Investigation of the photoinduced electron injection processes for natural dye-sensitized solar cells: the impact of anchoring groups

RSC Advances ◽  
2016 ◽  
Vol 6 (88) ◽  
pp. 85125-85134 ◽  
Author(s):  
S. Akın ◽  
S. Açıkgöz ◽  
M. Gülen ◽  
C. Akyürek ◽  
S. Sönmezoğlu
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Electron Injection ◽  
Natural Dye ◽  
Natural Dyes ◽  
Dye Sensitized ◽  
Photovoltaic Parameters ◽  
Anchoring Groups ◽  
The Impact ◽  
Sensitized Solar Cells

In this study, nine different natural dyes having various anchoring groups were extracted from various plants and used as photo-sensitizers in DSSC applications. The photovoltaic parameters were investigated as a function of these anchoring groups.

scholarly journals Natural Dyes: From Cotton Fabrics to Solar Cells

2021 ◽  
Author(s):  
Indriana Kartini ◽  
Adhi Dwi Hatmanto
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Cotton Fabrics ◽  
Natural Dye ◽  
Natural Dyes ◽  
Oxide Surface ◽  
Solar Cell Efficiency ◽  
Cell Efficiency ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

This article will discuss natural dyes’ role, from colouring the cotton fabrics with some functionality to harvesting sunlight in the dye-sensitized solar cells. Natural dye colourants are identical to the low light- and wash-fastness. Therefore, an approach to improving the colourant’s physical properties is necessary. Colouring steps employing silica nanosol and chitosan will be presented. The first part will be these multifunctional natural dye coatings on cotton fabrics. Then, functionality such as hydrophobic surfaces natural dyed cotton fabrics will be discussed. Natural dyes are also potential for electronic application, such as solar cells. So, the second part will present natural dyes as the photosensitizers for solar cells. The dyes are adsorbed on a semiconductor oxide surface, such as TiO2 as the photoanode. Electrochemical study to explore natural dyes’ potential as sensitizer will be discussed, for example, natural dyes for Batik. Ideas in improving solar cell efficiency will be discussed by altering the photoanode’s morphology. The ideas to couple the natural dyes with an organic–inorganic hybrid of perovskite and carbon dots are then envisaged.

scholarly journals Performance of natural-dye-sensitized solar cells by ZnO nanorod and nanowall enhanced photoelectrodes

2017 ◽  
Vol 8 ◽  
pp. 287-295 ◽  
Author(s):  
Saif Saadaoui ◽  
Mohamed Aziz Ben Youssef ◽  
Moufida Ben Karoui ◽  
Rached Gharbi ◽  
Emanuele Smecca ◽  
...  
Keyword(s):  
Solar Cells ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Growth Time ◽  
Dye Sensitized ◽  
Different Temperatures ◽  
Photovoltaic Parameters ◽  
Anchoring Groups ◽  
Sensitized Solar Cells

In this work, two natural dyes extracted from henna and mallow plants with a maximum absorbance at 665 nm were studied and used as sensitizers in the fabrication of dye-sensitized solar cells (DSSCs). Fourier transform infrared (FTIR) spectra of the extract revealed the presence of anchoring groups and coloring constituents. Two different structures were prepared by chemical bath deposition (CBD) using zinc oxide (ZnO) layers to obtain ZnO nanowall (NW) or nanorod (NR) layers employed as a thin film at the photoanode side of the DSSC. The ZnO layers were annealed at different temperatures under various gas sources. Indeed, the forming gas (FG) (N2/H2 95:5) was found to enhance the conductivity by a factor of 103 compared to nitrogen (N2) or oxygen (O2) annealing gas. The NR width varied between 40 and 100 nm and the length from 500 to 1000 nm, depending on the growth time. The obtained NWs had a length of 850 nm. The properties of the developed ZnO NW and NR layers with different thicknesses and their effect on the photovoltaic parameters were studied. An internal coverage of the ZnO NWs was also applied by the deposition of a thin TiO2 layer by reactive sputtering to improve the cell performance. The application of this layer increased the overall short circuit current J sc by seven times from 2.45 × 10−3 mA/cm2 to 1.70 × 10−2 mA /cm2.

