Near-infrared luminescence and energy transfer processes in LaOF:Nd3+, Yb3+

RSC Advances ◽  
2016 ◽  
Vol 6 (94) ◽  
pp. 91127-91132 ◽  
Author(s):  
Shiman Shi ◽  
Qiufeng Shi ◽  
Cai'e Cui ◽  
Lei Wang ◽  
Yue Tian ◽  
...  

The cross-relaxation energy transfer from Nd3+ (4D3/2 → 4G5/2) to Yb3+ (2F7/2 → 2F5/2) was confirmed.

2019 ◽  
Vol 33 (28) ◽  
pp. 1950348
Author(s):  
S. Q. Asadullayeva ◽  
Q. Y. Eyyubov

In this paper, we study widely investigated photoluminescent properties of [Formula: see text] compounds in the near-infrared ranges. The increase of the infrared luminescence intensity with increasing [Formula: see text] concentration can be attributed to the cross-relaxation process between the activator ions.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2901
Author(s):  
Wojciech A. Pisarski ◽  
Joanna Pisarska ◽  
Radosław Lisiecki ◽  
Witold Ryba-Romanowski

This paper deals with broadband near-infrared luminescence properties of lead germanate glass triply doped with Yb3+/Er3+/Tm3+. Samples were excited at 800 nm and 975 nm. Their emission intensities and lifetimes depend significantly on Er3+ and Tm3+ concentrations. For samples excited at 800 nm, broadband emissions corresponding to the overlapped 3H4 → 3F4 (Tm3+) and 4I13/2 → 4I15/2 (Er3+) transitions centered at 1.45 µm and 1.5 µm was identified. Measurements of decay curves confirm reduction of 3H4 (Tm3+), 2F5/2 (Yb3+) and 4I13/2 (Er3+) luminescence lifetimes and the presence of energy-transfer processes. The maximal spectral bandwidth equal to 269 nm for the 3F4 → 3H6 transition of Tm3+ suggests that our glass co-doped with Yb3+/Er3+/Tm3+ is a good candidate for broadband near-infrared emission. The energy transfer from 4I13/2 (Er3+) to 3F4 (Tm3+) and cross-relaxation processes are responsible for the enhancement of broadband luminescence near 1.8 µm attributed to the 3F4 → 3H6 transition of thulium ions in lead germanate glass under excitation of Yb3+ ions at 975 nm.


2022 ◽  
Vol 130 (1) ◽  
pp. 99
Author(s):  
Xiaowu Hu ◽  
Fabio Piccinelli ◽  
Marco Bettinelli

In this work the optical spectroscopy and the energy transfer processes involving the Tb3+and Tm3+ ions, have been studied in eulytite double phosphate hosts of the type Sr3Y(PO4)3 doped with various amounts of the two Ln ions. It has been found that several energy transfer and cross-relaxation processes are active in this class of materials, upon excitation in the 5D4 level of Tb, and in the 1G4 one of Tm. In particular, a Tb→Tm transfer of excitation has been found to quench strongly the 5D4 level of Tb. This process occurs with a transfer efficiency increasing from 0.08 to 0.62, for a donor concentration of 2 mol%, and an acceptor concentration increasing from 2 to 15 mol%. The emission spectra are strongly affected by the presence of Tb⟷Tm energy transfer, and Tm→Tm cross relaxation processes.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Wojciech A. Pisarski ◽  
Joanna Pisarska ◽  
Marta Kuwik ◽  
Marcin Kochanowicz ◽  
Jacek Żmojda ◽  
...  

AbstractFluoroindate glasses co-doped with Pr3+/Er3+ ions were synthesized and their near-infrared luminescence properties have been examined under selective excitation wavelengths. For the Pr3+/Er3+ co-doped glass samples several radiative and nonradiative relaxation channels and their mechanisms are proposed under direct excitation of Pr3+ and/or Er3+. The energy transfer processes between Pr3+ and Er3+ ions in fluoroindate glasses were identified. In particular, broadband near-infrared luminescence (FWHM = 278 nm) associated to the 1G4 → 3H5 (Pr3+), 1D2 → 1G4 (Pr3+) and 4I13/2 → 4I15/2 (Er3+) transitions of rare earth ions in fluoroindate glass is successfully observed under direct excitation at 483 nm. Near-infrared luminescence spectra and their decays for glass samples co-doped with Pr3+/Er3+ are compared to the experimental results obtained for fluoroindate glasses singly doped with rare earth ions.


2005 ◽  
Author(s):  
Jianfeng Wu ◽  
Shibin Jiang ◽  
Tiequn Qiu ◽  
Michael Morrell ◽  
Axel Schulzgen ◽  
...  

2013 ◽  
Vol 49 (2) ◽  
pp. 527-531 ◽  
Author(s):  
Jiayue Sun ◽  
Dianpeng Cui ◽  
Guangchao Sun ◽  
Bing Xue ◽  
Chun Cao

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