scholarly journals Palladium-catalyzed regioselective and stereo-invertive ring-opening borylation of 2-arylaziridines with bis(pinacolato)diboron: experimental and computational studies

2016 ◽  
Vol 7 (9) ◽  
pp. 6141-6152 ◽  
Author(s):  
Youhei Takeda ◽  
Akinobu Kuroda ◽  
W. M. C. Sameera ◽  
Keiji Morokuma ◽  
Satoshi Minakata
Keyword(s):  
Ring Opening ◽  
Computational Studies ◽  
Ring Opening Reaction ◽  
Palladium Catalyzed

A palladium catalyzed regioselective borylative ring-opening reaction of 2-arylaziridines to give β-amino-β-arylethylborates was developed.

Palladium-Catalyzed Synthesis of Polysubstituted Pyrazoles by Ring-Opening Reactions of 2H-Azirines with Hydrazones

Synlett ◽  
2020 ◽  
Author(s):  
Jiaan Shao ◽  
Ke Shu ◽  
Wenteng Chen ◽  
Shuangrong Liu ◽  
Huajian Zhu ◽  
...  
Keyword(s):  
Ring Opening ◽  
Chemical Conversion ◽  
Alternative Route ◽  
Ring Opening Reaction ◽  
Ring Opening Reactions ◽  
Palladium Catalyzed ◽  
Plausible Mechanism

AbstractA palladium–catalyzed ring-opening reaction of 2H-azirines with hydrazones has been developed. This protocol provides an alternative route for the construction of various polysubstituted pyrazoles with a wide substrate scope. Moreover, a plausible mechanism is proposed for this reaction, which should further enrich the chemical conversion of 2H-azirines.

Palladium-Catalyzed Asymmetric Ring Opening Reaction of Azabenzonorbornadienes with Aromatic Amines

2015 ◽  
Vol 357 (14-15) ◽  
pp. 3121-3125 ◽  
Author(s):  
Zhiwu Lu ◽  
Jun Wang ◽  
Baiqiu Han ◽  
Sifeng Li ◽  
Yongyun Zhou ◽  
...  
Keyword(s):  
Aromatic Amines ◽  
Ring Opening ◽  
Ring Opening Reaction ◽  
Palladium Catalyzed ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction
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