Unravel the Impact of Anchoring Groups on the Photovoltaic Performances of Diketopyrrolopyrrole Sensitizers for Dye-Sensitized Solar Cells

2015 ◽  
Vol 3 (10) ◽  
pp. 2389-2396 ◽  
Author(s):  
Paramaguru Ganesan ◽  
Aswani Yella ◽  
Thomas W. Holcombe ◽  
Peng Gao ◽  
Renganathan Rajalingam ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Anchoring Groups ◽  
The Impact ◽  
Sensitized Solar Cells

Pyridyl vs. bipyridyl anchoring groups of porphyrin sensitizers for dye sensitized solar cells

RSC Advances ◽  
2016 ◽  
Vol 6 (26) ◽  
pp. 22187-22203 ◽  
Author(s):  
Panagiotis A. Angaridis ◽  
Eleftherios Ferentinos ◽  
Georgios Charalambidis ◽  
Kalliopi Ladomenou ◽  
Vasilis Nikolaou ◽  
...  
Keyword(s):  
Solar Cells ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Electron Injection ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Anchoring Groups ◽  
Sensitized Solar Cells

Two D–π–A porphyrins (A = pyridyl, bipyridyl) are synthesized and used as sensitizers in DSSCs. The enhanced photovoltaic performance of the bipyridyl-sensitized device is attributed to its faster electron injection and reduced charge recombination.

Molecular engineering of anchoring groups for designing efficient triazatruxene-based organic dye-sensitized solar cells

2019 ◽  
Vol 43 (17) ◽  
pp. 6480-6491 ◽  
Author(s):  
Narendra Nath Ghosh ◽  
Md. Habib ◽  
Anup Pramanik ◽  
Pranab Sarkar ◽  
Sougata Pal
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Organic Dye ◽  
Molecular Engineering ◽  
Dye Sensitized ◽  
Anchoring Groups ◽  
Sensitized Solar Cells

Triazatruxene with designed anchoring groups provides better photovoltaic activities.

Photosystem I Multilayer Films for Photovoltage Enhancement in Natural Dye-Sensitized Solar Cells

2018 ◽  
Vol 1 (2) ◽  
pp. 301-305 ◽  
Author(s):  
Maxwell T. Robinson ◽  
Marie E. Armbruster ◽  
Avi Gargye ◽  
David E. Cliffel ◽  
G. Kane Jennings
Keyword(s):  
Solar Cells ◽  
Photosystem I ◽  
Dye Sensitized Solar Cells ◽  
Multilayer Films ◽  
Natural Dye ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Application of new natural dyes extracted from Nasturtium flowers (Tropaeolum majus) as photosensitizer in dye-sensitized solar cells

Optik ◽  
2021 ◽  
pp. 167331
Author(s):  
Shalini Singh ◽  
Ishwar Chandra Maurya ◽  
Shubham Sharma ◽  
Shiva Prakash Singh Kushwaha ◽  
Pankaj Srivastava ◽  
...  
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Natural Dyes ◽  
Dye Sensitized ◽  
Tropaeolum Majus ◽  
Sensitized Solar Cells

Influence of Electron Injection Rate in Triphenylamine Based Dye for Dye-Sensitized Solar Cells: A First Principle Study

2019 ◽  
Vol 233 (9) ◽  
pp. 1247-1259
Author(s):  
Madhu Prakasam
Keyword(s):  
Solar Cells ◽  
Absorption Spectra ◽  
Density Functional ◽  
Dye Sensitized Solar Cells ◽  
Visible Region ◽  
Electron Injection ◽  
Injection Rate ◽  
Visible Absorption ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Abstract In this work, we systematically investigate the impacts of electron-donor based on Triphenylamine (TPA). The Geometry structure, energy levels, light-harvesting ability and ultraviolet-visible absorption spectra were calculated by using Density Functional Theory (DFT) and Time-Dependent-DFT. The electron injection rate of the TPA-N(CH3)2 based dyes has 0.71 eV for high among the dye sensitizer. The First and Second order Hyperpolarizability of the 11.95 × 10−30 e.s.u and 12195.54 a.u, respectively for TPA-N(CH3)2 based dye. The calculated absorption spectra were showed in the ultra-violet visible region for power conversion region. The study reveals that the electron transfer character of TPA-N(CH3)2 based dyes can be made suitable for applications in Dye-Sensitized Solar Cells.

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