Going beyond the classical amphiphilicity paradigm: the self-assembly of completely hydrophobic polymers into free-standing sheets and hollow nanostructures in solvents of variable quality

Soft Matter ◽  
2016 ◽  
Vol 12 (22) ◽  
pp. 5011-5021 ◽  
Author(s):  
Huanting Huang ◽  
Yin Liao ◽  
Weifeng Bu ◽  
Wenjie Wang ◽  
Jing Zhi Sun
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Free Standing ◽  
Hydrophobic Polymers ◽  
Hollow Nanostructures ◽  
Variable Quality

Multifunctional Free-Standing Membrane from the Self-assembly of Ultralong MnO2 Nanowires

2013 ◽  
Vol 5 (15) ◽  
pp. 7458-7464 ◽  
Author(s):  
Bang Lan ◽  
Lin Yu ◽  
Ting Lin ◽  
Gao Cheng ◽  
Ming Sun ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Free Standing ◽  
Mno2 Nanowires

Stepwise self-assembly of a block copolymer–platinum(ii) complex hybrid in solvents of variable quality: from worm-like micelles to free-standing sheets to vesicle-like nanostructures

Soft Matter ◽  
2017 ◽  
Vol 13 (27) ◽  
pp. 4791-4798 ◽  
Author(s):  
Nijuan Liu ◽  
Qun He ◽  
Yongyue Wang ◽  
Weifeng Bu
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Shell Structures ◽  
Core Shell ◽  
Free Standing ◽  
Complex Hybrid ◽  
Form Star ◽  
Variable Quality

Worm-like micelles of a block copolymer–platinum(ii) hybrid evolve into sheet- and vesicle-like nanostructures in solvents of weakened quality. The worm-like micelles snap off to form star micelles or short worms that still hold their core–shell structures.

scholarly journals Monolayer Nanosheets Formed by Liquid Exfoliation of Charge-as-Sisted Hydrogen-Bonded Frameworks

2020 ◽  
Author(s):  
Josh Nicks ◽  
Stephanie Boer ◽  
Nicholas White ◽  
jonathan Foster
Keyword(s):  
Self Assembly ◽  
Organic Dye ◽  
The Self ◽  
Two Dimensional ◽  
Free Standing ◽  
Liquid Exfoliation ◽  
New Family ◽  
Two Dimensional Materials ◽  
Ultrasound Assisted ◽  
Hydrogen Bonded

Hydrogen-bonded organic frameworks (HOFs) are a diverse and tunable class of materials, but their potential as free-standing two-dimensional nanomaterials has yet to be explored. Here we report the self-assembly of two layered hydrogen-bonded frameworks based on strong, charge-assisted hydrogen-bonding between carboxylate and amidinium groups. Ultrasound-assisted liquid exfoliation of both materials readily produces monolayer hydrogen-bonded organic nanosheets (HONs) with micron-sized lateral dimensions. The HONs show remarkable stability and maintain their extended crystallinity and monolayer structures even after being suspended in water at 80 °C for three days. These systems also exhibit efficient fluorescence quenching of an organic dye in organic solvents, superior to the quenching ability of the bulk frameworks. We anticipate that this approach will provide a route towards a diverse new family of molecular two-dimensional materials with great potential for use in separation, sensing, catalysis, delivery, and electronics materials applications.

scholarly journals Monolayer Nanosheets Formed by Liquid Exfoliation of Charge-as-Sisted Hydrogen-Bonded Frameworks

2020 ◽  
Author(s):  
Josh Nicks ◽  
Stephanie Boer ◽  
Nicholas White ◽  
jonathan Foster
Keyword(s):  
Self Assembly ◽  
Organic Dye ◽  
The Self ◽  
Two Dimensional ◽  
Free Standing ◽  
Liquid Exfoliation ◽  
New Family ◽  
Two Dimensional Materials ◽  
Ultrasound Assisted ◽  
Hydrogen Bonded

Hydrogen-bonded organic frameworks (HOFs) are a diverse and tunable class of materials, but their potential as free-standing two-dimensional nanomaterials has yet to be explored. Here we report the self-assembly of two layered hydrogen-bonded frameworks based on strong, charge-assisted hydrogen-bonding between carboxylate and amidinium groups. Ultrasound-assisted liquid exfoliation of both materials readily produces monolayer hydrogen-bonded organic nanosheets (HONs) with micron-sized lateral dimensions. The HONs show remarkable stability and maintain their extended crystallinity and monolayer structures even after being suspended in water at 80 °C for three days. These systems also exhibit efficient fluorescence quenching of an organic dye in organic solvents, superior to the quenching ability of the bulk frameworks. We anticipate that this approach will provide a route towards a diverse new family of molecular two-dimensional materials with great potential for use in separation, sensing, catalysis, delivery, and electronics materials applications.

