Rational design of cobalt–chromium layered double hydroxide as a highly efficient electrocatalyst for water oxidation

2016 ◽  
Vol 4 (29) ◽  
pp. 11292-11298 ◽  
Author(s):  
Chenlong Dong ◽  
Xiaotao Yuan ◽  
Xin Wang ◽  
Xiangye Liu ◽  
Wujie Dong ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Water Oxidation ◽  
High Performance ◽  
Rational Design ◽  
Cost Effective ◽  
Cobalt Chromium ◽  
Electrochemical Water Splitting ◽  
Double Hydroxide

The design of a high performance, stable and cost-effective electrocatalyst for oxygen evolution is crucial for H2 production from electrochemical water splitting.

Boosting Oxygen Evolution of Layered Double Hydroxide through Electronic Coupling with Ultralow Noble Metal

2022 ◽  
Author(s):  
Zhao Li ◽  
Dongsheng Liu ◽  
Xinhua Lu ◽  
Minglin Du ◽  
Zhenyang Chen ◽  
...  
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Water Oxidation ◽  
Cost Effective ◽  
Electronic Coupling ◽  
Rate Determining Step ◽  
The Cost ◽  
Double Hydroxide ◽  
Splitting Process

Electrocatalytic water oxidation is a rate-determining step in the water splitting process, however, its efficiency is significantly hampered by the limitations of the cost-effective electrocatalysts. Here, an advanced ultralow iridium...

Facile construction of self-supported Fe-doped Ni3S2 nanoparticle arrays for ultralow-overpotential oxygen evolution reaction

Nanoscale ◽  
2020 ◽  
Author(s):  
Ning Xie ◽  
Dong-Dong Ma ◽  
Xintao Wu ◽  
Qi-Long Zhu
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Water Oxidation ◽  
High Performance ◽  
Cost Effective ◽  
Nanoparticle Arrays ◽  
Overall Water Splitting ◽  
Construction Of Self ◽  
One Step

Constructing high-performance and cost-effective electrocatalysts for water oxidation, particularly for overall water splitting is extremely needed, whereas still challenging. Herein, based on an economical and facile one-step surface sulfurization strategy,...

Hierarchically porous FeNi3@FeNi layered double hydroxide nanostructures: One-step fast electrodeposition and highly efficient electrocatalytic performances for overall water splitting

2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hierarchically Porous ◽  
One Step ◽  
Double Hydroxide

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...

scholarly journals Engineering single-atomic ruthenium catalytic sites on defective nickel-iron layered double hydroxide for overall water splitting

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Panlong Zhai ◽  
Mingyue Xia ◽  
Yunzhen Wu ◽  
Guanghui Zhang ◽  
Junfeng Gao ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Layered Double Hydroxide ◽  
Hydrogen Evolution Reaction ◽  
Active Sites ◽  
Density Functional ◽  
Rational Design ◽  
Single Atom ◽  
Nickel Iron ◽  
Double Hydroxide

AbstractRational design of single atom catalyst is critical for efficient sustainable energy conversion. However, the atomic-level control of active sites is essential for electrocatalytic materials in alkaline electrolyte. Moreover, well-defined surface structures lead to in-depth understanding of catalytic mechanisms. Herein, we report a single-atomic-site ruthenium stabilized on defective nickel-iron layered double hydroxide nanosheets (Ru1/D-NiFe LDH). Under precise regulation of local coordination environments of catalytically active sites and the existence of the defects, Ru1/D-NiFe LDH delivers an ultralow overpotential of 18 mV at 10 mA cm−2 for hydrogen evolution reaction, surpassing the commercial Pt/C catalyst. Density functional theory calculations reveal that Ru1/D-NiFe LDH optimizes the adsorption energies of intermediates for hydrogen evolution reaction and promotes the O–O coupling at a Ru–O active site for oxygen evolution reaction. The Ru1/D-NiFe LDH as an ideal model reveals superior water splitting performance with potential for the development of promising water-alkali electrocatalysts.

scholarly journals A ruthenium-based catalyst on carbon electrodes for electrochemical water splitting

2021 ◽  
Author(s):  
Lin Li ◽  
Biswanath Das ◽  
Ahibur Rahaman ◽  
Andrey Shatskiy ◽  
Fei Ye ◽  
...  
Keyword(s):  
Water Splitting ◽  
Water Oxidation ◽  
State Of The Art ◽  
Cost Effective ◽  
Molecular Catalyst ◽  
Electrolysis Cells ◽  
Multi Walled Carbon Nanotubes ◽  
Energy Economy ◽  
Electrochemical Water Splitting ◽  
Walled Carbon Nanotubes

Electrochemical water splitting constitutes one of the most promising strategies for converting water into hydrogen-based fuels, and this technology is predicted to play a key role in our transition towards a carbon-neutral energy economy. To enable the design of cost-effective electrolysis cells based on this technology, new and more efficient anodes with augmented water splitting activity and stability will be required. Herein, we report an active molecular Ru-based catalyst for electrochemically-driven water oxidation and two simple methods for preparing anodes by attaching this catalyst onto multi-walled carbon nanotubes. The anodes modified with the molecular catalyst were characterized by a broad toolbox of microscopy and spectroscope techniques, and interestingly no RuO2 formation was detected during electrocatalysis over 4 h. These results demonstrate that the herein presented strategy can be used to prepare anodes that rival the performance of state-of-the-art metal oxide anodes.

Amorphous NiFe layered double hydroxide nanosheets decorated on 3D nickel phosphide nanoarrays: a hierarchical core–shell electrocatalyst for efficient oxygen evolution

2018 ◽  
Vol 6 (28) ◽  
pp. 13619-13623 ◽  
Author(s):  
Luo Yu ◽  
Haiqing Zhou ◽  
Jingying Sun ◽  
Ishwar Kumar Mishra ◽  
Dan Luo ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Water Oxidation ◽  
Core Shell ◽  
Nickel Phosphide ◽  
Double Hydroxide

Amorphous NiFe LDH nanosheets were decorated on nickel phosphide nanoarrays to form a 3D core–shell electrocatalyst for efficient water oxidation.

Template-directed synthesis of sulphur doped NiCoFe layered double hydroxide porous nanosheets with enhanced electrocatalytic activity for the oxygen evolution reaction

2018 ◽  
Vol 6 (7) ◽  
pp. 3224-3230 ◽  
Author(s):  
Li-Ming Cao ◽  
Jia-Wei Wang ◽  
Di-Chang Zhong ◽  
Tong-Bu Lu
Keyword(s):  
Water Splitting ◽  
Oxygen Evolution ◽  
Layered Double Hydroxide ◽  
Oxygen Evolution Reaction ◽  
Electrocatalytic Activity ◽  
Hydrogen Energy ◽  
Highly Efficient ◽  
Porous Nanosheets ◽  
Directed Synthesis ◽  
Double Hydroxide

The development of readily available, highly efficient and stable electrocatalysts for the oxygen evolution reaction (OER) is extremely significant to facilitate water splitting for the generation of clean hydrogen energy.

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