Glycerol as green hydrogen source for catalytic reduction over anisotropic silver nanoparticles

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 103471-103477 ◽  
Author(s):  
A. D. Verma ◽  
R. K. Mandal ◽  
I. Sinha

Effect of shape and size of AgNPs on the catalytic kinetics of p-nitrophenol reduction using glycerol as a hydrogen source.

1983 ◽  
Vol 48 (11) ◽  
pp. 3202-3208 ◽  
Author(s):  
Zdeněk Musil ◽  
Vladimír Pour

The kinetics of the reduction of nitrogen oxide by carbon monoxide on CuO/Al2O3 catalyst (8.36 mass % CuO) were determined at temperatures between 413 and 473 K. The reaction was found to be first order in NO and zero order in CO. The observed kinetics are consistent with a rate equation derived from a mechanism proposed on the basis of IR spectroscopic measurements.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Luqman Ali Shah ◽  
Rida Javed ◽  
Mohammad Siddiq ◽  
Iram BiBi ◽  
Ishrat Jamil ◽  
...  

AbstractThe in-situ stabilization of Ag nanoparticles is carried out by the use of reducing agent and synthesized three different types of hydrogen (anionic, cationic, and neutral) template. The morphology, constitution and thermal stability of the synthesized pure and Ag-entrapped hybrid hydrogels were efficiently confirmed using scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and thermo gravimetric analysis (TGA). The prepared hybrid hydrogels were used in the decolorization of methylene blue (MB) and azo dyes congo red (CR), methyl Orange (MO), and reduction of 4-nitrophenol (4-NP) and nitrobenzene (NB) by an electron donor NaBH4. The kinetics of the reduction reaction was also assessed to determine the activation parameters. The hybrid hydrogen catalysts were recovered by filtration and used continuously up to six times with 98% conversion of pollutants without substantial loss in catalytic activity. It was observed that these types of hydrogel systems can be used for the conversion of pollutants from waste water into useful products.


2021 ◽  
Vol 329 ◽  
pp. 115537
Author(s):  
Nazia Iqbal ◽  
S.M. Shakeel Iqubal ◽  
Aejaz Abdullatif Khan ◽  
Tasneem Mohammed ◽  
Ali Mohamed Alshabi ◽  
...  

2013 ◽  
Vol 3 (8) ◽  
pp. 1910 ◽  
Author(s):  
Miao Liang ◽  
Libing Wang ◽  
Rongxin Su ◽  
Wei Qi ◽  
Mengfan Wang ◽  
...  

2012 ◽  
Vol 1371 ◽  
Author(s):  
M.I. Hernández-Castillo ◽  
O. Zaca-Moran ◽  
P. Zaca-Moran ◽  
M. Rojas-López ◽  
V.L. Gayou ◽  
...  

ABSTRACTBy using the citrate reduction procedure we have synthesized Ag nanoparticles, applying several conditions of preparation, being after characterized by UV-visible spectrophotometry. Following a logical sequence, the starting experiment was realized varying the reaction time, after that it was varied the concentration of the reductor agent, and finally it was varied the volume of the reductor agent. According to this methodology, TEM measurements show that firstly we have nanostructures with different shape and size, whereas in the last part of the experiment we have Ag nanoparticles with homogeneous shape and size.


2012 ◽  
Vol 429 ◽  
pp. 325-331 ◽  
Author(s):  
Amro M. El Badawy ◽  
Kirk G. Scheckel ◽  
Makram Suidan ◽  
Thabet Tolaymat

1995 ◽  
Vol 34 (5) ◽  
pp. 1572-1580 ◽  
Author(s):  
Yao-Sheng Lee ◽  
Mou-Yung Yeh ◽  
Yen-Ping Shih

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