Self-Assembly of Polyoxometalate-Based Starlike Polymers in Solvents of Variable Quality: From Free-Standing Sheet to Vesicle

2014 ◽  
Vol 47 (20) ◽  
pp. 7158-7168 ◽  
Author(s):  
Yin Liao ◽  
Nijuan Liu ◽  
Qian Zhang ◽  
Weifeng Bu
Keyword(s):  
Self Assembly ◽  
Free Standing ◽  
Variable Quality

A Comparative Study on the Self-Assembly of Peptide TGV-9 by In Situ Atomic Force Microscopy

2020 ◽  
Vol 26 (2) ◽  
pp. 319-325
Author(s):  
Yaping Li ◽  
Na Li ◽  
Lei Wang ◽  
Qinhua Lu ◽  
Xiang Ji ◽  
...  
Keyword(s):  
Atomic Force Microscopy ◽  
Self Assembly ◽  
The Self ◽  
Peptide Sequence ◽  
Bulk Solution ◽  
Free Standing ◽  
Atomic Lattice ◽  
Force Microscopy ◽  
Atomic Force

AbstractPrevious studies of amyloid diseases reported that the aggregating proteins share a similar conserved peptide sequence which can form the cross-β-sheet-containing nanostructures like nanofilaments. The template-assisted self-assembly (TASA) of peptides on inorganic substrates with different hydrophilicity could be an alternative approach to shed light on the fibrillization mechanism of proteins/peptides in vivo. To figure out the effect of interfaces on amyloid aggregation, we herein employed in situ atomic force microscopy (AFM) to investigate the self-assembling of a Parkinson disease-related core peptide sequence (TGV-9) on a hydrophobic liquid–solid interface via real-time observation of the dynamic fibrillization process. The results show that TGV-9 forms one-dimensional nanostructures on the surface of highly ordered pyrolytic graphite (HOPG) with three preferred growth orientations, which are consistent with the atomic lattice of HOPG, indicating an epitaxial growth or TASA. Conversely, the nanostructures formed in bulk solution can be free-standing nanofilaments, and the fibrillization mechanism is different from that on HOPG. These results could not only deepen the understanding of the protein/peptide aggregation mechanism but also benefit for the early diagnosis and clinic treatment of related diseases.

The Nature of Rapidly Extracted Phycocyanin from the Blue-Green Alga Plectonema Boryanum

1971 ◽  
Vol 29 ◽  
pp. 366-367
Author(s):  
M. Kessel ◽  
R. MacColl
Keyword(s):  
Self Assembly ◽  
Analytical Ultracentrifugation ◽  
Uranyl Acetate ◽  
The Self ◽  
Major Protein ◽  
Subunit Structure ◽  
Blue Green Alga ◽  
Thin Sections ◽  
Blue Green Algae ◽  
Cacodylate Buffer

The major protein of the blue-green algae is the biliprotein, C-phycocyanin (Amax = 620 nm), which is presumed to exist in the cell in the form of distinct aggregates called phycobilisomes. The self-assembly of C-phycocyanin from monomer to hexamer has been extensively studied, but the proposed next step in the assembly of a phycobilisome, the formation of 19s subunits, is completely unknown. We have used electron microscopy and analytical ultracentrifugation in combination with a method for rapid and gentle extraction of phycocyanin to study its subunit structure and assembly.To establish the existence of phycobilisomes, cells of P. boryanum in the log phase of growth, growing at a light intensity of 200 foot candles, were fixed in 2% glutaraldehyde in 0.1M cacodylate buffer, pH 7.0, for 3 hours at 4°C. The cells were post-fixed in 1% OsO4 in the same buffer overnight. Material was stained for 1 hour in uranyl acetate (1%), dehydrated and embedded in araldite and examined in thin sections.

