Nanoporous Mn-based electrocatalysts through thermal conversion of cyano-bridged coordination polymers toward ultra-high efficiency hydrogen peroxide production

2016 ◽  
Vol 4 (23) ◽  
pp. 9266-9274 ◽  
Author(s):  
Mohamed B. Zakaria ◽  
Cuiling Li ◽  
Malay Pramanik ◽  
Yoshihiro Tsujimoto ◽  
Ming Hu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Polymers ◽  
High Efficiency ◽  
Thermal Conversion ◽  
Hydrogen Peroxide Production

Nanoporous Mn-based electrocatalysts are realized through thermal conversion of cyano-bridged coordination polymers.

Trace water triggers high-efficiency photocatalytic hydrogen peroxide production

2021 ◽  
Author(s):  
Zaixiang Xu ◽  
Yang Li ◽  
Yongyong Cao ◽  
Renfeng Du ◽  
Zhikang Bao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
High Efficiency ◽  
Hydrogen Peroxide Production ◽  
Trace Water

scholarly journals Kinetic resolution of indolines by asymmetric hydroxylamine formation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Gang Wang ◽  
Ran Lu ◽  
Chuangchuang He ◽  
Lei Liu
Keyword(s):  
Hydrogen Peroxide ◽  
Chemical Synthesis ◽  
Late Stage ◽  
Kinetic Resolution ◽  
High Efficiency ◽  
Bond Formation ◽  
Bioactive Molecules ◽  
Environmentally Benign ◽  
Secondary Amines

AbstractCatalytic kinetic resolution of amines represents a longstanding challenge in chemical synthesis. Here, we described a kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation. The economic and practical titanium-catalyzed asymmetric oxygenation with environmentally benign hydrogen peroxide as oxidant is applicable to a range of racemic indolines with multiple stereocenters and diverse substituent patterns in high efficiency with efficient chemoselectivity and enantio-discrimination. Late-stage asymmetric oxygenation of bioactive molecules that are otherwise difficult to synthesize was also explored.

Photoelectrochemical Hydrogen Peroxide Production from Water on a WO3/BiVO4Photoanode and from O2on an Au Cathode Without External Bias

2017 ◽  
Vol 12 (10) ◽  
pp. 1111-1119 ◽  
Author(s):  
Kojiro Fuku ◽  
Yuta Miyase ◽  
Yugo Miseki ◽  
Takashi Funaki ◽  
Takahiro Gunji ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Hydrogen Peroxide Production ◽  
External Bias
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