Electronic and spatial control over the formation of transient ion pairs during photoinduced electron transfer between proflavine–amine systems in a subpicosecond time regime

Chaitrali Sengupta; Piyali Mitra; Banabithi Koley Seth; Debabrata Mandal; Samita Basu

doi:10.1039/c6ra28286e

Electronic and spatial control over the formation of transient ion pairs during photoinduced electron transfer between proflavine–amine systems in a subpicosecond time regime

RSC Advances ◽

10.1039/c6ra28286e ◽

2017 ◽

Vol 7 (25) ◽

pp. 15149-15157 ◽

Cited By ~ 1

Author(s):

Chaitrali Sengupta ◽

Piyali Mitra ◽

Banabithi Koley Seth ◽

Debabrata Mandal ◽

Samita Basu

Keyword(s):

Physical Chemistry ◽

Electron Transfer ◽

Free Energy ◽

Photoinduced Electron Transfer ◽

Ion Pairs ◽

Spatial Control ◽

Rate Of Reaction ◽

Reaction Free Energy ◽

Time Regime

Probing photoinduced electron transfer (PET) in solution in terms of rate of reaction and reaction free energy is a great challenge in physical chemistry.

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Free-Energy-Gap Law for Ultrafast Charge Recombination of Ion Pairs Formed by Intramolecular Photoinduced Electron Transfer

The Journal of Physical Chemistry B ◽

10.1021/acs.jpcb.6b10550 ◽

2017 ◽

Vol 121 (3) ◽

pp. 589-598 ◽

Cited By ~ 11

Author(s):

Alexey E. Nazarov ◽

Roman Malykhin ◽

Anatoly I. Ivanov

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Photoinduced Electron Transfer ◽

Energy Gap ◽

Ion Pairs ◽

Charge Recombination ◽

Energy Gap Law

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Marcus Free Energy Dependence of the Sign of Exchange Interactions in Radical Ion Pairs Generated by Photoinduced Electron Transfer Reactions

Journal of the American Chemical Society ◽

10.1021/ja972533m ◽

1998 ◽

Vol 120 (6) ◽

pp. 1325-1326 ◽

Cited By ~ 29

Author(s):

Shinji Sekiguchi ◽

Yasuhiro Kobori ◽

Kimio Akiyama ◽

Shozo Tero-Kubota

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Energy Dependence ◽

Photoinduced Electron Transfer ◽

Ion Pairs ◽

Exchange Interactions ◽

Transfer Reactions ◽

Electron Transfer Reactions

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Effect of charge separation free energy gap on the rate constant of ultrafast charge recombination in ion pairs formed by intramolecular photoinduced electron transfer

Journal of Photochemistry and Photobiology A Chemistry ◽

10.1016/j.jphotochem.2018.03.017 ◽

2018 ◽

Vol 358 ◽

pp. 207-214 ◽

Cited By ~ 4

Author(s):

Alexey E. Nazarov ◽

Georgy G. Eloev ◽

Anatoly I. Ivanov

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Rate Constant ◽

Charge Separation ◽

Photoinduced Electron Transfer ◽

Energy Gap ◽

Ion Pairs ◽

Charge Recombination

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Photoinduced electron transfer within ion pairs. Direct measure of the intramolecular electron-transfer quenching constant

Chemical Physics Letters ◽

10.1016/0009-2614(85)80456-5 ◽

1985 ◽

Vol 119 (5) ◽

pp. 459-462 ◽

Cited By ~ 8

Author(s):

Roberto Ballardini ◽

M.Teresa Gandolfi ◽

Vincenzo Balzani

Keyword(s):

Electron Transfer ◽

Photoinduced Electron Transfer ◽

Ion Pairs ◽

Intramolecular Electron Transfer ◽

Direct Measure

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Optical and photoinduced electron transfer in tris(ethylenediamine)cobalt(III)-cyanometallate ion pairs

Journal of Photochemistry and Photobiology A Chemistry ◽

10.1016/s1010-6030(96)04562-5 ◽

1997 ◽

Vol 103 (3) ◽

pp. 239-247 ◽

Cited By ~ 11

Author(s):

Roland Billing ◽

A. Vogler

Keyword(s):

Electron Transfer ◽

Photoinduced Electron Transfer ◽

Ion Pairs

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ChemInform Abstract: Charge Transfer Ion Pairs. Structure and Photoinduced Electron Transfer of Carbonylmetalate Salts.

ChemInform ◽

10.1002/chin.198940104 ◽

1989 ◽

Vol 20 (40) ◽

Author(s):

T. M. BOCKMAN ◽

J. K. KOCHI

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Photoinduced Electron Transfer ◽

Ion Pairs

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Photoinduced Electron Transfer at Liquid|Liquid Interfaces: Dynamics of the Heterogeneous Photoreduction of Quinones by Self-Assembled Porphyrin Ion Pairs

Journal of the American Chemical Society ◽

10.1021/ja029589n ◽

2003 ◽

Vol 125 (16) ◽

pp. 4862-4869 ◽

Cited By ~ 33

Author(s):

Nicolas Eugster ◽

David J. Fermín ◽

Hubert H. Girault

Keyword(s):

Electron Transfer ◽

Photoinduced Electron Transfer ◽

Ion Pairs ◽

Liquid Interfaces ◽

Self Assembled

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ChemInform Abstract: Cyanoanthracene-Sensitized Photooxidations of N,N- Dibenzylhydroxylamine and Its Derivatives: Free-Energy Dependence of Back Electron-Transfer Rates within Geminate Radical Ion Pairs.

ChemInform ◽

10.1002/chin.199519027 ◽

2010 ◽

Vol 26 (19) ◽

pp. no-no

Author(s):

T. SAKURAI ◽

M. YOKONO ◽

K. KOMIYA ◽

Y. MASUDA ◽

H. INOUE

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Energy Dependence ◽

Ion Pairs ◽

Transfer Rates ◽

Back Electron Transfer

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Photoinduced Electron Transfer in Hydrogen Bonded Donor−Acceptor Systems. Study of the Dependence of Rate on Free Energy and Simultaneous Observation of the Marcus and Rehm−Weller Behaviors†

Journal of the American Chemical Society ◽

10.1021/ja993872d ◽

2000 ◽

Vol 122 (13) ◽

pp. 3191-3196 ◽

Cited By ~ 35

Author(s):

E. Prasad ◽

K. R. Gopidas

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Photoinduced Electron Transfer ◽

Simultaneous Observation ◽

Donor Acceptor ◽

Hydrogen Bonded

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Free energy dependence of the diffusion-limited quenching rate constants in photoinduced electron transfer processes

Photochemical & Photobiological Sciences ◽

10.1039/b708797g ◽

2008 ◽

Vol 7 (1) ◽

pp. 104-108 ◽

Cited By ~ 7

Author(s):

Vicente Avila ◽

Carlos M. Previtali ◽

Carlos A. Chesta

Keyword(s):

Electron Transfer ◽

Free Energy ◽

Energy Dependence ◽

Rate Constants ◽

Photoinduced Electron Transfer ◽

Quenching Rate ◽

Transfer Processes ◽

Diffusion Limited ◽

Electron Transfer Processes

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