Pd nanoparticles deposited on Isoniazid grafted multi walled carbon nanotubes: synthesis, characterization and application for Suzuki reaction in aqueous media

RSC Advances ◽  
2016 ◽  
Vol 6 (92) ◽  
pp. 88916-88924 ◽  
Author(s):  
Mahsa Hajighorbani ◽  
Malak Hekmati
Keyword(s):  
Carbon Nanotubes ◽  
High Activity ◽  
Aqueous Media ◽  
Suzuki Reaction ◽  
Coupling Reaction ◽  
Pd Nanoparticles ◽  
Aryl Halides ◽  
Suzuki Coupling Reaction ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

The prepared Isoniazide-MWCNTs were used to deposition of Pd NPs as novel nanocatalyst. The catalyst showed high activity in Suzuki coupling reaction of aryl halides (X = I, Br, Cl).

Amoxicillin Removal from Aqueous Media Using Multi-Walled Carbon Nanotubes

2014 ◽  
Vol 23 (2) ◽  
pp. 165-169 ◽  
Author(s):  
Ali Mohammadi ◽  
Maryam Kazemipour ◽  
Hadi Ranjbar ◽  
Roderick B. Walker ◽  
Mehdi Ansari
Keyword(s):  
Carbon Nanotubes ◽  
Aqueous Media ◽  
Multi Walled Carbon Nanotubes ◽  
Amoxicillin Removal ◽  
Walled Carbon Nanotubes

Langmuir-Blodgett Film of Multi-Walled Carbon Nanotubes for Hydrogen Sensor on Paper

2015 ◽  
Vol 754-755 ◽  
pp. 1146-1150
Author(s):  
Muhammad Mahyiddin Ramli ◽  
Siti Salwa Mat Isa ◽  
Mohd Nazrin Md Isa ◽  
Shahrir Rizal Kasjoo ◽  
Simon J. Henley
Keyword(s):  
Carbon Nanotubes ◽  
Hydrogen Sensor ◽  
Pd Nanoparticles ◽  
Paper Substrate ◽  
Blodgett Film ◽  
Langmuir Blodgett ◽  
Multi Walled Carbon Nanotubes ◽  
Gas Molecules ◽  
Walled Carbon Nanotubes ◽  
Functionalized Mwcnts

Langmuir-Blodgett technique was applied to build optically homogeneous film of functionalized multi-walled carbon nanotubes (MWCNTs) on paper substrate. The palladium (Pd) nanoparticles were drop-casted onto MWCNTs network films before being exposed in hydrogen (H2) gas molecules environment under vacuum and atmospheric pressure at room temperature. The results demonstrate that the functionalized MWCNTs dispersed with Pd nanoparticles show good H2sensing response on paper substrate where the sensitivity of around 10 % was recorded at only 2 minutes exposure time.

Synthesis of modified carbon nanotube-supported Pd and the catalytic performance for hydrodehalogenation of aryl halides

2013 ◽  
Vol 91 (5) ◽  
pp. 307-314 ◽  
Author(s):  
Yuandong Xu ◽  
Long Chen ◽  
Xiaolai Wang
Keyword(s):  
Surface Functionalization ◽  
Pd Nanoparticles ◽  
Catalytic Performance ◽  
Surface Oxide ◽  
Aryl Halides ◽  
Optimal Conditions ◽  
Reaction Conditions ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Supported Pd

The effects of surface functionalization on the deposition of Pd nanoparticles on multi-walled carbon nanotubes (CNTs) have been studied. Two methods were used for the functionalization of CNTs: one employed a 1:1 (v/v) mixture of concentrated H2SO4/HNO3, sonicated at RT; the other employed a 3:1 (v/v) mixture of concentrated H2SO4/HNO3, sonicated at 60 °C. A large number of surface oxide groups were introduced on the surface of functionalized CNTs, especially in strong oxidation power (H2SO4/HNO3 = 3:1, 60 °C). The dispersion of Pd nanoparticles on CNTs was found to depend on the amount of surface oxide groups, with larger amounts of surface oxide groups resulting in higher dispersion of Pd nanoparticles. The effects of CNT surface functionalization on the performance of Pd/CNTs catalysts were studied, and the reaction conditions optimized, using the hydrodebromination of bromobenzene as model reaction. Under optimal conditions, the hydrodehalogenation of various aryl halides were tested over Pd/CNTs catalysts.

Sign in / Sign up

Export Citation Format

Share Document