Anion exchange membranes with well-defined ion transporting nanochannels via self-assembly of polymerizable ionic liquids

2016 ◽  
Vol 4 (34) ◽  
pp. 13316-13323 ◽  
Author(s):  
Xinpei Gao ◽  
Fei Lu ◽  
Bin Dong ◽  
Aoli Wu ◽  
Na Sun ◽  
...  

We present a facile method to construct highly ordered and well-defined ionic channels in anion exchange membranes via the self-organization of polymerizable amphiphilic ionic liquids.

2019 ◽  
Vol 573 ◽  
pp. 595-601 ◽  
Author(s):  
Qianqian Ge ◽  
Xian Liang ◽  
Liang Ding ◽  
Jianqiu Hou ◽  
Jibin Miao ◽  
...  

2021 ◽  
Vol 12 (1) ◽  
pp. 270-281
Author(s):  
Stefan Bitter ◽  
Moritz Schlötter ◽  
Markus Schilling ◽  
Marina Krumova ◽  
Sebastian Polarz ◽  
...  

The self-organization properties of a stimuli responsive amphiphile can be altered by subjecting the paramagnetic oxidized form to a magnetic field of 0.8 T and monitored in real time by coupling optical birefringence with dynamic light scattering.


Author(s):  
Alejandro Rodríguez ◽  
Alexander Grushin ◽  
James A. Reggia

Drawing inspiration from social interactions in nature, swarm intelligence has presented a promising approach to the design of complex systems consisting of numerous, simple parts, to solve a wide variety of problems. Swarm intelligence systems involve highly parallel computations across space, based heavily on the emergence of global behavior through local interactions of components. This has a disadvantage as the desired behavior of a system becomes hard to predict or design. Here we describe how to provide greater control over swarm intelligence systems, and potentially more useful goal-oriented behavior, by introducing hierarchical controllers in the components. This allows each particle-like controller to extend its reactive behavior in a more goal-oriented style, while keeping the locality of the interactions. We present three systems designed using this approach: a competitive foraging system, a system for the collective transport and distribution of goods, and a self-assembly system capable of creating complex 3D structures. Our results show that it is possible to guide the self-organization process at different levels of the designated task, suggesting that self-organizing behavior may be extensible to support problem solving in various contexts.


Entropy ◽  
2020 ◽  
Vol 22 (2) ◽  
pp. 251 ◽  
Author(s):  
Maximino Aldana ◽  
Miguel Fuentes-Cabrera ◽  
Martín Zumaya

Self-assembly is a spontaneous process through which macroscopic structures are formed from basic microscopic constituents (e.g., molecules or colloids). By contrast, the formation of large biological molecules inside the cell (such as proteins or nucleic acids) is a process more akin to self-organization than to self-assembly, as it requires a constant supply of external energy. Recent studies have tried to merge self-assembly with self-organization by analyzing the assembly of self-propelled (or active) colloid-like particles whose motion is driven by a permanent source of energy. Here we present evidence that points to the fact that self-propulsion considerably enhances the assembly of polymers: self-propelled molecules are found to assemble faster into polymer-like structures than non self-propelled ones. The average polymer length increases towards a maximum as the self-propulsion force increases. Beyond this maximum, the average polymer length decreases due to the competition between bonding energy and disruptive forces that result from collisions. The assembly of active molecules might have promoted the formation of large pre-biotic polymers that could be the precursors of the informational polymers we observe nowadays.


RSC Advances ◽  
2015 ◽  
Vol 5 (78) ◽  
pp. 63732-63737 ◽  
Author(s):  
Xinpei Gao ◽  
Fei Lu ◽  
Bin Dong ◽  
Tao Zhou ◽  
Yizhi Liu ◽  
...  

Nanostructured proton conductors having hexagonal and cubic structures were constructed by the self-assembly of zwitterionic ionic liquids. These nanostructured proton conductors all exhibited an assembled-structure dependent proton conduction behavior.


RSC Advances ◽  
2016 ◽  
Vol 6 (99) ◽  
pp. 96768-96777 ◽  
Author(s):  
Yuhao Chu ◽  
Yuenan Chen ◽  
Nanjun Chen ◽  
Fanghui Wang ◽  
Hong Zhu

Recently a new method for increasing the ion conductivity of anion exchange membranes (AEM) was developed based on the novel materials ionic liquids (ILs).


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