Immobilizing AgPd alloy on Vulcan XC-72 carbon: a novel catalyst for highly efficient hydrogen generation from formaldehyde aqueous solution

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105638-105643 ◽  
Author(s):  
Shutao Gao ◽  
Tao Feng ◽  
Qiuhua Wu ◽  
Cheng Feng ◽  
Ningzhao Shang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Room Temperature ◽  
Hydrogen Generation ◽  
Bimetallic Catalyst ◽  
Highly Efficient ◽  
Novel Catalyst ◽  
First Time

A novel bimetallic catalyst, AgPd nanoalloy supported on Vulcan XC-72 carbon (AgPd@C-72), has been successfully fabricated and used for catalyzing H2 generation from formaldehyde aqueous solution at room temperature for the first time.

scholarly journals Synthesis of cobalt nanowires in aqueous solution under an external magnetic field

2016 ◽  
Vol 7 ◽  
pp. 990-994 ◽  
Author(s):  
Xiaoyu Li ◽  
Lijuan Sun ◽  
Hu Wang ◽  
Kenan Xie ◽  
Qin Long ◽  
...  
Keyword(s):  
Magnetic Field ◽  
Aqueous Solution ◽  
External Magnetic Field ◽  
Room Temperature ◽  
Magnetic Measurements ◽  
Chemical Reduction ◽  
Average Diameter ◽  
Firm Structure ◽  
Cobalt Nanowires ◽  
First Time

In contrast to the majority of related experiments, which are carried out in organic solvents at high temperatures and pressures, cobalt nanowires were synthesized by chemical reduction in aqueous solution with the assistance of polyvinylpyrrolidone (PVP) as surfactant under moderate conditions for the first time, while an external magnetic field of 40 mT was applied. Uniform linear cobalt nanowires with relatively smooth surfaces and firm structure were obtained and possessed an average diameter of about 100 nm with a coating layer of PVP. By comparison, the external magnetic field and PVP were proven to have a crucial influence on the morphology and the size of the synthesized cobalt nanowires. The prepared cobalt nanowires are crystalline and mainly consist of cobalt as well as a small amount of platinum. Magnetic measurements showed that the resultant cobalt nanowires were ferromagnetic at room temperature. The saturation magnetization (M s) and the coercivity (H c) were 112.00 emu/g and 352.87 Oe, respectively.

Role of surfactant and micelle promoted mild, green, highly efficient and sustainable approach for construction of novel fused pyrimidines at room temperature in water

RSC Advances ◽  
2016 ◽  
Vol 6 (72) ◽  
pp. 67651-67661 ◽  
Author(s):  
Pramod K. Sahu
Keyword(s):  
Room Temperature ◽  
Green Protocol ◽  
Highly Efficient ◽  
First Time

A facile, efficient and green protocol for surfactant catalyzed synthesis of fused pyrimidines in water at room temperature was developed for the first time.

CeOx-modified RhNi nanoparticles grown on rGO as highly efficient catalysts for complete hydrogen generation from hydrazine borane and hydrazine

2015 ◽  
Vol 3 (46) ◽  
pp. 23520-23529 ◽  
Author(s):  
Zhujun Zhang ◽  
Zhang-Hui Lu ◽  
Hongliang Tan ◽  
Xiangshu Chen ◽  
Qilu Yao
Keyword(s):  
Aqueous Solution ◽  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Hydrogen Generation ◽  
Graphene Oxide Nanosheets ◽  
Highly Efficient ◽  
Reduced Graphene ◽  
Recyclable Catalysts

Amorphous CeOx-doped Rh-Ni NPs grown on reduced graphene oxide nanosheets have been used as highly efficient and recyclable catalysts for complete hydrogen generation from aqueous solution of N2H4BH3 or N2H4.

Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand

2018 ◽  
Vol 20 (8) ◽  
pp. 1835-1840 ◽  
Author(s):  
Sheng-Mei Lu ◽  
Zhijun Wang ◽  
Jijie Wang ◽  
Jun Li ◽  
Can Li
Keyword(s):  
High Temperature ◽  
Formic Acid ◽  
Room Temperature ◽  
High Efficiency ◽  
Hydrogen Generation ◽  
Acid Decomposition ◽  
Highly Efficient ◽  
Iridium Catalyst ◽  
Formic Acid Decomposition ◽  
Aqueous Formic Acid

A new iridium catalyst bearing a dioxime derived ligand has been developed for aqueous formic acid (FA) dehydrogenation in the absence of any additives. These catalysts can work at high temperature or room temperature with high efficiency and stability.

Water-soluble Poly(4-styrenesulfonic acid-co-maleic acid)-stabilized Nickel(0) and Cobalt(0) Nanoclusters as Highly Active Catalysts in Hydrogen Generation from the Hydrolysis of Ammonia-Borane

2009 ◽  
Vol 1217 ◽  
Author(s):  
Önder Metin ◽  
Saim Özkar
Keyword(s):  
Maleic Acid ◽  
Room Temperature ◽  
Hydrogen Generation ◽  
Ammonia Borane ◽  
Water Soluble ◽  
High Catalytic Activity ◽  
Highly Active ◽  
First Time ◽  
Hydrolysis Of ◽  
Soluble Poly

AbstractWater soluble poly(4-styrenesulfonic acid-co-maleic acid), PSSA-co-MA, stabilized nickel(0) and cobalt(0) nanoclusters were prepared for the first time from the reduction of nickel(II) chloride and cobalt(II) chloride by using minimum amount of sodium borohydride shortly before their usage as catalysts in the hydrolysis of ammonia-borane (AB) in the same medium at room temperature. PSSA-co-MA stabilized nickel(0) and cobalt(0) nanoclusters showed high catalytic activity in hydrogen generation from the hydrolysis of AB even at low temperature.

Polymeric room-temperature molten salt as a multifunctional additive toward highly efficient and stable inverted planar perovskite solar cells

2020 ◽  
Vol 13 (12) ◽  
pp. 5068-5079
Author(s):  
Shuangjie Wang ◽  
Bowen Yang ◽  
Jian Han ◽  
Ziwei He ◽  
Tongtong Li ◽  
...  
Keyword(s):  
Solar Cells ◽  
Molten Salt ◽  
Room Temperature ◽  
High Efficiency ◽  
Perovskite Solar Cells ◽  
Multifunctional Additive ◽  
Highly Efficient ◽  
First Time ◽  
Excellent Stability

We for the first time report the application of a polymeric room-temperature molten salt in high efficiency and excellent stability inverted perovskite solar cells.

An aqueous synthesis of porous PtPd nanoparticles with reversed bimetallic structures for highly efficient hydrogen generation from ammonia borane hydrolysis

Nanoscale ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 638-647 ◽  
Author(s):  
Kaisheng Yao ◽  
Chenchen Zhao ◽  
Nan Wang ◽  
Tianji Li ◽  
Weiwei Lu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Generation ◽  
Ammonia Borane ◽  
One Pot ◽  
Aqueous Synthesis ◽  
Catalytic Activities ◽  
Highly Efficient ◽  
Bimetallic Structures

Porous PtPd NPs with reversed bimetallic structures from Pd-on-Pt to Pt-on-Pd can be one-pot prepared in aqueous solution under the modulation of [C16mim]Cl and glycine and show superior catalytic activities for AB hydrolysis to produce hydrogen.

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