Interrelationship of the cellular distribution and secretion of regular structure (RS) protein in Bacillus licheniformis nm 105

1992 ◽  
Vol 50 (1) ◽  
pp. 712-713
Author(s):  
Xiaorong Zhu ◽  
Richard McVeigh ◽  
Bijan K. Ghosh
Keyword(s):  
Alkaline Phosphatase ◽  
Bacillus Licheniformis ◽  
Self Assembly ◽  
Gel Electrophoresis ◽  
Culture Supernatant ◽  
Regular Structure ◽  
The Self ◽  
Cellular Distribution ◽  
Structural Protein ◽  
Laboratory Cultures

A mutant of Bacillus licheniformis 749/C, NM 105 exhibits some notable properties, e.g., arrest of alkaline phosphatase secretion and overexpression and hypersecretion of RS protein. Although RS is known to be widely distributed in many microbes, it is rarely found, with a few exceptions, in laboratory cultures of microorganisms. RS protein is a structural protein and has the unusual properties to form aggregate. This characteristic may have been responsible for the self assembly of RS into regular tetragonal structures. Another uncommon characteristic of RS is that enhanced synthesis and secretion which occurs when the cells cease to grow. Assembled RS protein with a tetragonal structure is not seen inside cells at any stage of cell growth including cells in the stationary phase of growth. Gel electrophoresis of the culture supernatant shows a very large amount of RS protein in the stationary culture of the B. licheniformis. It seems, Therefore, that the RS protein is cotranslationally secreted and self assembled on the envelope surface.

Nanoscale Self-Assembly Using Ion and Electron Beam Techniques: A Rapid Review

MRS Advances ◽  
2020 ◽  
Vol 5 (64) ◽  
pp. 3507-3520
Author(s):  
Chunhui Dai ◽  
Kriti Agarwal ◽  
Jeong-Hyun Cho
Keyword(s):  
Electron Beam ◽  
Self Assembly ◽  
Ion Beam ◽  
Three Dimensional ◽  
The Self ◽  
Stress Generation ◽  
Rapid Review ◽  
High Yield ◽  
3D Nanostructures ◽  
Self Assembled

AbstractNanoscale self-assembly, as a technique to transform two-dimensional (2D) planar patterns into three-dimensional (3D) nanoscale architectures, has achieved tremendous success in the past decade. However, an assembly process at nanoscale is easily affected by small unavoidable variations in sample conditions and reaction environment, resulting in a low yield. Recently, in-situ monitored self-assembly based on ion and electron irradiation has stood out as a promising candidate to overcome this limitation. The usage of ion and electron beam allows stress generation and real-time observation simultaneously, which significantly enhances the controllability of self-assembly. This enables the realization of various complex 3D nanostructures with a high yield. The additional dimension of the self-assembled 3D nanostructures opens the possibility to explore novel properties that cannot be demonstrated in 2D planar patterns. Here, we present a rapid review on the recent achievements and challenges in nanoscale self-assembly using electron and ion beam techniques, followed by a discussion of the novel optical properties achieved in the self-assembled 3D nanostructures.

Bottom-up Evolution from Disks to High-Genus Polymersomes

2018 ◽  
Author(s):  
Claudia Contini ◽  
Russell Pearson ◽  
Linge Wang ◽  
Lea Messager ◽  
Jens Gaitzsch ◽  
...  
Keyword(s):  
Self Assembly ◽  
The Self ◽  
Amphiphilic Copolymers ◽  
Chain Entanglement ◽  
Bottom Up ◽  
New Approach ◽  
High Genus ◽  
Transmission Electron ◽  
Minimal Radius ◽  
Stop Flow

<div><div><div><p>We report the design of polymersomes using a bottom-up approach where the self-assembly of amphiphilic copolymers poly(2-(methacryloyloxy) ethyl phosphorylcholine)–poly(2-(diisopropylamino) ethyl methacrylate) (PMPC-PDPA) into membranes is tuned using pH and temperature. We study this process in detail using transmission electron microscopy (TEM), nuclear magnetic resonance (NMR) spectroscopy, dynamic light scattering (DLS), and stop-flow ab- sorbance disclosing the molecular and supramolecular anatomy of each structure observed. We report a clear evolution from disk micelles to vesicle to high-genus vesicles where each passage is controlled by pH switch or temperature. We show that the process can be rationalised adapting membrane physics theories disclosing important scaling principles that allow the estimation of the vesiculation minimal radius as well as chain entanglement and coupling. This allows us to propose a new approach to generate nanoscale vesicles with genus from 0 to 70 which have been very elusive and difficult to control so far.</p></div></div></div>

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