A bifunctional metal–organic framework featuring the combination of open metal sites and Lewis basic sites for selective gas adsorption and heterogeneous cascade catalysis

2016 ◽  
Vol 4 (39) ◽  
pp. 15240-15246 ◽  
Author(s):  
Hongming He ◽  
Fuxing Sun ◽  
Briana Aguila ◽  
Jason A. Perman ◽  
Shengqian Ma ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Basic Sites ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework ◽  
Cascade Catalysis

A bifunctional MOF featuring the combination of open metal sites (Zn2+) and Lewis basic sites (–NH2) has been constructed for selective gas adsorption and heterogeneous cascade catalysis.

Triple Framework Interpenetration and Immobilization of Open Metal Sites within a Microporous Mixed Metal–Organic Framework for Highly Selective Gas Adsorption

2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Mixed Metal ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Organic Framework

Merging open metal sites and Lewis basic sites in a NbO-type metal–organic framework for improved C2H2/CH4 and CO2/CH4 separation

2015 ◽  
Vol 44 (33) ◽  
pp. 14823-14829 ◽  
Author(s):  
Chengling Song ◽  
Jiayi Hu ◽  
Yajing Ling ◽  
Yunlong Feng ◽  
De-Li Chen ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Framework ◽  
Gas Mixtures ◽  
Basic Sites ◽  
Basic Nitrogen ◽  
Nitrogen Donor ◽  
Open Metal Sites ◽  
Metal Organic ◽  
Copper Sites ◽  
Organic Framework

A new NbO-type metal–organic framework ZJNU-47a incorporating Lewis acidic copper sites and Lewis basic nitrogen donor sites exhibits better performance than the isostructural NOTT-101a in the separation of C2H2/CH4 and CO2/CH4 gas mixtures at room temperature.

Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains

CrystEngComm ◽  
2013 ◽  
Vol 15 (45) ◽  
pp. 9688 ◽  
Author(s):  
Yangyang Liu ◽  
Ying-Pin Chen ◽  
Tian-Fu Liu ◽  
Andrey A. Yakovenko ◽  
Aaron M. Raiff ◽  
...  
Keyword(s):  
Phase Transition ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Magnesium Metal ◽  
Metal Organic ◽  
Organic Framework

Enhanced performance in gas adsorption and Li ion batteries by docking Li+ in a crown ether-based metal–organic framework

2016 ◽  
Vol 52 (14) ◽  
pp. 3003-3006 ◽  
Author(s):  
Linyi Bai ◽  
Binbin Tu ◽  
Yi Qi ◽  
Qiang Gao ◽  
Dong Liu ◽  
...  
Keyword(s):  
Crown Ether ◽  
Metal Ions ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Li Ion Batteries ◽  
Metal Organic ◽  
Li Ion ◽  
Organic Framework

Incorporating supramolecular recognition units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance.

The cascade catalysis of the porphyrinic zirconium metal-organic framework PCN-224-Cu for CO2 conversion to alcohols

2021 ◽  
Author(s):  
Shi-Chao Qi ◽  
Zhi-Hui Yang ◽  
Rong-Rong Zhu ◽  
Xiao-Jie Lu ◽  
Ding-Ming Xue ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Co2 Conversion ◽  
Cascade System ◽  
The Past ◽  
Highly Efficient ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Organic Framework ◽  
Cascade Catalysis

Reproducing the highly efficient catalytic cascade system to mimic life behaviors in vitro has been intensively investigated over the past few decades. However, except the biocatalysis with enzymes, most chemocatalytic...

An Uncommon Carboxyl-Decorated Metal-Organic Framework with Selective Gas Adsorption and Catalytic Conversion of CO2

2017 ◽  
Vol 24 (4) ◽  
pp. 865-871 ◽  
Author(s):  
Yong-Zhi Li ◽  
Hai-Hua Wang ◽  
Hong-Yun Yang ◽  
Lei Hou ◽  
Yao-Yu Wang ◽  
...  
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Catalytic Conversion ◽  
Metal Organic ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document