Decoloration of azo and triarylmethane dyes in the aqueous phase by catalytic hydrotreatment with Pd supported on pillared clays

RSC Advances ◽  
2016 ◽  
Vol 6 (115) ◽  
pp. 113820-113825 ◽  
Author(s):  
A. H. Pizarro ◽  
C. B. Molina ◽  
J. J. Rodriguez

Catalytic hydrotreatment of synthetic dyes as azo compounds and triarylmethanes has been carried out under ambient-like conditions (25–50 °C, 1 atm) with H2using Pd supported on Al-pillared clays and Al2O3as catalysts.

2009 ◽  
Vol 172 (1) ◽  
pp. 214-223 ◽  
Author(s):  
C.B. Molina ◽  
L. Calvo ◽  
M.A. Gilarranz ◽  
J.A. Casas ◽  
J.J. Rodriguez
Keyword(s):  

F1000Research ◽  
2020 ◽  
Vol 9 ◽  
pp. 1053
Author(s):  
Juni Handajani ◽  
Urfa Tabtila ◽  
Nadia Rully Auliawati ◽  
Abdul Rohman

Background: Azo compounds, containing naphthol and diazonium salts, are synthetic dyes widely used in the batik industry. Azo compounds are considered toxic when they are exposed to human tissue. The purpose of this study was to analyze buccal cell DNA exposed to azo compounds in batik workers. Methods: A cross-sectional study involving 20 male subjects divided into two groups (n=10 group), namely azo-exposed and non-exposed (control group). Inclusion criteria were batik workers of the colouring division who have been exposed to azo for at least 5 years. Buccal cells were taken using cytobrush then DNA were isolated from buccal cell. DNA isolation was done by buccal DNA kit, while the purity and concentration of the DNA was determined using spectrophotometer and electrophoresis. Results: The azo-exposed group revealed higher purity DNA than those in the control group. The purity of the DNA in the azo-exposed group and control group was 0.61±0.93 and 0.21±0.09, respectively, while the concentration of DNA was of 59.02 and 19.35 ng/UL, respectively. The ratio at 260/280 nm was 1.84-1.94 (azo-exposed) and 1.85-1.92 (control). Principal component analysis using the first principle component (PC1) and second principle component (PC2) could successfully classify subjects in the control and azo-exposed groups. Conclusion: Characteristics of DNA could be used as an indication of exposure to azo compounds in workers of batik industries.


2009 ◽  
Vol 45 (4) ◽  
pp. 206-212 ◽  
Author(s):  
C.B. Molina ◽  
L. Calvo ◽  
M.A. Gilarranz ◽  
J.A. Casas ◽  
J.J. Rodriguez

2012 ◽  
Vol 65 (4) ◽  
pp. 653-660 ◽  
Author(s):  
C. B. Molina ◽  
A. H. Pizarro ◽  
J. A. Casas ◽  
J. J. Rodriguez

Bimetallic Pd–Rh catalysts supported on pillared clays have been prepared and tested for aqueous-phase hydrodechlorination (HDC) using 4-chlorophenol (4-CP) as target compound. These bimetallic catalysts combine the higher activity of Rh with the better stability of Pd found in previous works with monometallic catalysts. Different combinations of Pd and Rh amounting to 1 wt% total metal load were tested and the catalyst with 0.75 wt% Pd and 0.25 wt% Rh yielded the best results. Ecotoxicity and biodegradability (measured as BOD5/COD ratio) of the effluents were checked. A significant decrease of ecotoxicity was observed while biodegradability was dramatically improved from 0.02 for the initial 4-CP solution up to values higher than 0.6.


2014 ◽  
Vol 522-524 ◽  
pp. 584-589
Author(s):  
Li Han ◽  
Yue Wen ◽  
Ning Ding ◽  
Qi Zhou

Azo compounds constitute the largest and the most diverse group of synthetic dyes and are widely used. The release of coloured wastewaters represents a serious environmental problem and a public health concern. The aim of this study was to investigate the impact of sulfate and redox mediator on the reduction of an azo dye (Acid orange 7, AO7) by anaerobic sludge. The kinetics showed the AO7 reduction rate can be greatly improved by the addition of sulfate and RF, thus it is possible to speed up the start-up of AO7 reduction system under appropriate condition.


