Oxidative dehydrogenation of thiols to disulfides at room temperature using silica supported iron oxide as an efficient solid catalyst

RSC Advances ◽  
2016 ◽  
Vol 6 (98) ◽  
pp. 95753-95759 ◽  
Author(s):  
Susmita Paul ◽  
S. M. Islam
Keyword(s):  
Iron Oxide ◽  
Oxidative Dehydrogenation ◽  
Room Temperature ◽  
Solid Catalyst ◽  
Reaction Conditions ◽  
Selective Transformation ◽  
Supported Iron

Selective transformation of thiols to disulfides by oxidative dehydrogenation has been described using easily prepared and recyclable silica supported iron oxide under green reaction conditions.

Preparation of Highly Dispersed Iron Oxide Nanoparticles in Amine-Modified SBA-15

2005 ◽  
Vol 876 ◽  
Author(s):  
Bing Tan ◽  
Wentao Xu ◽  
Alan Dozier ◽  
Stephen E. Rankin
Keyword(s):  
Iron Oxide ◽  
Iron Oxide Nanoparticles ◽  
Room Temperature ◽  
Oxide Nanoparticles ◽  
Amine Functionalized ◽  
Highly Dispersed ◽  
Uniform Diameter ◽  
Supported Iron

AbstractSilica-supported iron oxide nanoparticles are prepared by precipitation within the pores of amine-functionalized SBA-15 silica. The loading of the iron oxide possible by this method is at least 11 wt%. STEM and TEM images show that the supported particles have a uniform diameter (average ∼ 4.0 nm) and are well dispersed. The supported iron oxide nanoparticles are amorphous after calcination at 300°C and, consistent with their nanoscale dimensions, are superparamagnetic at room temperature.

scholarly journals Reversible oxidation and reduction of gold-supported iron oxide islands at room temperature

2020 ◽  
Vol 152 (7) ◽  
pp. 074710
Author(s):  
Yixuan Jiang ◽  
Yaguang Zhu ◽  
Dechun Zhou ◽  
Zhao Jiang ◽  
Nan Si ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Room Temperature ◽  
Supported Iron

Naturally Occurring Organic Acid-catalyzed Facile Diastereoselective Synthesis of Biologically Active (E)-3-(arylimino)indolin-2-one Derivatives in Water at Room Temperature

2019 ◽  
Vol 23 (16) ◽  
pp. 1778-1788 ◽  
Author(s):  
Gurpreet Kaur ◽  
Arvind Singh ◽  
Kiran Bala ◽  
Mamta Devi ◽  
Anjana Kumari ◽  
...  
Keyword(s):  
Room Temperature ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Diastereoselective Synthesis ◽  
Substituted Anilines ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Acid Catalyzed ◽  
Reaction Media ◽  
Column Chromatographic

A simple, straightforward and efficient method has been developed for the synthesis of (E)-3-(arylimino)indolin-2-one derivatives and (E)-2-((4-methoxyphenyl)imino)- acenaphthylen-1(2H)-one. The synthesis of these biologically-significant scaffolds was achieved from the reactions of various substituted anilines and isatins or acenaphthaquinone, respectively, using commercially available, environmentally benign and naturally occurring organic acids such as mandelic acid or itaconic acid as catalyst in aqueous medium at room temperature. Mild reaction conditions, energy efficiency, good to excellent yields, environmentally benign conditions, easy isolation of products, no need of column chromatographic separation and the reusability of reaction media are some of the significant features of the present protocol.

A Facile, Efficient and Selective Deprotection of P - Methoxy Benzyl Ethers Using Zinc (II) Trifluoromethanesulfonate

2019 ◽  
Vol 16 (12) ◽  
pp. 955-958
Author(s):  
Reddymasu Sireesha ◽  
Reddymasu Sreenivasulu ◽  
Choragudi Chandrasekhar ◽  
Mannam Subba Rao
Keyword(s):  
Room Temperature ◽  
Protecting Groups ◽  
Side Reactions ◽  
Reaction Conditions ◽  
Acid Sensitivity ◽  
Time Period ◽  
Protective Groups ◽  
Benzyl Ethers ◽  
Last Stage ◽  
Zinc Triflate

: Deprotection is significant and conducted over mild reaction conditions, in order to restrict any more side reactions with sensitive functional groups as well as racemization or epimerization of stereo center because the protective groups are often cleaved at last stage in the synthesis. P - Methoxy benzyl (PMB) ether appears unique due to its easy introduction and removal than the other benzyl ether protecting groups. A facile, efficient and highly selective cleavage of P - methoxy benzyl ethers was reported by using 20 mole% Zinc (II) Trifluoromethanesulfonate at room temperature in acetonitrile solvent over 15-120 min. time period. To study the generality of this methodology, several PMB ethers were prepared from a variety of substrates having different protecting groups and subjected to deprotection of PMB ethers using Zn(OTf)2 in acetonitrile. In this methodology, zinc triflate cleaves only PMB ethers without affecting acid sensitivity, base sensitivity and also chiral epoxide groups.

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