Poly(oxymethylene) dimethyl ether synthesis – a combined chemical equilibrium investigation towards an increasingly efficient and potentially sustainable synthetic route

2017 ◽  
Vol 2 (1) ◽  
pp. 50-59 ◽  
Author(s):  
M. Ouda ◽  
G. Yarce ◽  
R. J. White ◽  
M. Hadrich ◽  
D. Himmel ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Chemical Equilibrium ◽  
Sustainable Energy ◽  
Synthetic Route ◽  
Energy Carriers ◽  
Platform Chemicals ◽  
Dimethyl Ether Synthesis ◽  
Ether Synthesis

Poly(oxymethylene) dimethyl ethers (denoted as OME) are potential sustainable energy carriers and platform chemicals.

Dimethyl Ether Synthesis Catalysts, Processes and Reactors

2013 ◽  
Vol 2 (1) ◽  
pp. 68-81 ◽  
Author(s):  
Grigore Bozga ◽  
Ioan T. Apan ◽  
Raluca E. Bozga
Keyword(s):  
Dimethyl Ether ◽  
Dimethyl Ether Synthesis ◽  
Synthesis Catalysts ◽  
Ether Synthesis

scholarly journals Intrinsic Kinetics Study of Dimethyl Ether Synthesis from Methanol on γ-Al2O3Catalysts

2008 ◽  
Vol 47 (18) ◽  
pp. 7130-7130 ◽  
Author(s):  
Majid Mollavali ◽  
Fereydoon Yaripour ◽  
Hossein Atashi ◽  
Saeed Sahebdelfar
Keyword(s):  
Dimethyl Ether ◽  
Kinetics Study ◽  
Intrinsic Kinetics ◽  
Dimethyl Ether Synthesis ◽  
Ether Synthesis

Dimethyl ether synthesis via methanol dehydration over Ta-supported catalysts

2019 ◽  
Vol 582 ◽  
pp. 117088 ◽  
Author(s):  
Concepción Herrera ◽  
Marina Cortés-Reyes ◽  
M. Ángeles Larrubia ◽  
M. Vanesa Domínguez-Barroso ◽  
M. Rocío Díaz-Rey ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Supported Catalysts ◽  
Methanol Dehydration ◽  
Dimethyl Ether Synthesis ◽  
Ether Synthesis

Study on Preparation and Catalytic Properties of Pd/γ-Al2O3 Catalysts in One-Step Synthesis of Dimethyl Ether

2011 ◽  
Vol 66-68 ◽  
pp. 1404-1409 ◽  
Author(s):  
Rui Zhi Chu ◽  
Zhong Cai Zhang ◽  
Ya Fei Liu ◽  
Xian Liang Meng ◽  
Zhi Min Zong ◽  
...  
Keyword(s):  
Dimethyl Ether ◽  
Catalytic Performance ◽  
Acid Sites ◽  
Co Conversion ◽  
Dimethyl Ether Synthesis ◽  
Acidic Sites ◽  
One Step ◽  
Space Time Yield ◽  
Ether Synthesis ◽  
Synthesis Of Dimethyl Ether

A series of Pd/γ-Al2O3 catalysts with different additons of Pd were prepared by impregnation. The effect of calcination condition and Pd loading on catalytic performance of catalysts for one-step dimethyl ether synthesis has been investigated. The physic-chemical performance and structure of Pd/γ-Al2O3 catalysts were characterized by CO-TPD, TGA and nitrogen physisorption. The results show that the dispersion of Pd and the amount of adsorbration on the CO-bridge of Pd could be increased to by the moderate microwave heating on the catalysts, and the catalyst performance can be improved. But a large number of surface acidic sites of Pd/γ-Al2O3 are covered by highly fragmented Pd-grain, it causes DME selectivity reduced. And the excessive Pd can reduce the samples’ surface acid, decrease the dispersion of the metal Pd and block up the pore of γ-Al2O3. The CO conversion rate and DME space-time yield could reach 60.1% and 28.76 mmol·g-1·h-1 respectively at 2% Pd loading, at this time Pd/γ-Al2O3 has a high Pd activity surface and ideal acid sites.

Deactivation Kinetics for Direct Dimethyl Ether Synthesis on a CuO−ZnO−Al2O3/γ-Al2O3Catalyst

2010 ◽  
Vol 49 (2) ◽  
pp. 481-489 ◽  
Author(s):  
Irene Sierra ◽  
Javier Ereña ◽  
Andrés T. Aguayo ◽  
Martin Olazar ◽  
Javier Bilbao
Keyword(s):  
Dimethyl Ether ◽  
Deactivation Kinetics ◽  
Dimethyl Ether Synthesis ◽  
Ether Synthesis
Sign in / Sign up

Export Citation Format

Share Document