Nitrogen-doped mesoporous carbon nanosheet/carbon nanotube hybrids as metal-free bi-functional electrocatalysts for water oxidation and oxygen reduction

2016 ◽  
Vol 4 (34) ◽  
pp. 13133-13141 ◽  
Author(s):  
Xinzhe Li ◽  
Yiyun Fang ◽  
Shiling Zhao ◽  
Juntian Wu ◽  
Feng Li ◽  
...  

Nitrogen-doped mesoporous carbon nanosheet/carbon nanotube hybrids are prepared. This metal-free catalyst exhibits remarkable catalytic performance for both OER and ORR in 0.1 M KOH solution.

RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43091-43097 ◽  
Author(s):  
Yonghyun Kwon ◽  
Kyoungsoo Kim ◽  
Ryong Ryoo

Nitrogen-doped zeolite-templated carbon having 3-dimensionally microporous structure exhibited low surface work function and high catalytic performance for oxygen reduction.


ChemNanoMat ◽  
2018 ◽  
Vol 4 (9) ◽  
pp. 954-963 ◽  
Author(s):  
Yu Wang ◽  
Xu Jin ◽  
Ying Pan ◽  
Jianming Li ◽  
Ningning Guo ◽  
...  

Carbon ◽  
2017 ◽  
Vol 114 ◽  
pp. 177-186 ◽  
Author(s):  
Tingsheng Zhou ◽  
Yao Zhou ◽  
Ruguang Ma ◽  
Zhenzhen Zhou ◽  
Guanghui Liu ◽  
...  

2014 ◽  
Vol 70 (10) ◽  
pp. 1610-1616 ◽  
Author(s):  
Huanan Wu ◽  
Min Lu ◽  
Lin Guo ◽  
Leonard Guan Hong Bay ◽  
Zheng Zhang ◽  
...  

Polyelectrolyte–single wall carbon nanotube (SCNT) composites are prepared by a solution-based method and used as metal-free cathode catalysts for oxygen reduction reaction (ORR) in air-cathode microbial fuel cells (MFCs). In this study, two types of polyelectrolytes, polydiallyldimethylammonium chloride (PDDA) and poly[bis(2-chloroethyl)ether-alt-1,3-bis[3-(dimethylamino)propyl]urea] (PEPU) are applied to decorate the SCNTs and the resulting catalysts exhibit remarkable catalytic ability toward ORR in MFC applications. The enhanced catalytic ability could be attributed to the positively charged quaternary ammonium sites of polyelectrolytes, which increase the oxygen affinity of SCNTs and reduce activation energy in the oxygen reduction process. It is also found that PEPU–SCNT composite-based MFCs show efficient performance with maximum power density of 270.1 mW m−2, comparable to MFCs with the benchmark Pt/C catalyst (375.3 mW m−2), while PDDA–SCNT composite-based MFCs produce 188.9 mW m−2. These results indicate that PEPU–SCNT and PDDA–SCNT catalysts are promising candidates as metal-free cathode catalysts for ORR in MFCs and could facilitate MFC scaling up and commercialization.


RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 25051-25056 ◽  
Author(s):  
Yanhong Yin ◽  
Hengbo Zhang ◽  
Rongzhen Gao ◽  
Aili Wang ◽  
Xinxin Mao ◽  
...  

In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach.


Sign in / Sign up

Export Citation Format

Share Document