scholarly journals Amorphous molybdenum sulfide on graphene–carbon nanotube hybrids as supercapacitor electrode materials

RSC Advances ◽  
2017 ◽  
Vol 7 (12) ◽  
pp. 6856-6864 ◽  
Author(s):  
Kien-Cuong Pham ◽  
David S. McPhail ◽  
Andrew T. S. Wee ◽  
Daniel H. C. Chua

Deposition of amorphous molybdenum sulfide on a high specific surface area carbon support strongly enhanced the specific capacitance of the material.

Author(s):  
Wenbo Geng ◽  
Qing Wang ◽  
Jianfeng Dai ◽  
Haoran Gao

The performance of supercapacitor electrode materials was greatly affected by the specific surface area. The urchin-like NiCo2O4 was transformed into porous NiCo2O4 (AA-NiCo2O[Formula: see text] using the acid–alkali treatment method. The specific surface area of AA-NiCo2O4 was 165.0660 m2/g, which was about three times larger than that of NiCo2O4. The specific capacitance of the AA-NiCo2O4 was enhanced significantly (1700 F/g at 1 A/g), and AA-NiCo2O4 possesses good rate capacitance (1277 F/g at 10 A/g). This is mainly attributed to the larger specific surface area, fast and convenient electron–ion transport and redox reaction. Therefore, AA-NiCo2O4 is a promising high-performance supercapacitor electrode material.


2016 ◽  
Vol 09 (01) ◽  
pp. 1640001 ◽  
Author(s):  
Kunfeng Chen ◽  
Gong Li ◽  
Dongfeng Xue

The biggest challenge for today’s supercapacitor systems readily possessing high power density is their low energy density. Their electrode materials with controllable structure, specific surface area, electronic conductivity, and oxidation state, have long been highlighted. Architecture engineering of functional electrode materials toward powerful supercapacitor systems is becoming a big fashion in the community. The construction of ion-accessible tunnel structures can microscopically increase the specific capacitance and materials utilization; stiff 3D structures with high specific surface area can macroscopically assure high specific capacitance. Many exciting findings in electrode materials mainly focus on the construction of ice-folded graphene paper, in situ functionalized graphene, in situ crystallizing colloidal ionic particles and polymorphic metal oxides. This feature paper highlights some recent architecture engineering strategies toward high-energy supercapacitor electrode systems, including electric double-layer capacitance (EDLC) and pseudocapacitance.


2018 ◽  
Vol 281 ◽  
pp. 854-858
Author(s):  
Xi Cheng Gao ◽  
Jian Qiang Bi ◽  
Wei Li Wang ◽  
Guo Xun Sun ◽  
Xu Xia Hao ◽  
...  

NiFe2O4 powders were synthesized by a facile hydrothermal method at 180°C followed by a thermal treatment at 300°C. The phase composition and morphology were analyzed by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results showed that the NiFe2O4 powders were well-crystallized, and they possessed a particle size in the range of 50-100 nm. The electrochemical property was characterized via cyclic voltammetry (CV) and constant current charge-discharge method. Encouragingly, the NiFe2O4 powders had an excellent electrochemical property, whose specific capacitance reached 266.84 F/g at the electric current density of 1 A/g due to the small particle size. Compared with other Fe-based metal compound oxides, NiFe2O4 has a better electrochemical performance, which can be widely used in the supercapacitor electrode materials.


RSC Advances ◽  
2015 ◽  
Vol 5 (39) ◽  
pp. 30943-30949 ◽  
Author(s):  
Shuai Yu ◽  
Duo Liu ◽  
Shuyan Zhao ◽  
Binfu Bao ◽  
Chunde Jin ◽  
...  

Wood derived carbon–polyaniline composites exhibit comparable specific capacitance (347 F g−1) and energy density (44.4 W h kg−1) to similar materials.


2018 ◽  
Vol 6 (30) ◽  
pp. 14644-14650 ◽  
Author(s):  
Shiyong Wang ◽  
Gang Wang ◽  
Tingting Wu ◽  
Yunqi Zhang ◽  
Fei Zhan ◽  
...  

BCN nanosheets show a pore structure with a high specific surface area and are investigated as CDI electrode materials for the first time.


Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 1982
Author(s):  
Qinghua Yuan ◽  
Zhuwen Ma ◽  
Junbiao Chen ◽  
Zhenrui Huang ◽  
Zeming Fang ◽  
...  

The recycling of macromolecular biowastes has been a problem for the agriculture industry. In this study, a novel N, S-codoped activated carbon material with an ultrahigh specific area was produced for the application of a supercapacitor electrode, using tobacco stalk biowastes as the carbon source, KOH as the activating agents and thiourea as the doping agent. Tobacco stalk is mainly composed of cellulose, but also contains many small molecules and inorganic salts. KOH activation resulted in many mesopores, giving the tobacco stem-activated carbon a large specific surface area and double-layer capacitance. The specific surface area of the samples reached up to 3733 m2·g−1, while the maximum specific capacitance of the samples obtained was up to 281.3 F·g−1 in the 3-electrode tests (1 A·g−1). The doping of N and S elements raised the specific capacitance significantly, which could be increased to a value as high as 422.5 F·g−1 at a current density of 1 A·g−1 in the 3-electrode tests, but N, S-codoping also led to instability. The results of this article prove that tobacco stalks could be efficiently reused in the field of supercapacitors.


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