Synthesis, characterization and photo-catalytic performance of meso-porous Si–N co-doped nano-spherical anatase TiO2 with high thermal stability

RSC Advances ◽  
2016 ◽  
Vol 6 (112) ◽  
pp. 110741-110749 ◽  
Author(s):  
PengChao Wen ◽  
WeiWei Ji ◽  
Hao Zhong ◽  
Lin Li ◽  
Bi Zhang ◽  
...  

Meso-porous Si–N co-doped nano-spherical anatase TiO2 with high thermal stability.

Nanomaterials ◽  
2018 ◽  
Vol 8 (5) ◽  
pp. 294 ◽  
Author(s):  
Peisan Wang ◽  
Chunxia Qi ◽  
Pengchao Wen ◽  
Luyuan Hao ◽  
Xin Xu ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1352 ◽  
Author(s):  
Minghui Zhang ◽  
Haiqin Wen ◽  
Xiuhong Pan ◽  
Jianding Yu ◽  
Hui Shao ◽  
...  

The effect of Yb3+ ions on upconversion luminescence and thermal properties of Tm3+/Yb3+ co-doped La2O3-Nb2O5-Ta2O5 glasses has been studied. Glass transition temperature is around 740 °C, indicating high thermal stability. The effect of Yb3+ ions on the thermal stability is not obvious. Both the glass forming ability and the upconversion luminescence first increase and then decrease with the increase of Yb3+ ions. The glasses perform low glass forming ability with ΔT around 55 °C. Blue and red emissions centered around 477, 651, and 706 nm are obtained at the excitation of 976 nm laser. The upconversion luminescence mechanism is energy transfer from Yb3+ to Tm3+ mixed with two- and three- photon processes. The thermal kinetic Differential Thermal Analysis (DTA)-analysis indicates that the average activation energy first increases and then decreases with the increase of Yb3+ ions. This result can be introduced in order to improve upconversion luminescence of glasses by crystallization in the future. Tm3+/Yb3+ co-doped La2O3-Nb2O5-Ta2O5 glasses with good upconversion and thermal properties show promising applications in solid-state laser, optical temperature sensing.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Libing Liao ◽  
Jie Fu ◽  
Dan Yang

Abstract What ideal w-LED phosphors always aim to do is to achieve a single phase near-sunlight emission phosphor simultaneously with both high luminescence efficiency and high thermal stability at operation temperature. And It is well known that apatite compound phosphors are one of the most promising optical materials to realize those above because of their unique structure enhanced luminescence properties and thermal stability. Here, we synthesized a co-doped single phase apatite phosphors Ca2La8(SiO4)6O2:Dy3+/Sm3+ (CLSO:Dy3+/Sm3+) for white light emission, which was provided with excellent thermal stability and of which luminescence intensity at 150 °C still was 92 percentage of that at room temperature. Moreover, X-ray diffraction technique, Fourier transform infrared spectroscopy, scanning electron microscope were employed to characterization of phase structure and morphology, and consequently pure apatite structure and gravel-like morphology of phosphors were proved. Analysis of photoluminescence spectra indicated that concentration quenching effect exist in single-doped CLSO:Dy3+ phosphors owing to dipole-dipole interaction between Dy3+ ions. It is revealed that maybe exist Dy3+ ↔ Sm3+ bilateral non-radiative energy transfer processes in Dy3+/Sm3+ co-doped CLSO system by PL spectra and decay curves. And variation of Sm3+ ion concentration can control color emission, namely CIE chromaticity coordinates and correlated color temperature, finally to achieve white light emission (0.309,0.309) with CCT 6848 K, able to be a potential candidate for commercial lighting applications.


ChemCatChem ◽  
2012 ◽  
Vol 4 (6) ◽  
pp. 844-850 ◽  
Author(s):  
Fanfei Sun ◽  
Wei Zhou ◽  
Guohui Tian ◽  
Kai Pan ◽  
Xiaohuan Miao ◽  
...  

2020 ◽  
Vol 846 ◽  
pp. 156435
Author(s):  
YaDan Ma ◽  
XiuSha Peng ◽  
MingZhi Fei ◽  
WenNa Zhang ◽  
LiMing Teng ◽  
...  

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