The enhanced performance of a CeSiOx support on a Mn/CeSiOx catalyst for selective catalytic reduction of NOx with NH3

RSC Advances ◽  
2016 ◽  
Vol 6 (86) ◽  
pp. 82707-82715 ◽  
Author(s):  
Wei Li ◽  
Rui-tang Guo ◽  
Shu-xian Wang ◽  
Wei-guo Pan ◽  
Qi-lin Chen ◽  
...  

A series of Mn/CeSiOx catalysts were prepared by the wet impregnation method and used for selective catalytic reduction of NO with NH3.

2021 ◽  
Author(s):  
Nawel Jr ◽  
Thabet Makhlouf ◽  
Gerard Delahay ◽  
Hassib Tounsi

Abstract Copper loaded η-alumina catalysts with different copper contents have been prepared by impregnation/evaporation method. The catalysts were characterized by XRD, FTIR, BET, UV–vis, H2-TPR and evaluated in the selective catalytic reduction of NO by NH3 and in the selective catalytic oxidation of NH3. The characterization techniques showed that the impregnation/evaporation method permits to obtain highly dispersed copper oxide species on the η-alumina surface when low amount of copper is used (1wt. % and 2 wt.%). The wet impregnation method made it possible to reach a well dispersion of the copper species on the surface of the alumina for the low copper contents Cu(1)-Al2O3 and Cu(2)-Al2O3. The latter justifies the similar behavior of Cu(1)-Al2O3) and Cu(2)-Al2O3 in the selective catalytic oxidation of NH3 where these catalysts exhibit a conversion of NH3 to N2 of the order of 100% at T > 500°C.


2011 ◽  
Vol 71-78 ◽  
pp. 2806-2813
Author(s):  
Jiang Jun Hu ◽  
Qian Ma ◽  
Ling Ouyang ◽  
Xi Chen ◽  
Fu Xing Gan

The selective catalytic reduction of nitric oxide by ethylene was studied over Cu/ZSM-5 catalyst in the temperature range of 200-550°C, in which NO cannot be reduced by ethylene without Cu/ZSM-5 catalyst. Prepared Cu/ZSM-5 catalyst in varies loading as Na/ZSM-5 by the wet impregnation method, and the effect of the catalytic activity was studied in varies fitting temperatures. Several influencing factors, such as the different reaction temperatures, oxygen gas concentration, and Cu2+ concentration were investigated. Cu-Ce-ZSM-5 catalyst was prepared by wet impregnation method and the metallic influence of CeO2 to the catalytic ability was studied.


RSC Advances ◽  
2015 ◽  
Vol 5 (110) ◽  
pp. 90235-90244 ◽  
Author(s):  
Shuangshuang Lai ◽  
Dongmei Meng ◽  
Wangcheng Zhan ◽  
Yun Guo ◽  
Yanglong Guo ◽  
...  

Ce doped Cu/ZSM-5 catalysts were prepared by the incipient-wetness-impregnation method, and the effect of Ce doping on the structure and the catalytic performance was investigated in detail for the selective catalytic reduction of NO with NH3


2014 ◽  
Vol 535 ◽  
pp. 709-712
Author(s):  
Ye Jiang ◽  
Yan Yan ◽  
Shan Bo Huang ◽  
Xiong Zhang ◽  
Xin Wei Wang ◽  
...  

A Ce-Zr-Ti oxide catalyst was prepared by an impregnation method and tested for the selective catalytic reduction of NO with NH3. The Ce-Zr-Ti oxide catalyst exhibited high activity and more than 95% NO conversion was obtained within the temperature range 300-500 °C at the high gas hourly space velocity of 50,000 h-1. The addition of Zr improved the activity of Ce-Ti oxides especially at higher reaction temperatures and their resistance to SO2.


RSC Advances ◽  
2019 ◽  
Vol 9 (55) ◽  
pp. 32232-32239 ◽  
Author(s):  
Dezhong Yu ◽  
Xin Zhong ◽  
Dong Liu ◽  
Ying Liang

Bi2O3/Co3O4 catalysts prepared by the impregnation method were investigated for the selective catalytic reduction of NO by C3H6 (C3H6-SCR) in the presence of O2.


2015 ◽  
Vol 1088 ◽  
pp. 569-572
Author(s):  
Zhi Hao Zhang ◽  
Yang Li ◽  
Yun Fang Qi ◽  
Qing Ye ◽  
Shu Lan Ji ◽  
...  

Cu/Na-Sep samples were prepared by the incipient wetness impregnation method. These catalysts were characterized by means of XRF, XRD, and XPS techniques, and their catalytic activities were performed by the SCR of NO with propylene. The results show that the Cu/Na-Sep catalyst exhibited the high performance in the C3H6-SCR of NO. After investigation by XRD and XPS, the result showed that there are Cu2+/Cu+redox species as a reaction activity center over Cu/Na-Sep.


2002 ◽  
Vol 20 (10) ◽  
pp. 937-945
Author(s):  
Th. El-Nabarawy ◽  
M.N. Alaya ◽  
S.A. Sayed Ahmed ◽  
A.M. Youssef

Vanadia/titania catalysts were prepared containing 6.0 or 8.0 wt% V2O5 via the impregnation method. The samples as prepared were calcined at 400°C or 600°C, respectively. Selective catalytic reduction (SCR) of NO with NH3 was carried out at 257°C over the prepared catalysts. NO conversion as a function of time was followed and the stationary conversion versus the amount of catalyst employed was also investigated. It was found that the vanadia/titania catalysts calcined at 400°C were more active in the SCR of NO with NH3 relative to those calcined at 600°C. This was attributed to such catalysts possessing complete monolayer coverage of vanadia on the titania substrate. It was established that V5+ was not the active vanadia species but V4+ and V3+ may act as such for the SCR of NO with NH3.


RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48785-48792 ◽  
Author(s):  
Quan Xu ◽  
Rigu Su ◽  
Li Cao ◽  
Yeqing Li ◽  
Chuanyao Yang ◽  
...  

A Ce–Mn–Fe/TiO2 catalyst has been successfully prepared using a single impregnation method with excellent low-temperature NH3-SCR activity.


2020 ◽  
Vol 10 (21) ◽  
pp. 7399-7399
Author(s):  
Jialing Chen ◽  
Gang Peng ◽  
Wei Zheng ◽  
Wenbo Zhang ◽  
Li Guo ◽  
...  

Correction for ‘Excellent performance of one-pot synthesized Fe-containing MCM-22 zeolites for the selective catalytic reduction of NOx with NH3’ by Jialing Chen et al., Catal. Sci. Technol., 2020, 10, 6583–6598, DOI: 10.1039/D0CY00989J.


Author(s):  
Yanke Yu ◽  
Xianfang Yi ◽  
Jiali Zhang ◽  
Zhaojian Tong ◽  
Changwei Chen ◽  
...  

Non-vanadium-based catalysts with high SO2 tolerance are still challenging to date in selective catalytic reduction of NO by NH3 (NH3-SCR) and SO2 adsorption is the foremost step for the deactivation...


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