Coumarin functionalized thiocarbonohydrazones as a new class of chromofluorescent receptors for selective detection of fluoride ion

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90322-90330 ◽  
Author(s):  
Satya Narayan Sahu ◽  
Subrata Kumar Padhan ◽  
Prabhat Kumar Sahu

Thiocarbonohydrazone receptors selectively recognize fluoride ionsviaH-bond interactions and subsequent deprotonation to elicit a distinct visual and fluorescence colour change.

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37935-37942 ◽  
Author(s):  
Ajit Kumar Mahapatra ◽  
Parthasarathi Karmakar ◽  
Jagannath Roy ◽  
Srimanta Manna ◽  
Kalipada Maiti ◽  
...  

Phenanthro-imidazole conjugate of biscarbanohyrazone, probe PI was designed, synthesized and characterized for selective detection of fluoride ion.


2021 ◽  
Vol 23 (09) ◽  
pp. 646-655
Author(s):  
Fazlur Rahaman ◽  
◽  
Prabhat Gautam ◽  
Priti Gupta ◽  
Subrata Mondal ◽  
...  

A new thiazole substituted chemosensor 1 has been designed and synthesized for selective detection of fluoride ions. The chemosensor 1 was characterized by 1H NMR and 13C NMR. The absorption studies of chemosensor in DMF exhibits two peaks at 283 nm and 327 nm. The anion sensing behaviour of chemosensor 1 for various anions (I-, Cl-, Br-, NO3-, HSO4-, PF6-, ClO4-) in DMF were investigated by UV-vis spectroscopy. Chemosensor 1 exhibited high degree of selectivity for fluoride ions over other anions. A good linearity in the range of 16-133 μM with 6.12 μM limit of detection value (LOD) was observed.


RSC Advances ◽  
2019 ◽  
Vol 9 (55) ◽  
pp. 32308-32312 ◽  
Author(s):  
Lihong Li ◽  
Min Zhang ◽  
Kaijing Chang ◽  
Yu Kang ◽  
Guodong Ren ◽  
...  

A sensitive and selective fluorescent off–on probe is developed for fluoride ion detection, and its applicability has been demonstrated by determining fluoride ions in real-water samples and toothpaste samples.


2016 ◽  
Vol 45 (2) ◽  
pp. 811-819 ◽  
Author(s):  
Siddhartha Sankar Boxi ◽  
Santanu Paria

In this study, a fluorometric method based on Ag–CdS/Ag–ZnS core/shell nanoparticles is developed for fluoride ion detection.


2017 ◽  
Vol 41 (23) ◽  
pp. 14246-14252 ◽  
Author(s):  
Yue Ni ◽  
Hong Liu ◽  
Jian Xu ◽  
Ying Yue ◽  
Shijun Shao

A new solid–liquid interface for selective recognition of fluoride ions in water was fabricated based on the Nbim/MWCNT/GCE.


2018 ◽  
Vol 42 (14) ◽  
pp. 12162-12171 ◽  
Author(s):  
Shagun Kainth ◽  
Akansha Mehta ◽  
Amit Mishra ◽  
Soumen Basu

The widespread pollution of fluoride ions in the environment badly affects the ecological system due to their high toxicity, mobility and the difficulty of their degradation.


2020 ◽  
Vol 24 (05n07) ◽  
pp. 929-937
Author(s):  
Ewa Jaworska ◽  
Fabrizio Caroleo ◽  
Corrado Di Natale ◽  
Krzysztof Maksymiuk ◽  
Roberto Paolesse ◽  
...  

We present here a new type of fluoride ion optode, constituted by a highly lipophilic PVDF porous membrane modified with a liquid receptor layer containing the emission-active Si corrole F[Formula: see text] selective ionophore. For the optimized composition of the receptor layer, in acidic solutions an increase of Si-corrole emission was observed by increasing fluoride ion concentration, a behavior different from most porphyrinoid-based optical sensors. An observed linear dependence of the Si corrole emission intensity (read at 635 nm) was within the range 10[Formula: see text] to 10[Formula: see text] M of fluoride ions.


2014 ◽  
Vol 103 ◽  
pp. 154-160 ◽  
Author(s):  
Matinder Kaur ◽  
Min Ju Cho ◽  
Dong Hoon Choi

Materials ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 3998 ◽  
Author(s):  
Rie Imataki ◽  
Yukari Shinonaga ◽  
Takako Nishimura ◽  
Yoko Abe ◽  
Kenji Arita

Especially in pediatric dentistry, prevention by the control of initial lesions prior to cavitation is very important, and application of a pit and fissure sealant is essential to achieve this. Numerous reports have suggested that resin-based sealants are inferior to sealants based on glass-ionomer cement (GIC), because of GIC’s many advantages, such as fluoride ion release properties and its good adhesion to tooth structures. However, the use of GIC is impeded due to its low flexural strength and fracture toughness. In this paper, we developed and characterized an apatite-ionomer cement (AIC) that incorporates hydroxyapatite (HAp) into the GIC; this development was aimed at not only reinforcing the flexural and compressive strength but also improving some functional properties for the creation of the material suitable for sealant. We examined the influence of differences in the compounding conditions of GIC powder, liquid, and HAp on flexural and compressive strengths, fracture toughness, fluoride ion release property, shear bond strength to bovine enamel, surface pH of setting cements, and acid buffer capability. These methods were aimed at elucidating the reaction mechanism of porous spherical-shaped HAp (HApS) in AIC. The following observations were deduced. (1) HAp can improve the mechanical strengths of AIC by strengthening the cement matrix. (2) The functional properties of AIC, such as acid buffer capability, improved by increasing the releasing amounts of various ions including fluoride ions. The novel AIC developed in this study is a clinically effective dental material for prevention and remineralization of tooth and initial carious lesion.


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