Carbon–carbon vs. carbon–oxygen bond activation in 2- and 3-furonitriles with nickel

RSC Advances ◽  
2016 ◽  
Vol 6 (103) ◽  
pp. 101259-101266 ◽  
Author(s):  
Ilnett García-Ventura ◽  
Marcos Flores-Alamo ◽  
Juventino J. García
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Oxygen Bond

The reaction between [(dippe)NiH]2 (1) (dippe = 1,2-bis(diisopropylphosphino)-ethane) and 2- and 3-furonitrile (2-FN and 3-FN) was carried out at room temperature.

Room-Temperature Selective Aliphatic Carbon–Carbon Bond Activation and Functionalization of Ethers by Rhodium(II) Porphyrin

2011 ◽  
Vol 30 (14) ◽  
pp. 3691-3693 ◽  
Author(s):  
Siu Yin Lee ◽  
Tsz Ho Lai ◽  
Kwong Shing Choi ◽  
Kin Shing Chan
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Aliphatic Carbon

scholarly journals Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

2016 ◽  
Vol 52 (88) ◽  
pp. 12960-12963 ◽  
Author(s):  
Andrea Monas ◽  
Krunoslav Užarević ◽  
Ivan Halasz ◽  
Marina Juribašić Kulcsár ◽  
Manda Ćurić
Keyword(s):  
Methyl Orange ◽  
Solid State ◽  
Room Temperature ◽  
Bond Activation ◽  
Aqueous Media ◽  
Accelerated Aging ◽  
Water Soluble ◽  
Clean Synthesis

Room-temperature accelerated aging in the solid state has been applied for quantitative azobenzene C–H bond activation by Pd(OAc)2. Water-soluble dicyclopalladated methyl orange is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in aqueous media.

scholarly journals Si–C(sp3) bond activation through oxidative addition at a Rh(i) centre

2020 ◽  
Vol 49 (17) ◽  
pp. 5416-5419
Author(s):  
S. Azpeitia ◽  
A. J. Martínez-Martínez ◽  
M. A. Garralda ◽  
A. S. Weller ◽  
M. A. Huertos
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Oxidative Addition

Rhodium promoted a fast, quantitative and room temperature Si–CH3 bond activation.

Reactions of Olefins with Ruthenium Hydride Nanoparticles: NMR Characterization, Hydride Titration, and Room-Temperature CC Bond Activation

2008 ◽  
Vol 47 (11) ◽  
pp. 2074-2078 ◽  
Author(s):  
Jordi García-Antón ◽  
M. Rosa Axet ◽  
Susanna Jansat ◽  
Karine Philippot ◽  
Bruno Chaudret ◽  
...  
Keyword(s):  
Room Temperature ◽  
Bond Activation ◽  
Ruthenium Hydride ◽  
Nmr Characterization

Investigations Directed at Catalytic Carbon−Carbon and Carbon−Oxygen Bond Formation via C−H Bond Activation

2007 ◽  
Vol 26 (20) ◽  
pp. 4881-4889 ◽  
Author(s):  
Ian J. Blackmore ◽  
Christopher J. Semiao ◽  
Miriam S. A. Buschhaus ◽  
Brian O. Patrick ◽  
Peter Legzdins
Keyword(s):  
Bond Activation ◽  
Bond Formation ◽  
Oxygen Bond
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