant oxygen vacancy defects (OVDs) can effectively improve the catalytic activity efficiency.

Mesoporous MnCo2O4with abundant oxygen vacancy defects as high-performance oxygen reduction catalysts

2014 ◽  
Vol 2 (23) ◽  
pp. 8676-8682 ◽  
Author(s):  
Tian Yi Ma ◽  
Yao Zheng ◽  
Sheng Dai ◽  
Mietek Jaroniec ◽  
Shi Zhang Qiao
Keyword(s):  
Oxygen Vacancy ◽  
Oxygen Reduction ◽  
High Performance ◽  
Vacancy Defects ◽  
Oxygen Reduction Catalysts ◽  
Reduction Catalysts

Cathodoluminescence Microanalysis of Irradiated Microcrystalline and Nanocrystalline Samarium Doped BaFCl

2012 ◽  
Vol 18 (6) ◽  
pp. 1229-1238 ◽  
Author(s):  
Marion A. Stevens-Kalceff ◽  
Zhiqiang Liu ◽  
Hans Riesen
Keyword(s):  
Spatial Distribution ◽  
Electron Beam ◽  
Fine Structure ◽  
Particle Surface ◽  
Host Lattice ◽  
Oxidation States ◽  
Precipitation Method ◽  
Vacancy Defects ◽  
X Ray ◽  
Co Precipitation

AbstractBaFCl:Sm3+ is an efficient photoluminescent storage phosphor for ionizing radiation. Cathodoluminescence (CL) microanalysis enables the Sm2+ and Sm3+ oxidation states of samarium doped BaFCl to be easily identified, provides information about electron-beam and X-ray induced modification of BaFCl:Sm, and enables the synthesis dependent spatial distribution of samarium dopants of <100 ppm concentration to be determined with sub-100 nm resolution at 295 K. CL spectroscopy of BaFCl:Sm particles reveals broad CL emissions at ∼360 and ∼500 nm associated with Vk(Cl−) and oxygen-vacancy defects in the BaFCl host lattice and fine structure CL emissions associated with major 4GJ → 6HJ (Sm3+) and 5DJ → 7FJ (Sm2+) transitions. CL microanalysis shows samarium dopants are uniformly distributed in conventional sintered microcrystalline BaFCl:Sm. In contrast, CL investigations reveal that for BaFCl:Sm nanoparticles, which have been prepared using a co-precipitation method, with greatly improved Sm3+ → Sm2+ conversion efficiency, the samarium dopants are concentrated near the particle surface resulting in a BaFCl:Sm3+ shell surrounding the BaFCl core, which is stable to energetic irradiation.

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