Preparation of polyacrylamide microspheres with core–shell structure via surface-initiated atom transfer radical polymerization

RSC Advances ◽  
2016 ◽  
Vol 6 (94) ◽  
pp. 91463-91467 ◽  
Author(s):  
Peng Zhang ◽  
Shixun Bai ◽  
Shilan Chen ◽  
Dandan Li ◽  
Zhenfu Jia ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Shell Structure ◽  
Core Shell ◽  
Atom Transfer ◽  
The Core ◽  
Core Shell Structure

Well defined core–shell microspheres were prepared by surface-initiated atom transfer radical polymerization with pre-crosslinked polyacrylamide as the core and non-crosslinked polyacrylamide as the shell.

scholarly journals Silica/polymer core–shell particles prepared via soap-free emulsion polymerization

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 254-261
Author(s):  
Mina Ishihara ◽  
Tomofumi Kaeda ◽  
Takashi Sasaki
Keyword(s):  
Emulsion Polymerization ◽  
Radical Polymerization ◽  
Shell Structure ◽  
Cross Linking ◽  
Core Shell ◽  
Shell Formation ◽  
The Core ◽  
Core Shell Structure ◽  
Soap Free Emulsion Polymerization ◽  
Shell Particles

AbstractIn this study, core–shell particles were prepared as a hybrid material, in which a thin polymer shell was formed on the surface of the SiO2 sphere particles. The core–shell structure was successfully achieved without adding a surfactant via simple free-radical polymerization (soap-free emulsion polymerization) for various monomers of styrene, methyl methacrylate (MMA), and their derivatives. MMA formed thin homogeneous shells of polymer (PMMA) less than 100 nm in thickness with complete surface coverage and a very smooth shell surface. The obtained shell morphology strongly depended on the monomers, which suggests different shell formation mechanisms with respect to the monomers. It was found that the cross-linking monomer 1,4-divinylbenzene tends to promote shell formation, and the cross-linking reaction may stabilize the core–shell structure throughout radical polymerization. It should also be noted that the present method produced a considerable amount of pure polymer besides the core–shell particles. The glass transition temperatures of the obtained polymer shells were higher than those of the corresponding bulk materials. This result suggests strong interactions at the core–shell interface.

Polymer@MOF@MOF: “grafting from” atom transfer radical polymerization for the synthesis of hybrid porous solids

2015 ◽  
Vol 51 (60) ◽  
pp. 11994-11996 ◽  
Author(s):  
Kyle A. McDonald ◽  
Jeremy I. Feldblyum ◽  
Kyoungmoo Koh ◽  
Antek G. Wong-Foy ◽  
Adam J. Matzger
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Outer Shell ◽  
Polymer Chains ◽  
Porous Solids ◽  
Core Shell ◽  
Atom Transfer ◽  
Hybrid Polymer ◽  
The Core ◽  
Grafting From

PMMA@IRMOF-3@MOF-5, a hybrid polymer–MOF composite, was produced through a combination of core–shell and post-synthetic modification techniques. The core–shell architecture allows polymer chains to be tethered to the outer shell selectively.

scholarly journals A SERS Study of Charge Transfer Process in Au Nanorod–MBA@Cu2O Assemblies: Effect of Length to Diameter Ratio of Au Nanorods

Nanomaterials ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 867
Author(s):  
Lin Guo ◽  
Zhu Mao ◽  
Sila Jin ◽  
Lin Zhu ◽  
Junqi Zhao ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Shell Structure ◽  
Shell Structures ◽  
Core Shell ◽  
Absorption Bands ◽  
Au Nanorods ◽  
The Core ◽  
Band Position ◽  
Surface Enhanced Raman ◽  
Core Shell Structure

Surface-enhanced Raman scattering (SERS) is a powerful tool in charge transfer (CT) process research. By analyzing the relative intensity of the characteristic bands in the bridging molecules, one can obtain detailed information about the CT between two materials. Herein, we synthesized a series of Au nanorods (NRs) with different length-to-diameter ratios (L/Ds) and used these Au NRs to prepare a series of core–shell structures with the same Cu2O thicknesses to form Au NR–4-mercaptobenzoic acid (MBA)@Cu2O core–shell structures. Surface plasmon resonance (SPR) absorption bands were adjusted by tuning the L/Ds of Au NR cores in these assemblies. SERS spectra of the core-shell structure were obtained under 633 and 785 nm laser excitations, and on the basis of the differences in the relative band strengths of these SERS spectra detected with the as-synthesized assemblies, we calculated the CT degree of the core–shell structure. We explored whether the Cu2O conduction band and valence band position and the SPR absorption band position together affect the CT process in the core–shell structure. In this work, we found that the specific surface area of the Au NRs could influence the CT process in Au NR–MBA@Cu2O core–shell structures, which has rarely been discussed before.

