Interfacial reaction-directed synthesis of a ceria nanotube-embedded ultra-small Pt nanoparticle catalyst with high catalytic activity and thermal stability

2016 ◽  
Vol 4 (37) ◽  
pp. 14148-14154 ◽  
Author(s):  
Yong Wang ◽  
Guolong Song ◽  
Zhenhe Xu ◽  
Federico Rosei ◽  
Dongling Ma ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Interfacial Reaction ◽  
High Catalytic Activity ◽  
Pt Nanoparticle ◽  
Directed Synthesis ◽  
Nanoparticle Catalyst

Due to the ultra-small size of Pt NPs and the extensive contact between Pt and ceria, the ceria nanotube-embedded ultra-small Pt nanoparticle catalyst exhibits remarkable catalytic activity and thermal stability toward CO oxidation.

scholarly journals CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst

Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 131 ◽  
Author(s):  
Rola Mohammad Al Soubaihi ◽  
Khaled Mohammad Saoud ◽  
Myo Tay Zar Myint ◽  
Mats A. Göthelid ◽  
Joydeep Dutta
Keyword(s):  
Carbon Monoxide ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Active Sites ◽  
Bond Activation ◽  
Dissociative Adsorption ◽  
High Catalytic Activity ◽  
Good Catalytic Activity ◽  
Pretreatment Conditions ◽  
Oxidation Efficiency

Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (Tig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than Tig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at Tig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.

CO Oxidation on Inverse CeOx/Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O2

2011 ◽  
Vol 133 (10) ◽  
pp. 3444-3451 ◽  
Author(s):  
Fan Yang ◽  
Jesús Graciani ◽  
Jaime Evans ◽  
Ping Liu ◽  
Jan Hrbek ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
High Catalytic Activity

Synthesis and characterization of new isostructural series LnFe0.5Sb1.5O6 (Ln = La-Sm) exhibiting high catalytic activity in CO oxidation

2019 ◽  
Vol 777 ◽  
pp. 655-662 ◽  
Author(s):  
A.V. Egorysheva ◽  
O.G. Ellert ◽  
E. Yu Liberman ◽  
D.I. Kirdyankin ◽  
S.V. Golodukhina ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
Synthesis And Characterization ◽  
High Catalytic Activity

High catalytic activity for CO oxidation on single Fe atom stabilized in graphene vacancies

RSC Advances ◽  
2016 ◽  
Vol 6 (96) ◽  
pp. 93985-93996 ◽  
Author(s):  
Yanan Tang ◽  
Jincheng Zhou ◽  
Zigang Shen ◽  
Weiguang Chen ◽  
Chenggang Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Co Oxidation ◽  
First Principles ◽  
High Catalytic Activity ◽  
First Principles Method

The geometric, electronic and catalytic characters of Fe atom embedded graphene (including monovacancy and divacancy) are investigated using the first-principles method, which gives a reference on designing graphene-based catalysts for CO oxidation.

scholarly journals Cellulose nanocrystals (CNCs) as hard templates for preparing mesoporous zeolite Y assemblies with high catalytic activity

2020 ◽  
Vol 22 (15) ◽  
pp. 5115-5122 ◽  
Author(s):  
Samer Abdulridha ◽  
Jiuxing Jiang ◽  
Shaojun Xu ◽  
Zhaoxia Zhou ◽  
He Liang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Cellulose Nanocrystals ◽  
Zeolite Y ◽  
Synthesis Method ◽  
High Catalytic Activity ◽  
Mesoporous Zeolite ◽  
Y Zeolite ◽  
Directed Synthesis

Faujasite (FAU) Y zeolite assemblies with high mesoporosity (Sext = 347 m2 g−1 and Vmeso = 0.52 cm3 g−1) were synthesised using sustainable and economic cellulose nanocrystals (CNCs) via a template-directed synthesis method.

scholarly journals The Sintering of Au Nanoparticles on Flat {100}, {111} and Zigzagged {111}-Nanofacetted Structures of Ceria and Its Influence on Catalytic Activity in CO Oxidation and CO PROX

2020 ◽  
Author(s):  
O. S. Bezkrovnyi ◽  
P. Kraszkiewicz ◽  
W. Mista ◽  
L. Kepinski
Keyword(s):  
Electron Microscopy ◽  
Thermal Stability ◽  
Catalytic Activity ◽  
Beneficial Effect ◽  
Co Oxidation ◽  
Au Nanoparticles ◽  
Ceria Support ◽  
Ceria Catalysts ◽  
Thermal Stability Of

Abstract The thermal stability of Au nanoparticles on ceria support of various morphology (nanocubes, nanooctahedra, and {111}-nanofacetted nanocubes) in oxidizing and reducing atmospheres was investigated by electron microscopy. A beneficial effect of the reconstruction of edges of ceria nanocubes into zigzagged {111}-nanofacetted structures on the inhibition of sintering of Au nanoparticles was shown. The influence of different morphology of Au particles on various ceria supports on the reducibility and catalytic activity in CO oxidation, and CO PROX of Au/ceria catalysts was also investigated and discussed. It was shown, that ceria nanocubes with flat {110} terminated edges are more suitable as a support for Au nanoparticles, used to catalyze CO oxidation, than zigzagged {111}- nanofacetted structures. Graphic Abstract

Preparation of TiO2-supported twinned gold nanoparticles by CO treatment and their CO oxidation activity

2015 ◽  
Vol 51 (87) ◽  
pp. 15823-15826 ◽  
Author(s):  
Junya Ohyama ◽  
Taiki Koketsu ◽  
Yuta Yamamoto ◽  
Shigeo Arai ◽  
Atsushi Satsuma
Keyword(s):  
Gold Nanoparticles ◽  
Catalytic Activity ◽  
Co Oxidation ◽  
Au Nanoparticles ◽  
High Catalytic Activity ◽  
Oxidation Activity

Au/TiO2 prepared by CO treatment showed high catalytic activity for CO oxidation due to twinned structure of Au nanoparticles.

A highly moisture-resistant Fe-doped mesoporous Co3O4 catalyst for efficient low-temperature CO oxidation

2015 ◽  
Vol 39 (3) ◽  
pp. 1742-1748 ◽  
Author(s):  
Gengnan Li ◽  
Liang Li ◽  
Yongsheng Li ◽  
Jianlin Shi
Keyword(s):  
Catalytic Activity ◽  
Low Temperature ◽  
Co Oxidation ◽  
High Catalytic Activity ◽  
Low Temperature Co Oxidation ◽  
Moisture Conditions ◽  
Moisture Resistant

Compared with pure Co3O4 spinel, the Fe-doped catalyst demonstrates high catalytic activity and stability in low temperature CO oxidation under moisture conditions.

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