2014 ◽  
Vol 148-149 ◽  
pp. 330-338 ◽  
Author(s):  
C.B. Molina ◽  
A.H. Pizarro ◽  
J.A. Casas ◽  
J.J. Rodriguez
Keyword(s):  

2021 ◽  
Author(s):  
Julijana D. Tadić ◽  
◽  
Jelena M. Lađarević ◽  
Maja D. Marković ◽  
Aleksandra M. Ivanovska ◽  
...  

Schiff bases, or azomethine compounds, are commonly employed in the fields of organic synthesis, metal complexes, materials, and engineering. Especially, they have gained importance in medicinal researches, considering their antimicrobial, anticancer, anti- inflammatory, and antioxidant properties. On the other side, azo dyes are the most significant group of synthetic dyes, utilized in textile fiber dyeing. Conjugation of Schiff bases with azo compounds leads to the class of azo-azomethine dyes, which have numerous applications related to their coloration and biological properties. Viscose is a textile material widely used in the medicine. Moreover, viscose fiber can be engineered in many ways which are significant in the development of medical materials. The antioxidant effect is an important feature of medical textiles, such as wound dressings. In this work, the microwave-assisted synthesis and characterization of novel azo-azomethine dye are reported. The azo-azomethine dye is obtained by the condensation between arylazo pyridone dye and 4-aminophenol. The structure of synthesized dye was determined by ATR-FTIR, NMR, and UV-Vis spectroscopy. Azo- azomethine dye was used for dyeing viscose, and the washing fastness of dyed material was evaluated according to the standard method. The viscose fabrics, before and after washing, were analyzed in terms of their color coordinates in the CIELab color space. The antioxidant properties of azo-azomethine dye and dyed viscose fabrics were examined by the ABTS method.


F1000Research ◽  
2020 ◽  
Vol 9 ◽  
pp. 1053
Author(s):  
Juni Handajani ◽  
Urfa Tabtila ◽  
Nadia Rully Auliawati ◽  
Abdul Rohman

Background: Azo compounds, containing naphthol and diazonium salts, are synthetic dyes widely used in the batik industry. Azo compounds are considered toxic when they are exposed to human tissue. The purpose of this study was to analyze buccal cell DNA exposed to azo compounds in batik workers. Methods: A cross-sectional study involving 20 male subjects divided into two groups (n=10 group), namely azo-exposed and non-exposed (control group). Inclusion criteria were batik workers of the colouring division who have been exposed to azo for at least 5 years. Buccal cells were taken using cytobrush then DNA were isolated from buccal cell. DNA isolation was done by buccal DNA kit, while the purity and concentration of the DNA was determined using spectrophotometer and electrophoresis. Results: The azo-exposed group revealed higher purity DNA than those in the control group. The purity of the DNA in the azo-exposed group and control group was 0.61±0.93 and 0.21±0.09, respectively, while the concentration of DNA was of 59.02 and 19.35 ng/UL, respectively. The ratio at 260/280 nm was 1.84-1.94 (azo-exposed) and 1.85-1.92 (control). Principal component analysis using the first principle component (PC1) and second principle component (PC2) could successfully classify subjects in the control and azo-exposed groups. Conclusion: Characteristics of DNA could be used as an indication of exposure to azo compounds in workers of batik industries.


1981 ◽  
Vol 11 ◽  
Author(s):  
M.H. Bradbury ◽  
D. Lever ◽  
D. Kinsey

One of the options being considered for the disposal of radioactive waste is deep burial in crystalline rocks such as granite. It is generally recognised that in such rocks groundwater flows mainly through the fracture networks so that these will be the “highways” for the return of radionuclides to the biosphere. The main factors retarding the radionuclide transport have been considered to be the slow water movement in the fissures over the long distances involved together with sorption both in man-made barriers surrounding the waste, and onto rock surfaces and degradation products in the fissures.


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