Construction of MOFs-Shell Porous Materials and Performance Study in Selective Adsorption and Separation of Benzene Pollutants

2021 ◽  
Author(s):  
Yu Qiao ◽  
Na Lv ◽  
Dong Li ◽  
Hongji Li ◽  
Xiangxin Xue ◽  
...  
Keyword(s):  
Porous Materials ◽  
Shell Structure ◽  
Selective Adsorption ◽  
Core Shell ◽  
Architecture Design ◽  
Performance Study ◽  
The Core ◽  
Core Shell Structure ◽  
And Performance ◽  
Sacrificial Agent

Metastable Cu2O is an attractive material for the architecture design of integrated nanomaterials. In this context, Cu2O was used as the sacrificial agent to form the core-shell structure of Cu2O@HKUST-1...

Core–shell stability of nanoparticles plays an important role for overcoming the intestinal mucus and epithelium barrier

2016 ◽  
Vol 4 (35) ◽  
pp. 5831-5841 ◽  
Author(s):  
Min Liu ◽  
Lei Wu ◽  
Xi Zhu ◽  
Wei Shan ◽  
Lian Li ◽  
...  
Keyword(s):  
Shell Structure ◽  
Core Shell ◽  
The Core ◽  
Shell Stability ◽  
Intestinal Mucus ◽  
Core Shell Structure ◽  
The Stability

The stability of the core–shell structure plays an important role in the nanoparticles ability to overcome both the mucus and epithelium absorption barrier.

Characterization of Fe3O4@CS@NMDP magnetic nanoparticles with core–shell structure prepared by chemical cross-linking method

2017 ◽  
Vol 10 (05) ◽  
pp. 1750056 ◽  
Author(s):  
Huiping Shao ◽  
Jiangcong Qi ◽  
Tao Lin ◽  
Yuling Zhou ◽  
Fucheng Yu
Keyword(s):  
Magnetic Nanoparticles ◽  
Shell Structure ◽  
High Performance ◽  
Cross Linking ◽  
Composite Particles ◽  
Core Shell ◽  
The Core ◽  
Targeting Delivery ◽  
Core Shell Structure ◽  
Chemical Cross Linking

The core–shell structure composite magnetic nanoparticles (NPs), Fe3O4@chitosan@nimodipine (Fe3O4@CS@NMDP), were successfully synthesized by a chemical cross-linking method in this paper. NMDP is widely used for cardiovascular and cerebrovascular disease prevention and treatment, while CS is of biocompatibility. The composite particles were characterized by an X-ray diffractometer (XRD), a Fourier transform infrared spectroscopy (FT-IR), a transmission electron microscopy (TEM), a vibrating sample magnetometers (VSM) and a high performance liquid chromatography (HPLC). The results show that the size of the core–shell structure composite particles is ranging from 12[Formula: see text]nm to 20[Formula: see text]nm and the coating thickness of NMDP is about 2[Formula: see text]nm. The saturation magnetization of core–shell composite NPs is 46.7[Formula: see text]emu/g, which indicates a good potential application for treating cancer by magnetic target delivery. The release percentage of the NMDP can reach 57.6% in a short time of 20[Formula: see text]min in the PBS, and to 100% in a time of 60[Formula: see text]min, which indicates the availability of Fe3O4@CS@NMDP composite NPs for targeting delivery treatment.

The use of galvanic displacement in synthesizing Pt(Cu) catalysts with the core-shell structure

2010 ◽  
Vol 46 (10) ◽  
pp. 1189-1197 ◽  
Author(s):  
B. I. Podlovchenko ◽  
T. D. Gladysheva ◽  
A. Yu. Filatov ◽  
L. V. Yashina
Keyword(s):  
Shell Structure ◽  
Core Shell ◽  
Galvanic Displacement ◽  
The Core ◽  
Cu Catalysts ◽  
Core Shell Structure

Seed-mediated synthesis of bimetallic ruthenium–platinum nanoparticles efficient in cinnamaldehyde selective hydrogenation

2014 ◽  
Vol 43 (24) ◽  
pp. 9283-9295 ◽  
Author(s):  
Xueqiang Qi ◽  
M. Rosa Axet ◽  
Karine Philippot ◽  
Pierre Lecante ◽  
Philippe Serp
Keyword(s):  
Selective Hydrogenation ◽  
Platinum Nanoparticles ◽  
Shell Structure ◽  
Core Shell ◽  
The Core ◽  
Core Shell Structure ◽  
Seed Mediated

The two-step synthesis of small ruthenium–platinum nanoparticles leads to the formation of a core–shell structure. The catalytic results provide supplementary evidence of the core–shell structure.

A cosolvency effect on tunable thermosensitive core–shell nanoparticle gels

Soft Matter ◽  
2015 ◽  
Vol 11 (19) ◽  
pp. 3936-3945 ◽  
Author(s):  
Sang Min Lee ◽  
Young Chan Bae
Keyword(s):  
Transition Temperature ◽  
Shell Structure ◽  
Core Shell ◽  
The Core ◽  
Volume Transition ◽  
Core Shell Structure ◽  
Propanol Solution

Schematic depiction of a core–shell structure composed of the PMMA core and the PHEMA shell, and the influence of three co-solvents on the volume transition temperature of the core–shell gels in 1-propanol solution.

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