scholarly journals Steric ploy for alternating donor–acceptor co-assembly and cooperative supramolecular polymerization

2017 ◽  
Vol 8 (2) ◽  
pp. 1040-1045 ◽  
Author(s):  
Saptarshi Chakraborty ◽  
Haridas Kar ◽  
Amrita Sikder ◽  
Suhrit Ghosh
Keyword(s):  
Charge Transfer ◽  
Synergistic Effect ◽  
Charge Transfer Interaction ◽  
Donor Acceptor ◽  
Supramolecular Polymerization

The presence of a bulky peripheral wedge destabilizes the homo-assembly of an amide functionalized acceptor monomer and thereby enables alternating supramolecular copolymerization with an amide appended donor monomer via the synergistic effect of H-bonding and the charge-transfer interaction.

Investigation of Charge-Transfer Interaction in Mixed Stack Donor–Acceptor Cocrystals Toward Tunable Solid-State Emission Characteristics

2018 ◽  
Vol 18 (10) ◽  
pp. 6001-6008 ◽  
Author(s):  
Rabia Usman ◽  
Arshad Khan ◽  
Mingliang Wang ◽  
Yi Luo ◽  
Weiwei Sun ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Solid State ◽  
Emission Characteristics ◽  
Charge Transfer Interaction ◽  
Donor Acceptor

scholarly journals Thermodynamic Consideration of the Charge Transfer Interaction of the Donor: Acceptor Type between Chloranilic Acid and Haloperidol

2004 ◽  
Vol 52 (3) ◽  
pp. 303-306 ◽  
Author(s):  
Anthony Amaechi Attama ◽  
Petra Obioma Nnamani ◽  
Michael Umale Adikwu ◽  
Florence Obianuju Akidi
Keyword(s):  
Charge Transfer ◽  
Chloranilic Acid ◽  
Thermodynamic Consideration ◽  
Charge Transfer Interaction ◽  
Donor Acceptor

scholarly journals Donor–acceptor single cocrystal of coronene and perylene diimide: molecular self-assembly and charge-transfer photoluminescence

RSC Advances ◽  
2017 ◽  
Vol 7 (4) ◽  
pp. 2382-2387 ◽  
Author(s):  
Chen Wang ◽  
Jianlin Wang ◽  
Na Wu ◽  
Miao Xu ◽  
Xiaomei Yang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Organic Semiconductor ◽  
Self Assembly ◽  
Perylene Diimide ◽  
Charge Transfer Interaction ◽  
Donor Acceptor

Organic semiconductor molecules, coronene and perylene diimide, form an alternate stacked cocrystal due to the strong donor–acceptor charge transfer interaction.

Fluorescence Quenching of Aminodiphenylamines with Chloromethanes

2002 ◽  
Vol 67 (8) ◽  
pp. 1154-1164 ◽  
Author(s):  
Nachiappan Radha ◽  
Meenakshisundaram Swaminathan
Keyword(s):  
Charge Transfer ◽  
Fluorescence Quenching ◽  
Ground State ◽  
Rate Constants ◽  
Quenching Mechanism ◽  
Quenching Rate ◽  
Charge Transfer Interaction ◽  
Electronically Excited ◽  
A Charge

The fluorescence quenching of 2-aminodiphenylamine (2ADPA), 4-aminodiphenylamine (4ADPA) and 4,4'-diaminodiphenylamine (DADPA) with tetrachloromethane, chloroform and dichloromethane have been studied in hexane, dioxane, acetonitrile and methanol as solvents. The quenching rate constants for the process have also been obtained by measuring the lifetimes of the fluorophores. The quenching was found to be dynamic in all cases. For 2ADPA and 4ADPA, the quenching rate constants of CCl4 and CHCl3 depend on the viscosity, whereas in the case of CH2Cl2, kq depends on polarity. The quenching rate constants for DADPA with CCl4 are viscosity-dependent but the quenching with CHCl3 and CH2Cl2 depends on the polarity of the solvents. From the results, the quenching mechanism is explained by the formation of a non-emissive complex involving a charge-transfer interaction between the electronically excited fluorophores and ground-state chloromethanes.

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