scholarly journals Direct amide synthesis over core–shell TiO2@NiFe2O4 catalysts in a continuous flow radiofrequency-heated reactor

RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 100997-101007 ◽  
Author(s):  
Yawen Liu ◽  
Pengzhao Gao ◽  
Nikolay Cherkasov ◽  
Evgeny V. Rebrov

A core–shell TiO2@NiFe2O4 catalyst showed high activity and stability in direct amide synthesis with easy regeneration from coke by a treatment with a 30 wt% hydrogen peroxide solution.

2013 ◽  
Vol 19 (3) ◽  
pp. 523-527 ◽  
Author(s):  
Miaomiao LIU ◽  
Juan FENG ◽  
Hongbo LIU ◽  
Xiaolan YANG ◽  
Liping FENG ◽  
...  

2009 ◽  
Vol 59 (12) ◽  
pp. 1400-1404
Author(s):  
Marius Tudorascu ◽  
Spiridon Oprea ◽  
Afrodita Doina Marculescu ◽  
Stefania Tudorascu

The mechanism of the enzymatic iodination process of diethylmaleate and diethylfumarate (which present no miscibility with water) in the presence of lactoperoxidase, both in diluted hydrogen peroxide solution and in a generating system of hydrogen peroxide using ammonium and calcium iodides as halide sources in disperse system (after an ultrasonic pretreatment) was studied. The obtained sole product (diethyl-2, 3-diiodosuccinate) after the enzymatic iodination process was directly hydrolyzed to a tartaric acid present in an optically inactive form. The mechanism of obtaining the intermediate and final products and respectively, the existence of both D, L-tartaric acid and meso-tartaric acids (as lithium bitartrates) were also investigated.


Author(s):  
Yu Jiang ◽  
Shanshan Gao ◽  
Gongchen Xu ◽  
Xiaoming Song

Porous and amorphous CoSx(OH)y core–shell nanoneedles covered by numerous ultra-thin small nanosheets are synthesized successfully on Ti-mesh, and act as a high activity and stability bifunctional catalyst for urea electrolysis.


2015 ◽  
Vol 17 (3) ◽  
pp. 1907-1917 ◽  
Author(s):  
Paolo Dambruoso ◽  
Marco Ballestri ◽  
Claudia Ferroni ◽  
Andrea Guerrini ◽  
Giovanna Sotgiu ◽  
...  

Photons and electrons cooperate for effective, clean sulfoxidations in pure water.


2013 ◽  
Vol 706-708 ◽  
pp. 219-223
Author(s):  
Hsiu Ling Hsu ◽  
Rosilda Selvin ◽  
L. Selva Roselin

A variety of solid acid catalysts especially 12-Tungstophosphoricacid (DTP) supported on silica has been reported for the acylation of anisole, veratrole and toluene. However, the activity of this catalyst is susceptible to coke formation or poor activity. This paper reports the novelties of steam treated SiO2-DTP core-shell nanoparticles, which exhibits tremendous stability, high activity and enhanced selectivity in the liquid-phase acylation of anisole, veratrole and toluene as compared to conventional DTP supported on silica.


PEDIATRICS ◽  
1990 ◽  
Vol 85 (4) ◽  
pp. 593-594
Author(s):  
WAYNE R. RACKOFF ◽  
DAVID F. MERTON

Gas embolism to the portal venous system is a well-recognized radiographic sign in infants with necrotizing enterocolitis. It also has been seen after colonic irrigation with hydrogen peroxide solution.1,2 We present what we believe is the first reported patient with radiographic evidence of portal venous gas embolism after ingestion of hydrogen peroxide solution. This finding is important because gas embolism to the portal venous system after colonic irrigation with hydrogen peroxide has been associated with gangrenous and perforated bowel.1,2 CASE REPORT A 2-year-old boy ingested an unknown amount of 3% hydrogen peroxide solution. The child was found with foam around his mouth.


2021 ◽  
Author(s):  
Kohei Kusada ◽  
Hiroshi Kitagawa

Alloy nanoparticles (NPs), including core-shell, segregated and solid-solution types, show a variety of attractive properties such as catalytic and optical properties and are used in a wide range of applications....


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