Inorganic layered double hydroxides as a 4-hexyl resorcinol delivery system for topical applications

RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 77709-77716 ◽  
Author(s):  
Damodar Mosangi ◽  
Sreejarani Kesavan Pillai ◽  
Lumbidzani Moyo ◽  
Suprakas Sinha Ray

In this study, the hydrophobic even skin tone active, 4-hexylresorcinol is intercalated into a Zn–Al layered double hydroxide by co-precipitation method and used as controlled release ingredient in a skin care formulation.

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4089
Author(s):  
Cristina Modrogan ◽  
Simona Cǎprǎrescu ◽  
Annette Madelene Dǎncilǎ ◽  
Oanamari Daniela Orbuleț ◽  
Eugeniu Vasile ◽  
...  

Magnesium–aluminum (Mg-Al) and magnesium–aluminum–nickel (Mg-Al-Ni) layered double hydroxides (LDHs) were synthesized by the co-precipitation method. The adsorption process of Mn2+ from synthetic wastewater was investigated. Formation of the layered double hydroxides and adsorption of Mn2+ on both Mg-Al and Mg-Ni-Al LDHs were observed by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) and Energy Dispersive Spectrometry (EDX) analysis. XRD patterns for prepared LDHs presented sharp and symmetrical peaks. SEM studies revealed that Mg-Al LDH and Mg-Al-Ni LDH exhibit a non-porous structure. EDX analysis showed that the prepared LDHs present uniformly spread elements. The adsorption equilibrium on these LDHs was investigated at different experimental conditions such as: Shaking time, initial Mn2+ concentration, and temperatures (10 and 20 °C). The parameters were controlled and optimized to remove the Mn2+ from synthetic wastewater. Adsorption isotherms of Mn2+ were fitted by Langmuir and Freundlich models. The obtained results indicated that the isotherm data fitted better into the Freundlich model than the Langmuir model. Adsorption capacity of Mn2+ gradually increased with temperature. The Langmuir constant (KL) value of Mg-Al LDH (0.9529 ± 0.007 L/mg) was higher than Mg-Al-Ni LDH (0.1819 ± 0.004 L/mg), at 20 °C. The final adsorption capacity was higher for Mg-Al LDH (91.85 ± 0.087%) in comparison with Mg-Al-Ni LDH (35.97 ± 0.093%), at 20 °C. It was found that the adsorption kinetics is best described by the pseudo-second-order model. The results indicated that LDHs can be considered as a potential material for adsorption of other metallic ions from wastewater.


RSC Advances ◽  
2021 ◽  
Vol 11 (40) ◽  
pp. 24747-24751
Author(s):  
Dimy Nanclares ◽  
Alysson F. Morais ◽  
Thainá Calaça ◽  
Ivan G. N. Silva ◽  
Danilo Mustafa

The incorporation of triply charged lanthanides in layered double hydroxides (LDHs) enables the curvature of the LDH sheets, unlocking the possibility of using a soft templating strategy to produce a class of luminescent, hierarchical LDH nanotubes.


RSC Advances ◽  
2015 ◽  
Vol 5 (115) ◽  
pp. 94562-94570 ◽  
Author(s):  
Jacky H. Adwani ◽  
Noor-ul H. Khan ◽  
Ram S. Shukla

A novel nano-bio composite of chitosan and a layered double hydroxide elegantly synthesized by a co-precipitation method had effectively and selectively catalysed the jasminaldehyde synthesis.


Clay Minerals ◽  
2004 ◽  
Vol 39 (2) ◽  
pp. 115-121 ◽  
Author(s):  
Deng-Shiu Yang ◽  
Ming-Kuang Wang ◽  
Shan-Li Wang

AbstractLayered double hydroxides (LDHs) are known as ‘anionic clays’. They comprise a class of material with positively charged octahedral double hydroxyl layers and exchangeable anions. The Li/Al LDH term includes a group of LDHs with Li/Al octahedral double hydroxyl layers. We have demonstrated a modifed method, using Li/Al LDH-OH (OH− as interlayer anions) as the starting material, for preparing Li/Al LDH-X (X represents interlayer anions, including dioctyl sulphosuccinate (DOSS), dodecyl sulphate (DDS), mercaptoacetate (MA), EDTA, Tiron and dichromate) under mild acid conditions (pH in the range 4 to 5). However, in the case of acidsensitive anions, Fe(CN)64−, Li/Al LDH-Fe(CN)64− can be prepared by a two-step procedure using Li/Al LDH-DOSS or similar compounds as intermediates to react with acid-sensitive anions under mild alkaline conditions (pH ≈ 9).


2019 ◽  
Vol 7 (6) ◽  
pp. 2831-2837 ◽  
Author(s):  
Qing Yan ◽  
Peng Yan ◽  
Tong Wei ◽  
Guiling Wang ◽  
Kui Cheng ◽  
...  

A highly-efficient water splitting device is assembled with the platinum sub-nanoclusters functionalized nickel iron layered double hydroxides and hierarchical nickel iron selenides.


RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16419-16436 ◽  
Author(s):  
Michele A. Rocha ◽  
Philippe A. D. Petersen ◽  
Erico Teixeira-Neto ◽  
Helena M. Petrilli ◽  
Fabrice Leroux ◽  
...  

Systems comprising anti-inflammatory sulindac intercalated into biocompatible layered double hydroxides nanovehicles were isolated through one pot synthetic method and showed high crystallinity and curled or scrolled particles.


2018 ◽  
Vol 42 (16) ◽  
pp. 13963-13970 ◽  
Author(s):  
Leila Jafari Foruzin ◽  
Biuck Habibi ◽  
Zolfaghar Rezvani

In this study, ultrasonication, a facile and rapid process, was utilized for the preparation of ternary-component layered double hydroxides (LDHs), Ni3AlxFe1−x-LDHs, as the electrocatalyst material for the oxygen evolution reaction (OER) in a neutral solution.


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