Microporous polyimides with functional groups for the adsorption of carbon dioxide and organic vapors

2016 ◽  
Vol 4 (29) ◽  
pp. 11453-11461 ◽  
Author(s):  
Guiyang Li ◽  
Biao Zhang ◽  
Jun Yan ◽  
Zhonggang Wang
Keyword(s):  
Carbon Dioxide ◽  
Functional Groups ◽  
Gas Storage ◽  
High Density ◽  
Organic Vapors

Microporous polyimides containing a high density of trifluoromethyls or benzophenone with uniform pores are synthesized, which possess high uptakes for CO2and aromatic and aliphatic vapors, exhibiting potential in gas storage and recovery of toxic organic vapors.

Modification of Activated Carbon from Biomass Nypa and Amine Functional Groups as Carbon Dioxide Adsorbent

2017 ◽  
Vol 28 (Suppl. 1) ◽  
pp. 227-240 ◽  
Author(s):  
Nur 'Izzati A. Ghani ◽  
◽  
Nur Yusra Mt Yusuf ◽  
Wan Nor Roslam Wan Isahak ◽  
Mohd Shahbuddin Masdar ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbon ◽  
Functional Groups

Atmospheric preservation of CH4 hydrate above ice point: A potential application for high-density natural gas storage under moderate conditions

Fuel ◽  
2021 ◽  
Vol 293 ◽  
pp. 120482 ◽  
Author(s):  
Shenglong Wang ◽  
Jian Xu ◽  
Shuanshi Fan ◽  
Yanhong Wang ◽  
Xuemei Lang ◽  
...  
Keyword(s):  
Natural Gas ◽  
Potential Application ◽  
Gas Storage ◽  
High Density ◽  
Natural Gas Storage

A phenanthroline-based porous organic polymer for the iridium-catalyzed hydrogenation of carbon dioxide to formate

2019 ◽  
Vol 7 (23) ◽  
pp. 14019-14026 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Sungho Yoon
Keyword(s):  
Carbon Dioxide ◽  
Functional Groups ◽  
Single Site ◽  
Organic Polymer ◽  
Selective Catalyst ◽  
Porous Organic Polymer ◽  
Highly Active ◽  
First Time ◽  
Hydrogenation Of Carbon Dioxide ◽  
Hydrogenation Of Co

A novel phenanthroline-functionalized porous organic polymer (phen-POP) has been designed, and prepared for the first time without other reactive functional groups in the polymer skeleton. Post-synthetic metalation of phen-POP with IrCl3 afforded a single-site, highly active and selective catalyst for the hydrogenation of CO2 to formate.

scholarly journals CVD Synthesis, Functionalization and CO2 Adsorption Attributes of Multiwalled Carbon Nanotubes

Processes ◽  
2019 ◽  
Vol 7 (9) ◽  
pp. 634 ◽  
Author(s):  
Shazia Shukrullah ◽  
Muhammad Yasin Naz ◽  
Norani M. Mohamed ◽  
Khalid A. Ibrahim ◽  
Nasser M. AbdEl-Salam ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Carbon Nanotubes ◽  
Adsorption Capacity ◽  
Multiwalled Carbon Nanotubes ◽  
Functional Groups ◽  
Co2 Adsorption ◽  
Breakthrough Curves ◽  
Multiwalled Carbon ◽  
Amine Functionalized ◽  
Co2 Adsorption Capacity

Carbon dioxide is one of the major greenhouse gases and a leading source of global warming. Several adsorbent materials are being tested for removal of carbon dioxide (CO2) from the atmosphere. The use of multiwalled carbon nanotubes (MWCNTs) as a CO2 adsorbent material is a relatively new research avenue. In this study, Fe2O3/Al2O3 composite catalyst was used to synthesize MWCNTs by cracking ethylene gas molecules in a fluidized bed chemical vapor deposition (CVD) chamber. These nanotubes were treated with H2SO4/HNO3 solution and functionalized with 3-aminopropyl-triethoxysilane (APTS). Chemical modification of nanotubes removed the endcaps and introduced some functional groups along the sidewalls at defected sites. The functionalization of nanotubes with amine introduced carboxylic groups on the tube surface. These functional groups significantly enhance the surface wettability, hydrophilicity and CO2 adsorption capacity of MWCNTs. The CO2 adsorption capacity of as-grown and amine-functionalized CNTs was computed by generating their breakthrough curves. BELSORP-mini equipment was used to generate CO2 breakthrough curves. The oxidation and functionalization of MWCNTs revealed significant improvement in their adsorption capacity. The highest CO2 adsorption of 129 cm3/g was achieved with amine-functionalized MWCNTs among all the tested samples.

Tetraphenyladamantane-Based Microporous Polybenzimidazoles for Adsorption of Carbon Dioxide, Hydrogen, and Organic Vapors

2015 ◽  
Vol 119 (23) ◽  
pp. 13080-13087 ◽  
Author(s):  
Biao Zhang ◽  
Guiyang Li ◽  
Jun Yan ◽  
Zhonggang Wang
Keyword(s):  
Carbon Dioxide ◽  
Organic Vapors

scholarly journals Carbon Dioxide Capture in Homogeneous and Heterogeneous Surfaces of Porous Silica Glass

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1260
Author(s):  
Chontira Boonfung ◽  
Chaiyot Tangsathitkulchai ◽  
Atichat Wongkoblap
Keyword(s):  
Carbon Dioxide ◽  
Functional Groups ◽  
Adsorption Isotherms ◽  
Silica Glass ◽  
Surface Defects ◽  
Porous Silica ◽  
Surface Heterogeneity ◽  
Slit Pore ◽  
Porous Silica Glass ◽  
Carbon Dioxide Co2

Experimental and simulation studies for carbon dioxide (CO2) adsorption on porous silica glass were performed to reveal how surface heterogeneity can affect the adsorption mechanism of CO2. In performing the simulation, the structure of porous silica glass was modeled as a slit pore consisting of parallel walls of connected SiO4 units. The adsorption isotherms of CO2 at 283 K were generated for a series of pore widths using a Monte Carlo ensemble. The defective surfaces created by random removal of surface atoms and the surfaces containing hydroxyl functional groups were chosen to represent the surface heterogeneity for the simulation tasks. The isotherms derived for the defective surfaces showed a rapid adsorption at low pressures because of the stronger interaction between the rough nonuniform surfaces and CO2 molecules. For the role of surface functional groups, the adsorption isotherms dramatically increased with an increasing number of functional groups. The amount of CO2 adsorbed for randomly placed functional groups was greater than that for the presence of functional groups at the pore edges. The proper control of surface heterogeneity by manipulating both the amounts of hydroxyl surface groups and surface defects should help enhance the efficient capture of CO2 in porous silica glass.

Micropore characterization of activated carbons of respirator cartridges with argon, carbon dioxide, and organic vapors of different vapor pressures

Carbon ◽  
2015 ◽  
Vol 94 ◽  
pp. 781-791 ◽  
Author(s):  
Florence Janvier ◽  
Ludovic Tuduri ◽  
Daniel Cossement ◽  
Daniel Drolet ◽  
Jaime Lara
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbons ◽  
Vapor Pressures ◽  
Organic Vapors
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